Abstract
A hydrothermal route was proposed to prepare and control nanocrystalline silver indium sulfides (orthorhombic AgInS2, tetragonal AgInS2, and cubic AgIn5S8). The reaction was carried out in an autoclave in the temperature range of 100–280 °C with AgCl, InCl3, and thiourea as reactants. X-ray powder diffraction patterns and transmission electron microscopy images showed that the products were AgInS2 and AgIn5S8 phases and well crystallized with grain diameter in the range of 20–70 nm. X-ray photoelectron spectra of the single AgIn5S8 phase revealed the surface stoichiometry (AgIn5.05S8.11), and its room temperature Raman spectrum showed a strong peak at 130 cm−1 and a weak peak at around 290 cm−1. The influence of reaction temperature on the phases in the final products was investigated. A possible reaction mechanism of the formation of silver indium sulfides was also briefly discussed.
Similar content being viewed by others
References
C. Paorici, L. Zanotti, N. Romeo, G. Sberveglieri, and L. Tarricone, Mater. Res. Bull. 12, 1207 (1977).
A. F. Wells, Structure Inorganic Chemistry, 3rd ed. (Clarendon Press, Oxford, United Kingdom, 1967), p. 214.
K. Okamoto and K. Kinoshite, Solid-State Electron. 19, 31 (1976).
R. S. Roth, H. S. Parker, and W. S. Brower, Mater. Res. Bull. 8, 333 (1973).
M. Górska, R. Beaulieu, J. J. Lofferski, and B. Roessler, Thin Solid Films 67, 341 (1980).
Y. Ueno, Y. Hattori, M. Ito, T. Sugiura, and H. Minoura, Sol. En-ergy Mater. Sol. Cells 26, 229 (1992).
F. F. Lange, Science 273, 903 (1996).
W.S. Sheldrich and M. Wachhold, Angew. Chem., Int. Ed. Engl. 36, 206 (1997).
J. Q. Hu, Q. Y. Lu, K. B. Tang, Y. T. Qian, G. E. Zhou, and X. M. Liu, Chem. Commun. 1093 (1999).
M. Rozman and M. Drofenik, J. Am. Chem. Soc. 78, 2449 (1995).
J. Moon, T. Li, C. A. Randall, and J. H. Adair, J. Mater. Res. 12, 189 (1997).
Y. D. Li, X. F. Duan, H. W. Liao, and Y. T. Qian, Chem. Mater. 1, 1 (1998).
Powder Diffraction File No. 25–1330, International Centre for Diffraction Data, Swarthmore, PA.
J. F. Moulder, W. F. Stickle, P. E. Sobol, and K. D. Bomben, in Handbook of X-ray Photoelectron Spectroscopy, edited by J. Chastain, Physical Electronics Division, Perkin-Elmer Corpo-ration, Eden Prarie, MN, (1992), p. 231.
N. M. Gasanly, A. Z. Magomedov, N. N. Melnik, and B. G. Salamov, Phys. Status Solidi B 177, K31 (1993).
M. M. Sinha, P. Ashdhir, H. C. Gupta, and B. B. Tripathi, Phys. Status Solidi B 187, K33 (1995).
R.G. Vranka and E. L. Amma, J. Am. Chem. Soc. 88, 4270 (1966).
A. G. Gash, E. H. Griffith, W. A. Spofford, and E. L. Amma, J. Chem. Soc., Chem. Commun. 256 (1973).
N. N. Golovnev, A. S. Primakov, and I. I. Gologneva, Zh. Neorg. Khim. 40, 973 (1995).
R. C. Bott, G. A. Bowmaker, C. A. Davis, G. A. Hope, and B. E. Jones, Inorg. Chem. 37, 651 (1998).
I.V. Mironov and L. D. Tsvelodub, J. Appl. Spectroscopy 64, 470 (1998).
F. Z. EI Aamrani, J. Garcia-Raurich, A. Sastre, L. Beyer, and A. Florido, Anal. Chim. Acta 402, 129 (1999).
G.E. Kitaev and T. P. Sokolva, Russ. J. Inorg. Chem. 15, 167 (1970).
I. K. Ostrovskaya, G. A. Kitaev, and A. A. Velijanov, Russ. J. Phys. Chem. 50, 956 (1976).
S. H. Yu, L. Shu, J. Yang, Z. H. Han, Y. T. Qian, and Y. H. Zhang, J. Mater. Res. 14, 4157 (1999).
J.M. Guilemany, J. Nutting, and N. Llorca-Isern, J. Therm. Spray Technol. 5, 483 (1996).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Hu, J.Q., Deng, B., Tang, K.B. et al. Preparation and phase control of nanocrystalline silver indium sulfides via a hydrothermal route. Journal of Materials Research 16, 3411–3415 (2001). https://doi.org/10.1557/JMR.2001.0469
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/JMR.2001.0469