Abstract
To estimate the ratio of densification to Vickers indentation volume, three-dimensional images of Vickers indentations on several glasses, including silicate glasses and bulk metallic glass (BMG), were obtained before and after annealing using an atomic force microscope. Large volume recovery of Vickers indentation by annealing was observed for all glasses but BMG. Following previous studies, this recovered volume almost corresponded to the densified volume under a Vickers indenter, and the compositional dependence of densification was discussed. The ratios of densification to the total indentation volume for silica and soda-lime glasses were 92% and 61%, respectively. It was concluded that densification was a general property for silicate glasses and that the ratios of densification to the total indentation volume for all the glasses correlated well with Poisson’s ratios of the glasses.
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References
K.W. Peter: Densification and flow phenomena of glass in indentation experiments. J. Non-Cryst. Solids 5, 103 (1970).
A. Arora, D.B. Marshall and B.R. Lawn: Indentation deformation/fracture of normal and anomalous glasses. J. Non-Cryst. Solids 31, 415 (1979).
J.T. Hagan: Shear deformation under pyramidal indentations in soda-lime glass. J. Mater. Sci. 15, 1417 (1980).
S.S. Chiang, D.B. Marshall and A.G. Evans: The response of solids to elastic/plastic indentation I. Stresses and residual stresses. J. Appl. Phys. 53, 298 (1982).
E.H. Yoffe: Elastic stress fields causes by indenting brittle materials. Philos. Mag. A 46, 617 (1982).
R.F. Cook and G.M. Pharr: Direct observation of indentation cracking in glass and ceramics. J. Am. Ceram. Soc. 73, 787 (1990).
F.M. Ernsberger: Role of densification in deformation of glasses under point loading. J. Am. Ceram. Soc. 51, 545 (1968).
C.R. Kurkjian, G.W. Kammlott and M.M. Chaudhri: Indentation behavior of soda-lime silica glass, fused silica, and single-crystal quartz at liquid-nitrogen temperature. J. Am. Ceram. Soc. 78, 737 (1995).
W.B. Hillig: Concerning the creation and stability of pyramidal hardness impression on glass, in Proceedings of VIth International Congress on Glass, Washington, July 8–14, 1962 (Am. Ceram. Soc., Westerville, OH, 1963), p. 51.
J.E. Neely and J.D. Mackenzie: Hardness and low-temperature deformation of silica glass. J. Mater. Sci. 3, 603 (1968).
S. Yoshida, S. Isono, J. Matsuoka and N. Soga: Shrinkage behavior of Knoop indentations in silica and soda-lime-silica glasses. J. Am. Ceram. Soc. 84, 2141 (2001).
J.D. Mackenzie: High-pressure effects on oxide glass: II. Subsequent heat treatment. J. Am. Ceram. Soc. 46, 470 (1963).
Y. He, R.B. Schwarz and J.I. Archuleta: Bulk glass formation in the Pd–Ni–P system. Appl. Phys. Lett. 69, 1861 (1996).
B. Baron, T. Chartier, T. Rouxel, P. Verdier and Y. Laurent: SiC particle reinforced oxynitride glass—Processing and mechanical properties. J. Eur. Ceram. Soc. 17, 773 (1997).
E.F. Lambson, W.A. Lambson, J.E. Macdonald, M.R.J. Gibbs, G.A. Saunders and D. Turnbull: Elastic behavior and vibrational anharmonicity of a bulk Pd40Ni40P20 metallic glass. Phys. Rev. B 33, 2380 (1986).
M.G. Walls, M.M. Chaudhri and T.B. Tang: STM profilometry of low-load Vickers indentations in a silicon crystal. J. Phys.: D 25, 500 (1992).
J. Shen, D.J. Green, R.E. Tressler and D.L. Shelleman: Stress relaxation of a soda lime silicate glass below the glass transition temperature. J. Non-Cryst. Solids 324, 277 (2003).
G. Hetherington, K.H. Jack and J.C. Kennedy: The viscosity of vitreous silica. Phys. Chem. Glasses 5, 130 (1964).
A. Agarwal and M. Tomozawa: Surface and bulk structural relaxation kinetics of silica glass. J. Non-Cryst. Solids 209, 264 (1997).
S.A. Brawer and W.B. White: Raman spectroscopic investigation of the structure of silicate glasses. I. The binary alkali silicates. J. Chem. Phys. 63, 2421 (1975).
N. Kitamura, K. Fukumi, H. Mizoguchi, M. Makihara, A. Higuchi, N. Ohno and T. Fukunaga: High pressure densification of lithium silicate glasses. J. Non-Cryst. Solids 274, 244 (2000).
K. Kase and D.J. Rowcliffe: Nanoindentation method foe measuring residual stress in brittle materials. J. Am. Ceram. Soc. 86, 811 (2003).
K. Kase, M. Tehler and B. Bergman: Contact residual stress relaxation in soda-lime glass Part 1. Measurement using nanoindentation. J. Euro. Ceram. Soc. (in press).
L.M. Wang, W.H. Wang, R.J. Wang, Z.J. Zhan, D.Y. Dai, L.L. Sun and W.K. Wang: Ultrasonic investigation of Pd39Ni10Cu30P21 bulk metallic glass upon crystallization. Appl. Phys. Lett. 77, 1147 (2000).
L.M. Wang, Z.J. Zhan, J. Liu, L.L. Sun, G. Li and W.K. Wang: Compression behavior of Pd39Ni10Cu30P21 bulk metallic glass up to 23.5 GPa. J. Phys.: Condens. Matter 13, 5743 (2001).
K. Suzuki, Y. Benino, T. Fujiwara and T. Komatsu: Densification energy during nanoindentation of silica glass. J. Am. Ceram. Soc. 85, 3102 (2002).
P.W. Bridgman and I. Simon: Effects of very high pressures on glass. J. Appl. Phys. 24, 405 (1953).
J.D. Mackenzie: High-pressure effects on oxide glasses: I. Densification in rigid state. J. Am. Ceram. Soc. 46, 461 (1963).
H.M. Cohen and R. Roy: Effects of ultrahigh pressures on glass. J. Am. Ceram. Soc. 44, 523 (1961).
T. Rouxel, J.C. Sanglebœuf, C. Moysan and B. Truffin: Indentation topometry in glasses by atomic force microscopy. J. Non-Cryst. Solids 344, 26 (2004).
S. Yoshida, J.C. Sanglebœuf, and T. Rouxel (unpublished data).
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Yoshida, S., Sangleboeuf, JC. & Rouxel, T. Quantitative evaluation of indentation-induced densification in glass. Journal of Materials Research 20, 3404–3412 (2005). https://doi.org/10.1557/jmr.2005.0418
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DOI: https://doi.org/10.1557/jmr.2005.0418