Abstract
In this work, the influence of SiO2 additions in leucite ceramics on the bulk linear thermal expansion coefficient (TEC) especially during the phase transition, has been studied. Thermal expansion and x-ray diffraction measurements at high temperatures were carried out to characterize the tetragonal-cubic phase transition. TEC for reference and SiO2-added leucite samples exhibited similar behavior as a function of temperature. Before and after the phase transition, the TEC values were similar to those observed in non-SiO2-added samples, whereas during the phase transition, a maximum TEC value was observed and it tends to decrease as the SiO2 addition increases. This behavior could be caused by the formation of an intermediate phase with an extremely high TEC (70 × 10–6 °C−1) during the phase transformation. Furthermore, the results suggest that as the intermediate phase is partially suppressed via SiO2 addition, the cubic phase can be partially stabilized at temperatures as low as 200 °C.
Similar content being viewed by others
References
J. Hautaniemi and H. Hero: Effect of crystalline leucite on porcelain bonding on titanium. J. Am. Ceram. Soc. 74, 1449 (1991).
J. Mackert and A. Evans: Quantitative x-ray diffraction determination of leucite thermal instability in dental porcelain. J. Am. Ceram. Soc. 74, 450 (1991).
T. Ota, M. Takahashi, and I. Yamai: High-thermal-expansion poly-crystalline leucite ceramic. J. Am. Ceram. Soc. 76, 2379 (1993).
T. Sheu, W. O’Brien, S. Rasmussen, and T. Tien: Mechanical properties and thermal expansion behavior in leucite containing materials. J. Mater. Sci. 29, 125 (1994).
J. Maixner, A. Klouzkova, M. Mrazova, and M. Kohoutkova: X-ray analysis in leucite systems. Z. Kristallogr. Suppl. 26, 531 (2007).
X. Li and L. Shaw: Formation of leucite-free zone in laser densified dental porcelains. Mater. Sci. 61, 3946 (2007).
A. Klouzkova, M. Mrazova, and M. Kohoutkova: Synthesis of partially stabilized leucite. J. Phys. Chem. Solids 68, 1207 (2007).
M. Novotna and J. Maixner: X-ray powder diffraction study of leucite crystallization. Z. Kristallogr. Suppl. 23, 455 (2006).
D. Taylor and C. Henderson: The thermal expansion of the leucite group of minerals. Am. Mineral. 53, 1476 (1968).
K. Hirao, N. Soga, and M. Kunugi: Thermal expansion and structure of leucite-type compounds. J. Phys. Chem. 80, 1612 (1976).
H. Newton, S. Hayward, and S. Redfern: Order parameter coupling in leucite: A calorimetric study. Phys. Chem. Miner. 35, 11 (2008).
T. Grögel, H. Boysen, and F. Frey: Phase transition and ordering in leucite. Acta Crystallogr. S40, C–256 (1984).
C. Henderson: The tetragonal-cubic inversion in leucite solid solutions. Prog. Exp. Petrol. 50, 50 (1981).
F. Mazzi, E. Galli, and G. Gottardi: Crystal structure of tetragonal leucite. Am. Mineral. 61, 108 (1976).
J. Rodriguez-Carvajal: Recent advances in magnetic structure determination by neutron powder diffraction. Z. Phys. B: Condens. Matter 192, 55 (1993).
Powder Diffraction Files: The International Centre for Diffraction, Swarthmore, PA, 2004.
J. Schairer and N. Bowen: Melting relations in the system Na2OAl2O3-SiO2 and K2O-Al2O3-SiO2. Am. J. Sci. 245, 193 (1947).
N. Henry and K. Lonsdale: International Tables for X-ray Crystallography (The International Union of Crystallography and The Kynoch Press Publishers, Birmingham, AL, 1965).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Wiff, J.P., Kinemuchi, Y., Naito, S. et al. Phase transition and thermal expansion coefficient of leucite ceramics with addition of SiO2. Journal of Materials Research 24, 1989–1993 (2009). https://doi.org/10.1557/jmr.2009.0241
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/jmr.2009.0241