Abstract
The mixed conducting LixMO2O4 system was shown to exhibit a high energy density (530Wh/kg) and average voltage (3.1V), suggesting that it would be a good candidate for a cathode in a Li-anode secondary battery. The transport properties of these oxide materials were then investigated by solid state 7Li NMR, dc and ac electrical measurements. The following phases are emphasized in this study: Li1.3MO2O4, Li2MO2O4, and the hydrated phase Li0.5 (H2O)1.3MO2O4.
Similar content being viewed by others
References
J.M. Tarascon, J. Electrochem. Soc., 134, 1345 (1987).
J.M. Tarascon and S. Colson, Mat. Res. Soc. Symp. Proc., 135, 421 (1989).
L.E. Aleandri, P.A. Edwards and R.E. McCarley, in American Chemical Society Meeting, Chicago, September 8-13 (1985).
L.E. Aleandri and R.E. McCarley, in American Chemical Society Meeting, New York, April 13-16 (1986).
S. Colson, J.M. Tarascon, S. Szu and L.C. Klein, to be published.
V.N. Schcherbakov, S.P. Gabuda and S.A. Seryshev, Soviet Physics-Solid state, 12, 2477 (1971).
Acknowledgement
The authors wish to thank Professor G. Sigel, Rutgers University, and Dr J.H. Wernick, Bell Communication Research, for supporting this project, as well as Dr P. Barboux and E. Vogel, Bell Communication Research, for technical discussions.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Colson, S., Tarascon, J., Szu, S. et al. Transport Properties of the Intercalated Layered Cathode Materials: LiXMo2O4.. MRS Online Proceedings Library 210, 405–410 (1990). https://doi.org/10.1557/PROC-210-405
Published:
Issue Date:
DOI: https://doi.org/10.1557/PROC-210-405