Abstract
Single-crystal thulium phosphide (TmP) was grown heteroepitaxially on (001) GaAs substrates by molecular beam epitaxy with the orientation relationship [100]TmP//[100]GaAs and {001}TmP//{001}GaAs. The crystal properties and the defects in TmP/GaAs, GaAs/TmP/GaAs heterostructure were characterized through x-ray diffraction, atomic force microscopy, and transmission electron microscopy. TmP was found to have a huge difference in thermal expansion coefficient compared GaAs, which produced high tensile residual stress and may result in the formation of defects. The major defects in the top GaAs layer are stacking faults or microtwins, and they directly correlated with the islandlike surface morphology of the GaAs overlayer. The composition profiles of the TmP/GaAs heterostructure were measured by secondary ion mass spectrometry. The reason for surface segregation of Tm and Ga atoms is discussed and is primarily due to their higher diffusion coefficient near the surface as compared to that in the TmP epilayer bulk. The thermally stable characters of the TmP/GaAs heterostructures allow them to be promising candidates in various device applications.
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A.L. Corre, B. Guenais, A. Guivarc’h, D. Lecrosnier, J. Caulet, M. Minier, G. Ropars, P.A. Badoz, and J.Y. Duboz, J. Cryst. Growth 105, 234 (1990).
H.J. Richter, R.S. Smith, N. Herres, M. Seelmann-Eggebert, and P. Wenekors, Appl. Phys. Lett. 53, 99 (1988).
P.P. Lee, R.J. Hwu, L.P. Sadwick, H. Balasubramaniam, B.R. Kumar, R. Alvis, R.T. Lareau, and M.C. Wood, J. Electron. Mater. 27, 405 (1998).
C.H. Lin, R.J. Hwu, L.P. Sadwick, and D. Heo (unpublished).
W.G. Moffatt, The Handbook of Binary Phase Diagrams (Genium, Schenectady, New York, 1984);
F.A. Shunk, Constitution of Binary Alloys, 2nd suppl. (McGraw-Hill, New York, 1969);
R.P. Elliot, Constitution of Binary Alloys, 1st suppl. (McGraw-Hill, New York, 1965);
M. Hansen, Constitution of Binary Alloys (McGraw-Hill, New York, 1958).
C.H. Lin, R.J. Hwu, L.P. Sadwick, and D. Heo (unpublished).
A.R. Patel and S.K. Arora, J. Phys. D 7, 2301 (1974).
C.C. Desai, J.L. Rai, and A.N. Hanchinal, Surf. Technol. 21, 67 (1984).
T. Ejima, W.H. Robinson, and J.P. Hirth, J.Cryst. Growth 7, 155 (1970).
T. Soga, S. Hattori, S. Sakai, M. Takeyasu, and M. Umeno, J. Appl. Phys. 57, 4578 (1985).
D.K. Biegelsen, F.A. Ponce, A.J. Smith, and J.C. Tramontana, J. Appl. Phys. 61, 1856 (1987).
F. Ernst and P. Pirouz, J. Appl. Phys. 64, 4526 (1988).
M.R. Bennett, K.E. Singer, A.C. Wright, and Z.H. Zaafri, in Rare-Earth-Doped Semiconductors II, edited by S. Coffa, A. Polman, and R.N. Schwartz (Mater. Res. Soc. Symp. Proc. 422, Pittsburgh, PA, 1996), p. 29.
C.E.C. Wood, D. Desimone, K. Singer, and G.W. Wicks, J. Appl. Phys. 53, 4230 (1982).
A. Rockett, T.J. Drummond, J.E. Greene, and H. Morkoc, J. Appl. Phys. 53, 7085 (1982).
Y. Ota, J. Appl. Phys. 51, 1102 (1980).
M. Tabe and K. Kajiyama, Jpn. J. Appl. Phys. 22, 423 (1983).
S.A. Barnett and J.E. Greene, Surf. Sci. 151, 67 (1985).
S. Andrieu, F. Arnaud d’Avitaya, and J.C. Pfister, J. Appl. Phys. 65, 2681 (1989).
S. Hampshire, in Materials Science and Technology: A Comprehensive Treatment, edited by R.W. Cahn, P. Haasen, and E.J. Kramer (VCH, Weinheim, Germany, 1992), p. 120.
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Lin, C.H., Hwu, R.J. & Sadwick, L.P. Investigation of crystal properties of TmP/GaAs and GaAs/TmP/GaAs heterostructures grown by molecular beam epitaxy. Journal of Materials Research 16, 3266–3273 (2001). https://doi.org/10.1557/JMR.2001.0450
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DOI: https://doi.org/10.1557/JMR.2001.0450