Abstract
Large-scale single-crystal cubic PbS nanorods were successfully achieved by using ultrasound irradiation in certain ethylenediamine tetraacetic acid (EDTA) solutions, particularly in the solution of Pb:EDTA = 1:1. The obtained PbS nanorods were characterized using x-ray diffraction, scanning electron microscopy, transmission electron microscopy, energy-dispersed x-ray spectrometry, selected area electronic diffraction, and high-resolution transmission electron microscopy. The results reveal that the PbS nanorods with straight and uniform structure have a diameter of about 70–80 nm and length of about 1000 nm, where the growth mechanism is tentatively discussed. The successful synthesis of these cubic structure semiconductor PbS nanorods may open up new possibilities for using these materials as building blocks to create functional two-dimensional or three-dimensional nanostructured materials.
Similar content being viewed by others
References
D.J. Hornbaker, S-J. Kahng, S. Misra, B.W. Smith, A.T. Johnson, E.J. Mele, D.E. Luzzi, A. Yazdani, Science 295, 828 (2002).
J. Machol, F. Wise, R. Patel, and D. Tanner, Phys. Rev. B 48, 2819 (1993).
A.A. Patel, F. Wu, J. Zhang, C. Martinez, R. Mehra, Y. Yang, and S. Risbud, J. Phys. Chem. B 104, 11598 (2000).
R. Kane, R. Cohen, and R. Silbey, J. Phys. Chem. 100, 7928 (1996).
M. Nogami, K. Nagasaka, and K. Kotani, J. Non-Cryst. Solids 126, 87 (1990).
S. Chen, L. Truax, and J. Sommers, Chem. Mater. 12, 3864 (2000).
M. Gao, Y. Yang, B. Yang, F. Bian, and J. Shen, Chem. Commun. 10, 2779 (1994).
W. Hergeth, W. Lebek, R. Kakusehke, and K. Schmutzer, Makromol. Chem. 192, 2265 (1991).
J. Zeng, Y. Zhu, J. Yang, Y. Liu, and T. Qian, Chem. Lett. 10, 1000 (2001).
Ultrasound: Its Chemical, Physical and Biological Effects, edited by K.S. Suslick (VCH, Weinheim, Germany, 1988).
G. Wang, G. Li, C. Liang, and L. Zhang, Chem. Lett. 4, 344 (2001).
S. Nikitenko, Y. Koltypin, Y. Mastai, M. Koltypin, and A. Gedanken, J. Mater. Chem. 12, 1450 (2002).
J. Zhu, Q. Qiu, H. Wang, J. Zhang, J. Zhu, and Z. Chen, Inorg. Chem. Commun. 5, 242 (2002).
H. Wang, J. Zhu, J. Zhu, and H. Chen, J. Phys. Chem. B 106, 3848 (2002).
JCPDS Card File No. 5–592 (International Centre for Diffraction Data, Newton Square, PA, 1999).
K. Okitsu, Y. Mizukoshi, H. Bandow, Y. Maedu, T. Yamamoto, and Y. Nagata, Ultrason. Sonochem. 3, S249 (1996).
J. Belloni, Radiat. Res. 150, S9 (1998).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Zhou, S.M., Feng, Y.S. & Zhang, L.D. Sonochemical synthesis of large-scale single-crystal PbS nanorods. Journal of Materials Research 18, 1188–1191 (2003). https://doi.org/10.1557/JMR.2003.0163
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/JMR.2003.0163