Abstract
Zinc powder reacts with equivalent elemental selenium in solvent ethylenediamine at 120 °C for 6 h to form a complex, which is converted to ZnSe nanoparticles by pyrolysis or protonization. X-ray diffraction results suggest that the as-formed products have wurtzite structure. Transmission electron microscopy observation show that particles with spherical and laminar morphology were produced by pyrolysis and protonization, respectively. The formation of ZnSe nanoparticles is also investigated by infrared and thermal analysis.
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I.P. Mcclean and C.B. Thomas, Semicond. Sci. Technol. 7, 1394 (1992).
M.G. Bawendi, D.J. Carroll, W.L. Wilson, and L.E. Brus, J. Chem. Phys. 96, 5649 (1992).
R. Rossetti, R. Hull, J.M. Gibson, and L.E. Brus, J. Chem. Phys. 82, 552 (1985).
M.A. Haase, J. Qiu, J.M. Depuydt, and H. Cheng, Appl. Phys. Lett. 59, 1272 (1991).
M.C. Harris, Y.H. Chang, Y.F. Chen, J.W. Hsu, J.M. Lin, and W.C. Chou, Appl. Phys. Lett. 70, 2413 (1997).
S.M. Stuczynski, J.G. Brennan, and M.L. Steigerwald, Inorg. Chem. 28, 4431 (1989).
J. Cheon and J.I. Zink, J. Am. Chem. Soc. 119, 3838 (1997).
B. Ludolph, M.A. Malik, P. O’Brien, and N. Revaprasadu, J. Chem. Soc. Chem. Commun. 1849 (1998).
H.C. Mctcalf, J.E. Williams, and J.F. Caskta, Modern Chemistry (Holt, Reihart, Winston, New York, 1982), p. 54.
E. Ramli, T.B. Rauchfuss, and C.L. Stern, J. Am. Chem. Soc. 112, 4043 (1990).
S. Dev, E. Ramli, T.B. Rauchfuss, and S.R. Wilson, Inorg. Chem. 30, 2514 (1991).
P.P. Paul, T.B. Rauchfuss, and S.R. Wilson, J. Am. Chem. Soc. 115, 3316 (1993).
G. Henshaw, I.P. Parkin, and G. Shaw, J. Chem. Soc. Chem. Commun. 1095 (1996).
G. Henshaw, I.P. Parkin, and G. Shaw, J. Chem. Soc. Dalton Trans. 231 (1997).
Y.D. Li, Y. Ding, and Y.T. Qian, Inorg. Chem. 37, 2344 (1998).
M.A. Hines and P. Guyot-Sionnest, J. Phys. Chem. B102, 3655 (1998).
C.B. Murray, D.J. Norris, and M.G. Bawendi, J. Am. Chem. Soc. 115, 8706 (1993).
H. Hartmann, R. Mach, and B. Selle, Current Topics in Materials Science, edited by E. Kaldis (North-Holland, New York, 1982), Vol. 9, p. 9.
A.S. Pashinkin, G.N. Tischenko, I.V. Korneeva, and V.N. Ryzhenko, Soviet Phys.-Cryst. 5, 243 (1960).
S. Dev, E. Ramli, T.B. Rauchfuss, and C.L. Stern, J. Am. Chem. Soc. 122, 6385 (1990).
A.K. Verma, T.B. Rauchfuss, and S.R. Wilson, Inorg. Chem. 34, 3072 (1995).
JCPDS Card No. 15-105.
N. Chestnoy, R. Hull, and L.E. Brus, J. Chem. Phys. 85, 2237 (1986).
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Zhan, J.H., Yang, X.G., Zhang, W.X. et al. A solvothermal route to wurtzite ZnSe nanoparticles. Journal of Materials Research 15, 629–632 (2000). https://doi.org/10.1557/JMR.2000.0093
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DOI: https://doi.org/10.1557/JMR.2000.0093