Abstract
We report a novel finding of slither propagation of shear bands on the fracture surface of a Cu47.5Zr47.5Al5 bulk metallic glass (BMG). The nanoscale heterogeneities in the as-cast state are aggregated along shear bands with irregular morphology. Such heterogeneities create a fluctuating stress field during shear band propagation leading to a slither propagation mode. The slither propagation of 10 to 15 nm wide shear bands is effective to improve both the plasticity and the “work-hardening-like” behavior of BMGs if the size, the morphology, and the elastic properties of the heterogeneities are intimately intercalated during solidification.
Similar content being viewed by others
References
F. Spaepen: Microscopic mechanism for steady-state inhomogeneous flow in metallic glasses. Acta Metall. 25, 407 1977
A.S. Argon: Plastic deformation in metallic glasses. Acta Metall. 27, 47 1979
A.L. Greer: Metallic glasses. Science 267, 1947 1995
W.L. Johnson: Bulk glass-forming metallic alloys: Science and technology. MRS Bull. 24, 42 1999
L.Q. Xing, Y. Li, K.T. Ramesh, J. Li T.C. Hufnagel: Enhanced plastic strain in Zr-based bulk amorphous alloys. Phys. Rev. B 64, 180201 2001
A. Inoue, W. Zhang, T. Zhang K. Kurosaka: High-strength Cu-based bulk glassy alloys in Cu–Zr–Ti and Cu–Hf–Ti ternary systems. Acta Mater. 49, 2645 2001
J. Schroers W.L. Johnson: Ductile bulk metallic glass. Phys. Rev. Lett. 93, 255506 2004
J. Das, M.B. Tang, K.B. Kim, R. Theissmann, F. Baier, W.H. Wang J. Eckert: “Work-hardenable” ductile bulk metallic glass. Phys. Rev. Lett. 94, 205501 2005
X.K. Xi, D.Q. Zhao, M.X. Pan, W.H. Wang, Y. Wu J.J. Lewandowski: Fracture of brittle metallic glasses: brittleness or plasticity. Phys. Rev. Lett. 94, 125510 2005
H. Kato, A. Inoue J. Saida: Influence of hydrostatic pressure during casting on as cast structure and mechanical properties in Zr65Al7.5Ni10Cu17.5−xPdx (x = 0, 17.5) alloys. Scripta Mater. 51, 1063 2004
W.L. Johnson K. Samwer: A universal criterion for plastic yielding of metallic glasses with a (T/Tg)2/3 temperature dependence. Phys. Rev. Lett. 95, 195501 2005
K.B. Kim, J. Das, S. Venkataraman, S. Yi J. Eckert: Work hardening ability of ductile Ti45Cu40Ni7.5Zr5Sn2.5 and Cu47.5Zr47.5Al5 bulk metallic glasses. Appl. Phys. Lett. 89, 071908 2006
J.J. Lewandowski, W.H. Wang A.L. Greer: Intrinsic plasticity or brittleness of metallic glasses. Philos. Mag. Lett. 85, 77 2005
J. Saida, A.D. Setyawan, H. Kato A. Inoue: Nanoscale multistep shear band formation by deformation-induced nanocrystallization in Zr–Al–Ni–Pd bulk metallic glass. Appl. Phys. Lett. 87, 151907 2005
A. Inoue, W. Zhang, T. Tsurui, A.R. Yavari A.L. Greer: Unusual room-temperature compressive plasticity in nanocrystal-toughened bulk copper-zirconium glass. Philos. Mag. Lett. 85, 221 2005
Q. Cao, J. Li, Y. Zhou J.Z. Jiang: Mechanically driven phase separation and corresponding microhardness change in Cu60Zr20Ti20 bulk metallic glass. Appl. Phys. Lett. 86, 081913 2005
K.B. Kim, J. Das, X.D. Wang, Z.F. Zhang, J. Eckert S. Yi: Effect of Sn on microstructure and mechanical properties of (Ti-Cu)-based bulk metallic glasses. Philos. Mag. Lett. 86, 479 2006
K.B. Kim, J. Das J. Eckert: Unpublished works
D.M. Mueth, G.F. Debregeas, G.S. Karczmar, P.J. Eng, S.R. Nagel H.M. Jaeger: Signatures of granular microstructure in dense shear flows. Nature 406, 385 2000
G. Porte, J-F. Berret J.L. Harden: Inhomogeneous flows of complex fluids: Mechanical instability versus non-equilibrium phase transition. J. Phys. II France 7, 459 1997
J. Tung, R.K. Gupta, G.P. Simon, G.H. Edward S.N. Bhattacharya: Rheological and mechanical comparative study of in situ polymerized and melt-blended nylon 6 nanocomposites. Polymer 46, 10405 2005
S.D. Papka S. Kyriakides: Biaxial crushing of honeycombs: Part 1. Exp. Int. J. Solids Struct. 36, 4367 1999
J. Li, F. Spaepen T.C. Hufnagel: Nano-scale defects in shear bands in a metallic glass. Philos. Mag. A 82, 2623 2002
P.E. Donovan W.M. Stobbs: The structure of shear bands in metallic glasses. Acta Metall. 29, 1419 1981
A.S. Argon: Mechanisms of inelastic deformation in metallic glasses. J. Phys. Chem. Solids 43, 945 1982
J. Das, K.B. Kim, W. Xu, B.C. Wei, Z.F. Zhang, W.H. Wang, S. Yi J. Eckert: Ductile metallic glasses in supercooled martensitic alloys. Mater. Trans. 37, 2606 2006
Acknowledgments
This work was supported by the European Union within the framework of the Research Training Network on ductile bulk metallic glass composites (MRTN-CT-2003-504692) and by the Center for Nanostructured Materials Technology (Grant 05K1501-00410) under the 21st Century Frontier R&D Program by of the Korea Ministry of Science and Technology, the Korean Ministry of Commerce, Industry and Energy for the development of structural metallic materials as well as by the Natural Science Foundation of China (Grant Nos. 50321101, 50401019, and 50323009), and the Korea Science and Engineering Foundation (KOSEF) grant funded by the Korea government (MOST) (ROI-2007-000-10549-0), and the Hundred of Talents Project by the Chinese Academy of Sciences.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Kim, K., Das, J., Lee, M. et al. Propagation of shear bands in a Cu47.5Zr47.5Al5 bulk metallic glass. Journal of Materials Research 23, 6–12 (2008). https://doi.org/10.1557/JMR.2008.0025
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/JMR.2008.0025