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Microstructure investigations of Pt-modified γ’-Ni3Al + γ-Ni coatings on Ni-based superalloys

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Abstract

The microstructure of Pt-modified γ’-Ni3Al + γ-Ni coating on CMSX-4 single-crystal superalloy has been investigated by transmission electron microscopy (TEM). Cross-sectional TEM analyses showed the presence of precipitates in the coating. This precipitate was identified as the hexagonal topologically close-packed (TCP) µ phase with lattice parameters a = 0.473 nm and c = 2.565 nm. The energy-dispersive x-ray (EDX) spectrum of the µ phase suggested a refractory element rich compound comprising the elements Re, W, and Co. Twin domains parallel to (001) were found in the µ phase. The mechanisms of the µ phase and twinning formation were discussed.

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References

  1. B. Gleeson Thermal-barrier coatings for aeroengine applications. J. Propul. Power 22, 375 (2006)

    Article  CAS  Google Scholar 

  2. G.W. Goward Progress in coatings for gas turbine airfoils. Surf. Coat. Technol. 108–109, 73 (1998)

    Article  Google Scholar 

  3. B.A. Pint, K.L. More Characterization of alumina interfaces in TBC systems. J. Mater. Sci. 44, 1676 (2009)

    Article  CAS  Google Scholar 

  4. N.P. Padture, M. Cell, E.H. Jordan Thermal-barrier coatings for gas-turbine engine applications. Science 296, 280 (2002)

    Article  CAS  Google Scholar 

  5. D.R. Clarke, C.G. Levi Materials design for the next generation thermal barrier coating. Annu. Rev. Mater. Res. 33, 383 (2003)

    Article  CAS  Google Scholar 

  6. M.W. Chen, M.L. Glynn, R.T. Ott, T.C. Hufnagel, K.L. Hemker Characterization and modeling of a martensitic transformation in a platinum modified diffusion aluminide bond coat for thermal-barrier coatings. Acta Mater. 51, 4279 (2003)

    Article  CAS  Google Scholar 

  7. T.M. Pollock, S. Tin Nickel-based superalloys for advanced turbine engines: Chemistry, microstructure, and properties. J. Propul. Power 22, 361 (2006)

    Article  CAS  Google Scholar 

  8. P. Poza, P.S. Grant Microstructure evolution of vacuum plasma sprayed CoNiCrAlY coatings after heat treatment and isothermal oxidation. Surf. Coat. Technol. 201, 2887 (2006)

    Article  CAS  Google Scholar 

  9. B. Gleeson, W. Wang, D.J. Sordelet High temperature coatings with Pt metal modified gamma-Ni + gamma’-Ni3Al alloy compositions. U.S. Patent No. 0229075 (2004)

    Google Scholar 

  10. B. Gleeson, B. Li, D.J. Sordelet, W.J. Brindley Methods for making high-temperature coatings having Pt metal modified gamma-Ni + gamma’-Ni3Al alloy compositions and a reactive element. U.S. Patent No. 0127695 (2006)

    Google Scholar 

  11. B.A. Nagaraj, W.B. Connor, R.W. Jendrix, D.J. Wortman, L.W. Plemmons Platinum, rhodium, or palladium protective coatings in thermal barrier coating systems. U.S. Patent No. 5427866 (1995)

    Google Scholar 

  12. D.S. Rickerby, S.R. Bell, R.G. Wing Method of applying a thermal barrier coating to a superalloy article and a thermal barrier coating. U.S. Patent No. 5667663 (1997)

    Google Scholar 

  13. B.A. Pint The role of chemical composition on the oxidation performance of aluminide coatings. Surf. Coat. Technol. 188–189, 71 (2004)

    Article  Google Scholar 

  14. Y. Zhang, B.A. Pint, J.A. Haynes, I.G. Wright A platinum-enriched γ + γ’ two-phase bond coat on Ni-based superalloys. Surf. Coat. Technol. 200, 1259 (2005)

    Article  CAS  Google Scholar 

  15. J.A. Haynes, B.A. Pint, Y. Zhang, I.G. Wright Comparison of the cyclic oxidation behavior of ß-NiAl, ß-NiPtAl and γ-γ’ NiPtAl coatings on various superalloys. Surf. Coat. Technol. 202, 730 (2007)

    Article  CAS  Google Scholar 

  16. J.A. Haynes, B.A. Pint, Y. Zhang, I.G. Wright The effect of Pt content on γ-γ’ NiPtAl coatings. Surf. Coat. Technol. 203, 413 (2008)

    Article  CAS  Google Scholar 

  17. Y. Zhang, J.P. Stacy, B.A. Pint, J.A. Haynes, B.T. Hazel, B.A. Nagaraj Interdiffusion behavior of Pt-diffused γ + γ’ coatings on Ni-based superalloys. Surf. Coat. Technol. 203, 417 (2008)

    Article  CAS  Google Scholar 

  18. J.A. Haynes, B.A. Pint, Y. Zhang, I.G. Wright Comparison of the oxidation behavior of ß and ?-?’ NiPtAl coatings. Surf. Coat. Technol. 204, 816 (2009)

    Article  CAS  Google Scholar 

  19. V. Deodeshmukh, N. Mu, B. Li, B. Gleeson Hot corrosion and oxidation behavior of a novel Pt + Hf-modified γ’-Ni3Al + γ-Ni-based coating. Surf. Coat. Technol. 201, 3836 (2006)

