Skip to main content
Log in

Characteristics of copper indium diselenide nanowires embedded in porous alumina templates

  • Article
  • Published:
Journal of Materials Research Aims and scope Submit manuscript

Abstract

Vertically aligned nanowire arrays of copper indium diselenide (CuInSe2 or CIS) of controllable diameter and length were fabricated by simultaneously electrodepositing Cu, In, and Se from an acid bath into the pores of anodized aluminum oxide (AAO) formed on top of an aluminum sheet. X-ray diffraction measurements revealed a preferential [112] orientation and the energy dispersive x-ray analysis (EDX) measurements indicated an overall composition close to stoichiometric CuInSe2. Ohmic contact to CIS was formed by depositing a 100 nm thick of gold layer on top, and thus a Schottky diode device of the Au/CIS nanowires/Al configuration was obtained. Analysis of the current–voltage characteristics of these devices yielded diode ideality factor and reverse saturate current density values slightly higher than those reported in the literature for bulk CIS/Al junctions. Capacitance–voltage measurements were performed on the diodes to get the estimates of space charge density and the junction potential.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. I. Repins, M.A. Contreras, B. Egaas, C. DeHart, J. Scharf, C.L. Perkins, B. To, R. Noufi 19.9%-efficient ZnO/CdS/CuInGaSe2 solar cell with 81.2% fill factor. Prog. Photovoltaics Res. Appl. 16, 235 (2008)

    Article  CAS  Google Scholar 

  2. J.D. Beach, B.E. McCandless Materials challenges for CdTe and CuInSe2 photovoltaics. MRS Bull. 32, (3) 225 (2007)

    Article  CAS  Google Scholar 

  3. K. Ramanathan, M.A. Contreras, C.L. Perkins, S. Asher, F.S. Hasoon, J. Keane, D. Young, M. Romero, W. Metzger, R. Noufi, J. Ward, A. Duda Properties of 19.2% efficiency ZnO/CdS/CuInGaSe2 thin-film solar solar cells. Prog. Photovoltaics Res. Appl. 11, 225 (2003)

    Article  CAS  Google Scholar 

  4. R.N. Bhattacharya Electrodeposition of CIGS for Solar Cells. NREL Technical Report, No. NREL/TP-590-32775, October 2002 http://www1.eere.energy.gov/solar/quantum_efficiency.html

    Google Scholar 

  5. A.R. Rocket, R.W. Birkmire CuInSe2 for photovoltaic applications. J. Appl. Phys. 70, R81 (1991)

    Article  Google Scholar 

  6. V.P. Singh, S. Rajaputra, P. Liu, S. Phok, S. Guduru Fabrication and characterization of CdS/CIS nanowire heterojunctions. Proceedings, 33rd IEEE-Photovoltaic Specialists Conference May 11–14 2008 San Diego, CA

    Google Scholar 

  7. S. Phok, S. Rajaputra, V.P. Singh Copper indium diselenide nanowire arrays by electrodeposition in porous alumina templates. Nanotechnology 18, 475601 (2007)

    Article  Google Scholar 

  8. A. Aguilera, V. Jayaraman, S. Sanagapalli, Suresh R. Singh, V. Jayaraman, K. Sampson, V.P. Singh Porous alumina templates and nanostructured CdS for thin film solar cell applications. Sol. Energy Mater. Sol. Cells 90, 713 (2006)

    Article  CAS  Google Scholar 

  9. V.P. Singh, S. Rajaputra, K.E. Sampson Nanostructured Materials for Solar Energy Conversion edited by T. Soga (Elsevier, B.V., Amsterdam, The Netherlands 2006) 167

  10. Y. Cui, X. Duan, J. Hu, C.M. Lieber Doping and electrical transport in silicon nanowires. J. Phys. Chem. B 104, 5213 (2000)

    Article  CAS  Google Scholar 

  11. S-Z Chu, K. Wada, S. Inoue, S. Todoroki Fabrication and characteristics of ordered Ni nanostructures on glass by anodization and direct current electrodeposition. Chem. Mater. 14, 4595 (2002)

    Article  CAS  Google Scholar 

  12. A. Srivastava, R.S. Singh, K.E. Sampson, V.P. Singh, R.V. Ramanujan Templated assembly of magnetic cobalt nanowire arrays. Metall. Mater. Trans. A 38, 717 (2007)

    Article  Google Scholar 

  13. C. Xu, H. Li, G. Zhao, H. Li Electrodeposition and magnetic properties of Ni nanowire arrays on anodic aluminum oxide/Ti/Si substrate. Appl. Surf. Sci. 253, 1399 (2006)

    Article  CAS  Google Scholar 

  14. H. Matsushita, Y. Tojo, T. Takizaw Schottky properties of CuInSe2 single crystals grown by the horizontal Bridgman method with controlling Se vapor pressure. J. Phys. Chem. Solids 64, 1825 (2003)

    Article  CAS  Google Scholar 

  15. R.P. Raffaelle, J.G. Mantovani, S.G. Bailey, A.F. Hepp, E.M. Gordon, R. Haraway NASA Report, TM-97-206322 (1997)

    Google Scholar 

  16. K. Nielsch, F. Muller, A-P Li, U. Gosele Uniform nickel deposition into ordered alumina pores by pulsed electrodeposition. Adv. Mater. 12, (8) 582 (2000)

    Article  CAS  Google Scholar 

  17. Y. Shi, Z. Jin, C. Li, H. An, J. Qiu Effects of post-heat treatment on the characteristics of chalcopyrite CuInSe2 film deposited by successive ionic layer absorption and reaction method. Thin Solid Films 515, (7-8) 3339 (2007)

    Article  CAS  Google Scholar 

  18. S.M. Sze Physics of Semiconductor Devices (John Wiley & Sons, New York, NY 1981) 81

    Google Scholar 

  19. Y. Sudo, S. Endo, T. Irie Preparation and characterization of electrodeposited CuInSe2 thin films. Jpn. J. Appl. Phys. 32, 1562 (1993)

    Article  CAS  Google Scholar 

  20. C-J Huang, Y-K Su, K-L Chen, M.Y. Lai Characteristics of copper indium diselenide thin films formed on flexible substrates by electrodeposition. Jpn. J. Appl. Phys. 44, 7795 (2005)

    Article  CAS  Google Scholar 

  21. H.M. Moller Semiconductors for Solar Cells (Artech House, Boston, MA 1993)

    Google Scholar 

  22. S.M. Sze Physics of Semiconductor Devices (John Wiley & Sons, New York, NY 1981) 17–27

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Vijay P. Singh.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Liu, P., Singh, V.P., Rajaputra, S. et al. Characteristics of copper indium diselenide nanowires embedded in porous alumina templates. Journal of Materials Research 25, 207–212 (2010). https://doi.org/10.1557/JMR.2010.0030

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/JMR.2010.0030

Navigation