Abstract
An in situ high temperature heat treatment was used to investigate the crystallization and growth behavior of AlB2 flakes in aluminum. Aluminum samples containing 1.8% boron were heated above the liquidus and then rapidly cooled through the Al(L) + AlB12 region to avoid the formation of AlB12 crystals. Subsequently, a homogeneous distribution of high aspect ratio AlB2 flakes crystallized upon holding below the peritectic transition temperature. Growth rate in the (a) and (c) dimensions increased during elevated hold temperatures below the peritectic transition temperature. Surprisingly, faster cooling rates from above the liquidus to room temperature resulted in thinner, wider flakes. Similar to graphite this phenomenon is believed to result from a need to accommodate a changing misfit strain energy between the solidifying aluminum and the growing AlB2 flakes.
Similar content being viewed by others
References
S. V. Kamat, J. P. Hirth, and R. Mehrabian, Acta Metall. 37, 2395 (1989).
D.L. McDanels, Metall. Trans. 16A, 1105 (1985).
J. M. Papazian and P. N. Adler, Metall. Trans. 21A, 401 (1990).
S.V. Nair, J. K. Tien, and R. C. Bates, Int. Met. Rev. 30, 275 (1985).
A. Levy and J.M. Papazian, Metall. Trans. 21A, 411 (1990).
F.M. Hosking, F.F. Portillo, R. Wunderlin, and R. Mehrabian, J. Mater. Sci. 17, 477 (1982).
T. Christman, A. Needleman, and S. Suresh, Acta Metall. Mater. 37, 3029 (1989).
J. Yang, S. M. Pickard, C. Cady, A. G. Evans, and R. Mehrabian, Acta Metall. Mater. 39, 1863 (1991).
D.C. Drucker, in High Strength Materials, edited by V. Zackay (Wiley, New York, 1964), p. 795.
L.M. Brown and D. R. Clarke, Acta Metall. 23, 821 (1975).
K. Tanaka and T. Mori, Acta Metall. 18, 931 (1970).
V.C. Nardone and K. M. Prewo, Scripta Metall. 20, 43 (1986).
A. Hellawell, Prog. Mater. Sci. 15, 1 (1970).
S.Z. Lu and A. Hellawell, Metall. Trans. 18A, 1721 (1987).
S. Khan and R. Elliott, J. Mater. Sci. 29, 736 (1994).
I. Minkoff, The Physical Metallurgy of Cast Iron (John Wiley and Sons Ltd., Chischester, UK, 1983), pp. 1–60.
P.F. Wieser, C. E. Bates, and J.F. Wallace, Mechanism of Graphite Formation in Iron-Silicon-Carbon Alloys (Malleable Founders Society, Cleveland, OH, 1967), 1st ed., p. 7.
M.E. Hyman, C. McCullough, C.G. Levi, and R. Mehrabian, Metall. Trans A 22A, 1647 (1991).
J. Economy, V.I. Matkovich, and L. Wohrer, SAMPE 5, 21 (1968).
L. Wohrer, A. Wosilait, and J. Economy, SAMPE 18, 340 (1973).
V.I. Matkovich, J. Economy, and R.F. Giese, Jr., Am. Chem. Soc. 86, 2337 (1964).
V.I. Matkovich, R. F. Giese, Jr., and J. Economy, Zeitschrift fur Kristallographie 122, 108 (1965).
C. Deppisch, G. Liu, J. K. Shang, and J. Economy, Mater. Sci. Eng. A225, 153 (1997).
M. J. Koczak and M. K. Prekumar, J. Minerals, Metals, and Materials Soc. 45, 44 (1993).
L. M. Brown and K. S. Mazdiyasni, Inorg. Chem. 9, 2783 (1970).
V. A. Neronov, Powder Metall. 10, 58 (1989).
V. A. Neronov, Russ. J. Eng. Thermophys. 2, 157 (1992).
G. V. Samsonov, V. A. Neronov, and L. K. Lamikhov, J. Less Comm. Metals 67, 291 (1979).
L. F. Mondolfo, in Aluminum Alloy Structure & Properties, edited by L. F. Mondolfo (Butterworth & Co. Ltd., London, 1976), pp. 228–229.
J. Wallace, in Gray Iron News, edited by Gray Iron Founders Society (Gray Iron Founders Society, Cleveland, OH, 1960), p. 14.
D.D. Double and A. Hellawell, in The Metallurgy of Cast Iron, edited by B. Lux, I. Minkoff, and F. Mollard (Georgi Pub. Co., St. Saphorin, Switzerland, 1974), pp. 509–528.
A.A. Abdel-Hamid, S. Hamar-Thibault, and R. Hamar, J. Cryst. Growth 71, 744 (1985).
P. Hartman, in Crystal Growth: An Introduction, edited by P. Hartman, W. Bardsley, D. T.J. Hurle, and J.B. Mullin (North-Holland Publishing Co., Amsterdam, The Netherlands, 1973), pp. 367–402.
C.J. Kuehmann and P. W. Voorhees, Metall. Trans. 27A, 937 (1996).
E.J. Felton, J. Am. Chem. Soc. 78, 5977 (1956).
R.W.G. Wyckoff, in Crystal Structures: Vol. 1, 2nd Edition (John Wiley & Sons, New York, London, Sydney, 1965), pp. 362–365.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Deppisch, C., Liu, G., Hall, A. et al. The crystallization and growth of AlB2 single crystal flakes in aluminum. Journal of Materials Research 13, 3485–3498 (1998). https://doi.org/10.1557/JMR.1998.0476
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/JMR.1998.0476