    Article  CAS  Google Scholar 

  20. V. Deodeshmukh, B. Gleeson Evaluation of the hot corrosion resistance of commercial ß-NiAl and developmental γ’-Ni3Al + γ-Ni-based coatings. Surf. Coat. Technol. 202, 643 (2007)

    Article  CAS  Google Scholar 

  21. Y. Zhang, D.A. Ballard, J.P. Stacy, B.A. Pint, J.A. Haynes Synthesis and oxidation behavior of platinum-enriched γ + γ’ bond coatings on Ni-based superalloys. Surf. Coat. Technol. 201, 3857 (2006)

    Article  CAS  Google Scholar 

  22. J.P. Stacy, Y. Zhang, B.A. Pint, J.A. Haynes, B.T. Hazel, B.A. Nagaraj Synthesis and oxidation performance of Al-enriched γ + γ’ bond coatings on Ni-based superalloys via secondary aluminizing. Surf. Coat. Technol. 202, 632 (2007)

    Article  CAS  Google Scholar 

  23. B. Gleeson, W. Wang, S. Hayashi, D.J. Sordelet Effects of platinum on the interdiffusion and oxidation behavior of Ni–Al-based alloys. Mater. Sci. Forum 461–464, 213 (2004)

    Article  Google Scholar 

  24. J.X. Yang, Q. Zheng, X.F. Sun, H.R. Guan, Z.Q. Hu Topologically close-packed phase precipitation in a nickel-base superalloy during thermal exposure. Mater. Sci. Eng., A 465, 100 (2007)

    Article  Google Scholar 

  25. A.C. Yeh, S. Tin Effects of Ru on the high-temperature phase stability of Ni-base single-crystal superalloys. Metall. Mater. Trans. A 37, 2621 (2006)

    Article  Google Scholar 

  26. J.D. Nystrom, T.M. Pollock, Y.M.H. Murphy, A. Garg Discontinuous cellular precipitation in a high-refractory nickel-based superalloy. Metall. Mater. Trans. A 28, 2443 (1997)

    Article  Google Scholar 

  27. Y.H. Zhang, D.M. Knowles, P.J. Withers Microstructural development in Pt-aluminide coating on CMSX-4 superalloy during TMF. Surf. Coat. Technol. 107, 76 (1998)

    Article  CAS  Google Scholar 

  28. C.T. Sims, N.S. Stoloff, W.C. Hagel Superalloys II (Wiley, New York 1986)

    Google Scholar 

  29. U. Hemmersmeier, M. Feller-Kniepmeier Element distribution in the macro- and microstructure of nickel base superalloy CMSX-4. Mater. Sci. Eng., A 248, 87 (1998)

    Article  Google Scholar 

  30. C. Schulze, M. Feller-Kniepmeier Transmission electron microscopy of phase composition and lattice misfit in the Re-containing nickel-base superalloy CMSX-10. Mater. Sci. Eng., A 281, 204 (2000)

    Article  Google Scholar 

  31. P.A. Carvalho, H.S.D. Haarsma, B.J. Kooi, P.M. Bronsveld, De J. HossonTh.M. HRTEM study of Co7W6 and its typical defect structure. Acta Mater. 48, 2703 (2000)

    Article  CAS  Google Scholar 

  32. C.M.F. Rae, R.C. Reed The precipitation of topologically closed-packed phase in rhenium containing superalloys. Acta Mater. 49, 4113 (2001)

    Article  CAS  Google Scholar 

  33. P.A. Carvalho, De J. HossonTh.M. Stacking faults in the Co7W6 isomorph of the µ phase. Scr. Mater. 45, 333 (2001)

    Article  CAS  Google Scholar 

  34. J. Zhu, H.Q. Ye On the microstructure and its diffraction anomaly of the µ phase in superalloys. Scr. Metall. Mater. 24, 1861 (1990)

    Article  CAS  Google Scholar 

  35. S.J. Andersson Structure related to the ß-tungsten or Cr3Si structure type. J. Solid State Chem. 23, 191 (1978)

    Article  CAS  Google Scholar 

  36. P.A. Carvalho, P.M. Bronsveld, B.J. Kooi, De J. HossonTh.M. On the fcc ? DO19 transformation in Co–W alloys. Acta Mater. 50, 4511 (2002)

    Article  CAS  Google Scholar 

  37. A.K. Jena, M.C. Chaturvedi The role of alloying elements in the design of nickel-base superalloy. J. Mater. Sci. 19, 3121 (1984)

    Article  CAS  Google Scholar 

  38. M. Simonetti, P. Caron Role and behavior of µ phase during deformation of a nickel-based single crystal superalloy. Mater. Sci. Eng., A 254, 1 (1998)

    Article  Google Scholar 

Download references

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Correspondence to Guanghui Cao.

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Cao, G., Ou, T., Jiang, H. et al. Microstructure investigations of Pt-modified γ’-Ni3Al + γ-Ni coatings on Ni-based superalloys. Journal of Materials Research 25, 1191–1195 (2010). https://doi.org/10.1557/JMR.2010.0148

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  • DOI: https://doi.org/10.1557/JMR.2010.0148

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