Abstract
This paper reports on the role of boron in situ doping on enhancing crystallization of silicon germanium deposited at 400 °C and 2 torr. The dependence of growth rate on germanium content and boron concentration is investigated. The minimum boron concentration and the minimum germanium content required for crystallizing the as-grown layers is experimentally determined. The texture and grain microstructure of doped and undoped poly SiGe layers has been investigated by means of x-ray diffraction spectroscopy and transmission electron microscopy. The low deposition temperature coupled with the low tensile stress of the polycrystalline material enable postprocessing of surface micromachined microelectromechanical systems on top of standard complementry metal oxide semiconductor wafers with Al interconnects. Furthermore, the resistivity of the as-grown layers is as low as 1 mΩ cm, and hence, it can be used as a seeding layer for polycrystalline Si solar cells compatible with glass substrates.
Similar content being viewed by others
References
T. Kamins, M. Mandurah, and K. Saraswat, J. Electrochem. Soc. 125, 927 (1978).
S. Sedky, A. Witvrouw, H. Bender, and K. Baert, IEEE Trans. Electron Devices 48, 1 (2001).
A.E. Franke, D. Bilic, D.T. Chang, P.T. Jones, T.J. King, R.T. Howe, and G.C. Johnson, Post-CMOS Integration of Germanium Microstructures, Twelfth IEEE International Conference on Micro Electro Mechanical Systems, MEMS ‘99, Orlando, FL, Jan. 17-21, 1999 (IEEE, Piscataway, NJ, 1999), pp. 630-637.
T.J. King and K. Saraswat, IEEE Trans. Electron Devices 41, 1581 (1994).
H.C. Lin, T.G. Jung, H.Y. Lin, and C.Y. Chang, Appl. Phys. Lett. 65, 1700 (1994).
T.J. King, J.R. Pfiester, J.D. Short, J.P. McVittie, and K. Saraswat, IEDM Tech. Dig. 253 (1990).
T.J. King and K.C. Saraswat, J. Electrochem. Soc. 141, 2235 (1994).
T.J. King and K.C. Saraswat, IEDM Tech. Dig. 567 (1991).
D.S. Bang, M. Cao, A. Wang, and K. Saraswat, Appl. Phys. Lett. 66, 195 (1995).
T. Kamins and D. Meyer, Appl. Phys. Lett. 61, 90 (1992).
P.M. Garone, J.C. Sturm, and P.V. Schwartz, Appl. Phys. Lett. 56, 1275 (1990).
S. Sedky, A. Witvrouw, M. Caymax, A. Saerens, and P. Van Houtte, Effect of Deposition Conditions on the Structural and Mechanical Properties of Poly SiGe (Mater. Res. Soc. Symp. Proc. 609, War-rendale, PA, 2000), pp. A8.5.1-7.
S. Sedky, P. Fiorini, M. Caymax, S. Loreti, K. Baert, L. Hermans, and R. Mertens, J. Micromech. Microeng. 7, 365 (1998).
H.C. Lin, C.Y. Chang, W.C. Tsai, T.C. Chang, T.G. Jung, and H.Y. Lin, J. Electrochem. Soc. 141, 2559 (1994).
V.Z. Li, M.R. Mirabedini, R.T. Kuehn, J.J. Wortman, M.C. Öztürk D. Batchelor, K. Christensen, and D.M. Maher, Appl. Phys. Lett. 71, 3388 (1997).
H. Lin, T. Jung, H. Lin, C. Chang, T. Lei, P. Wang, R. Deng, J. Lin, and C. Chao, Appl. Phys. 74, 5395 (1993).
P. Scafidi, J. Cali, and E. Bustarret, in Polycrystalline Thin Films: Structure, Texture, Properties, and Applications II, edited by H.J. Frost, MA. Parker, C.A. Ross, and E.A. Holm (Mater. Res. Soc. Symp. Proc. 403, Pittsburgh, PA, 1996), pp. 379-384.
F. Edelman, T. Raz, Y. Komen, M. Stolzer, P. Werner, P. Zaumseil, H-J. Osten, J. Griesche, and M. Capitan, Thin Solid Films 337, 152 (1999).
A.E. Franke, D. Bilic, D. Chang, P.T. Jones, T.J. King, R.T. Howe, and G.C. Johnson, in Proceedings of the 1999 International Conference on Solid-State Sensors and Actuators, Transducers ‘99, Sendai, Japan, 1999, pp. 530-533.
A.E. Franke, Y. Jia, M.T. Wu, T.J. King, and R.T. Howe, Solid-State Sens. Actuator Workshop Techn. Dig. (June 2000), pp. 18-21.
S. Sedky, P. Fiorini, K. Baert, L. Hermans, and R. Mertens, IEEE Trans. Electron Devices 46, 675 (1999).
W. Geiger, B. Folkmer, U. Sobe, H. Sandmaier, and W. Lang, Int. Conf. Solid State Sens. Actuators 2, 1129 (1997).
M.J. Vellekoop, GW. Lubking, P.M. Sarro, and A. Venema, Sens. Actuators, A A44, 249 (1994).
H. Miura, H. Ohta, N. Okamoto, and T. Kaga, Appl. Phys. Lett. 60, 2746 (1992).
M. Cao, A.W. Wang, and K.C. Saraswat, in Process Physics and Modeling in Semiconductor Technology, edited by G.R. Srinivasan, K. Taniguichi, and C.S. Murphy, PV 93-6 (The Electrochemical Society Proceedings Series PV 93-6, Pennington, NJ, 1993), pp. 350-356.
T. Kamins, Polycrystalline Silicon for Integrated Circuit Applications (Kluwer Academic, Dordrecht, The Netherlands, 1988), Chap. 2.
S. Sedky, A. Witvrouw, and K. Baert, in The 11th International Conference on Solid State Sensors and Actuators, June 11-14, (Springer-Verlag, Munich, Germany, 2001), pp. 988-991.
T.J. King and K.C. Saraswat, IEEE Electron Device Lett. 13, 309 (1992).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Sedky, S., Witvrouw, A., Saerens, A. et al. Effect of in situ boron doping on properties of silicon germanium films deposited by chemical vapor deposition at 400 °C. Journal of Materials Research 16, 2607–2612 (2001). https://doi.org/10.1557/JMR.2001.0358
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/JMR.2001.0358