Abstract
The microstructure of Pt-modified γ’-Ni3Al + γ-Ni coating on CMSX-4 single-crystal superalloy has been investigated by transmission electron microscopy (TEM). Cross-sectional TEM analyses showed the presence of precipitates in the coating. This precipitate was identified as the hexagonal topologically close-packed (TCP) µ phase with lattice parameters a = 0.473 nm and c = 2.565 nm. The energy-dispersive x-ray (EDX) spectrum of the µ phase suggested a refractory element rich compound comprising the elements Re, W, and Co. Twin domains parallel to (001) were found in the µ phase. The mechanisms of the µ phase and twinning formation were discussed.
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References
B. Gleeson Thermal-barrier coatings for aeroengine applications. J. Propul. Power 22, 375 (2006)
G.W. Goward Progress in coatings for gas turbine airfoils. Surf. Coat. Technol. 108–109, 73 (1998)
B.A. Pint, K.L. More Characterization of alumina interfaces in TBC systems. J. Mater. Sci. 44, 1676 (2009)
N.P. Padture, M. Cell, E.H. Jordan Thermal-barrier coatings for gas-turbine engine applications. Science 296, 280 (2002)
D.R. Clarke, C.G. Levi Materials design for the next generation thermal barrier coating. Annu. Rev. Mater. Res. 33, 383 (2003)
M.W. Chen, M.L. Glynn, R.T. Ott, T.C. Hufnagel, K.L. Hemker Characterization and modeling of a martensitic transformation in a platinum modified diffusion aluminide bond coat for thermal-barrier coatings. Acta Mater. 51, 4279 (2003)
T.M. Pollock, S. Tin Nickel-based superalloys for advanced turbine engines: Chemistry, microstructure, and properties. J. Propul. Power 22, 361 (2006)
P. Poza, P.S. Grant Microstructure evolution of vacuum plasma sprayed CoNiCrAlY coatings after heat treatment and isothermal oxidation. Surf. Coat. Technol. 201, 2887 (2006)
B. Gleeson, W. Wang, D.J. Sordelet High temperature coatings with Pt metal modified gamma-Ni + gamma’-Ni3Al alloy compositions. U.S. Patent No. 0229075 (2004)
B. Gleeson, B. Li, D.J. Sordelet, W.J. Brindley Methods for making high-temperature coatings having Pt metal modified gamma-Ni + gamma’-Ni3Al alloy compositions and a reactive element. U.S. Patent No. 0127695 (2006)
B.A. Nagaraj, W.B. Connor, R.W. Jendrix, D.J. Wortman, L.W. Plemmons Platinum, rhodium, or palladium protective coatings in thermal barrier coating systems. U.S. Patent No. 5427866 (1995)
D.S. Rickerby, S.R. Bell, R.G. Wing Method of applying a thermal barrier coating to a superalloy article and a thermal barrier coating. U.S. Patent No. 5667663 (1997)
B.A. Pint The role of chemical composition on the oxidation performance of aluminide coatings. Surf. Coat. Technol. 188–189, 71 (2004)
Y. Zhang, B.A. Pint, J.A. Haynes, I.G. Wright A platinum-enriched γ + γ’ two-phase bond coat on Ni-based superalloys. Surf. Coat. Technol. 200, 1259 (2005)
J.A. Haynes, B.A. Pint, Y. Zhang, I.G. Wright Comparison of the cyclic oxidation behavior of ß-NiAl, ß-NiPtAl and γ-γ’ NiPtAl coatings on various superalloys. Surf. Coat. Technol. 202, 730 (2007)
J.A. Haynes, B.A. Pint, Y. Zhang, I.G. Wright The effect of Pt content on γ-γ’ NiPtAl coatings. Surf. Coat. Technol. 203, 413 (2008)
Y. Zhang, J.P. Stacy, B.A. Pint, J.A. Haynes, B.T. Hazel, B.A. Nagaraj Interdiffusion behavior of Pt-diffused γ + γ’ coatings on Ni-based superalloys. Surf. Coat. Technol. 203, 417 (2008)
J.A. Haynes, B.A. Pint, Y. Zhang, I.G. Wright Comparison of the oxidation behavior of ß and ?-?’ NiPtAl coatings. Surf. Coat. Technol. 204, 816 (2009)
