Skip to main content
Log in

In-Situ Surface Photo-Absorption Study of Movpe Surface

  • Published:
MRS Online Proceedings Library Aims and scope

Abstract

In-situ surface photo-absorption (SPA) method was applied to study the dynamic surface processes and the static surface structures during metal-organic vapor phase epitaxy (MOVPE). Observed spectra in near-ultaviolet and visible regions consist of an anisotropic dielectric response due to surface dimer-bonds as well as an isotropic response probably due to surface back-bonds. Time-resolved spectra showing dynamic changes of surface can be measured by the use of optical multichannel analyzer. The rate of surface decomposition of source molecule was measured as the change of reflectivity at a fixed wavelength. The decomposition of source molecule was characterized quantitatively, and various effects on the decomposition were studied. The style of decomposition and the activation energy depended on the substituent of source molecule and the rate of decomposition was affected by the surface potential and the strain.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. H. Saito, K. Uwai, and N. Kobayashi, Jpn. J. Appl. Phys. 32, 4440 (1993).

    Article  CAS  Google Scholar 

  2. S. Ando, N. Kobayashi, and H. Ando, Jpn. J. Appl. Phys. 32, L1293 (1993).

    Article  CAS  Google Scholar 

  3. N. Kobayashi and Y. Horikoshi, Jpn. J. Appl. Phys. 28, L1880 (1989).

    Article  CAS  Google Scholar 

  4. G. B. Stringfellow, in Organometallic Vapor-Phase Epitaxy: Theory and Practice, (Academic Press Inc, 1989).

    Google Scholar 

  5. N. Kobayashi and Y. Horikoshi, Jpn. J. Appl. Phys. 29, L702 (1990).

    Article  CAS  Google Scholar 

  6. Y. Horikoshi, M. Kawashima, and N. Kobayashi, J. Crystal Growth 111, 200 (1991).

    Article  CAS  Google Scholar 

  7. Y-C. Chang and D. E. Aspnes, Phys. Rev. B41, 12002 (1990).

    Article  Google Scholar 

  8. Y. Yamauchi, K. Uwai, and N. Kobayashi, Jpn. J. Appl. Phys. 32, 3363 (1993).

    Article  CAS  Google Scholar 

  9. I. Kamiya, D. E. Aspnes, H. Tanaka, L. T. Florez, J. P. Harbison, and R. Bhat, Phys. Rev. Lett. 68, 627 (1992).

    Article  CAS  Google Scholar 

  10. D. W. Kisker, P. H. Fuoss, K. L. Tokuda, G. Renaudo, S. Brennan, and J. L. Kahn, Appl. Phys. Lett. 56, 2025 (1990).

    Article  CAS  Google Scholar 

  11. Y. Kobayashi and N. Kobayashi, to be published in Jpn. J. Appl. Phys. 33 (1994).

  12. D. E. Aspnes, Y-C. Chang, A. A. Studna, L. T. Florez, H. H. Farrell, and J. P. Harbison, Phys. Rev. Lett. 64, 192 (1990).

    Article  CAS  Google Scholar 

  13. N. Kobayashi and Y. Horikoshi, Jpn. J. Appl. Phys. 30, L1443 (1991).

    Article  CAS  Google Scholar 

  14. N. Kobayashi, Y. Kobayashi, Y. Yamauchi, and Y. Horikoshi, Appl. Surface Sci. 60/61, 544 (1992).

    Article  Google Scholar 

  15. N. Kobayashi and Y. Horikoshi, Jpn. J. Appl. Phys. 30, L319 (1991).

    Article  CAS  Google Scholar 

  16. N. Kobayashi and Y. Kobayashi, Thin Solid Films 225, 32 (1993).

    Article  CAS  Google Scholar 

  17. Y. Yamauchi, T. Makimoto, N. Kobayashi, and Y. Horikoshi, Jpn. J. Appl. Phys. 29, L1353 (1990).

    Article  CAS  Google Scholar 

  18. Y. Yamauchi and N. Kobayashi, Jpn. J. Appl. Phys. 30, L2073 (1991).

    Article  CAS  Google Scholar 

  19. N. Kobayashi and Y. Yamauchi, J. Crystal Growth 124, 44 (1992).

    Article  CAS  Google Scholar 

  20. Y. Kobayashi and N. Kobayashi, to be published in J. Crystal Growth 126 (1994).

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kobayashi, N. In-Situ Surface Photo-Absorption Study of Movpe Surface. MRS Online Proceedings Library 340, 91–103 (1994). https://doi.org/10.1557/PROC-340-91

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/PROC-340-91

Navigation