V. Deodeshmukh, N. Mu, B. Li, B. Gleeson Hot corrosion and oxidation behavior of a novel Pt + Hf-modified γ’-Ni3Al + γ-Ni-based coating. Surf. Coat. Technol. 201, 3836 (2006)
V. Deodeshmukh, B. Gleeson Evaluation of the hot corrosion resistance of commercial ß-NiAl and developmental γ’-Ni3Al + γ-Ni-based coatings. Surf. Coat. Technol. 202, 643 (2007)
Y. Zhang, D.A. Ballard, J.P. Stacy, B.A. Pint, J.A. Haynes Synthesis and oxidation behavior of platinum-enriched γ + γ’ bond coatings on Ni-based superalloys. Surf. Coat. Technol. 201, 3857 (2006)
J.P. Stacy, Y. Zhang, B.A. Pint, J.A. Haynes, B.T. Hazel, B.A. Nagaraj Synthesis and oxidation performance of Al-enriched γ + γ’ bond coatings on Ni-based superalloys via secondary aluminizing. Surf. Coat. Technol. 202, 632 (2007)
B. Gleeson, W. Wang, S. Hayashi, D.J. Sordelet Effects of platinum on the interdiffusion and oxidation behavior of Ni–Al-based alloys. Mater. Sci. Forum 461–464, 213 (2004)
J.X. Yang, Q. Zheng, X.F. Sun, H.R. Guan, Z.Q. Hu Topologically close-packed phase precipitation in a nickel-base superalloy during thermal exposure. Mater. Sci. Eng., A 465, 100 (2007)
A.C. Yeh, S. Tin Effects of Ru on the high-temperature phase stability of Ni-base single-crystal superalloys. Metall. Mater. Trans. A 37, 2621 (2006)
J.D. Nystrom, T.M. Pollock, Y.M.H. Murphy, A. Garg Discontinuous cellular precipitation in a high-refractory nickel-based superalloy. Metall. Mater. Trans. A 28, 2443 (1997)
Y.H. Zhang, D.M. Knowles, P.J. Withers Microstructural development in Pt-aluminide coating on CMSX-4 superalloy during TMF. Surf. Coat. Technol. 107, 76 (1998)
C.T. Sims, N.S. Stoloff, W.C. Hagel Superalloys II (Wiley, New York 1986)
U. Hemmersmeier, M. Feller-Kniepmeier Element distribution in the macro- and microstructure of nickel base superalloy CMSX-4. Mater. Sci. Eng., A 248, 87 (1998)
C. Schulze, M. Feller-Kniepmeier Transmission electron microscopy of phase composition and lattice misfit in the Re-containing nickel-base superalloy CMSX-10. Mater. Sci. Eng., A 281, 204 (2000)
P.A. Carvalho, H.S.D. Haarsma, B.J. Kooi, P.M. Bronsveld, De J. HossonTh.M. HRTEM study of Co7W6 and its typical defect structure. Acta Mater. 48, 2703 (2000)
C.M.F. Rae, R.C. Reed The precipitation of topologically closed-packed phase in rhenium containing superalloys. Acta Mater. 49, 4113 (2001)
P.A. Carvalho, De J. HossonTh.M. Stacking faults in the Co7W6 isomorph of the µ phase. Scr. Mater. 45, 333 (2001)
J. Zhu, H.Q. Ye On the microstructure and its diffraction anomaly of the µ phase in superalloys. Scr. Metall. Mater. 24, 1861 (1990)
S.J. Andersson Structure related to the ß-tungsten or Cr3Si structure type. J. Solid State Chem. 23, 191 (1978)
P.A. Carvalho, P.M. Bronsveld, B.J. Kooi, De J. HossonTh.M. On the fcc ? DO19 transformation in Co–W alloys. Acta Mater. 50, 4511 (2002)
A.K. Jena, M.C. Chaturvedi The role of alloying elements in the design of nickel-base superalloy. J. Mater. Sci. 19, 3121 (1984)
M. Simonetti, P. Caron Role and behavior of µ phase during deformation of a nickel-based single crystal superalloy. Mater. Sci. Eng., A 254, 1 (1998)
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Cao, G., Ou, T., Jiang, H. et al. Microstructure investigations of Pt-modified γ’-Ni3Al + γ-Ni coatings on Ni-based superalloys. Journal of Materials Research 25, 1191–1195 (2010). https://doi.org/10.1557/JMR.2010.0148
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DOI: https://doi.org/10.1557/JMR.2010.0148