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Electron microscopic interfacial analysis of diamond film grown on silicon substrate

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Abstract

We have investigated the near-interface characterization of diamond films grown on Si(100) substrates by means of a hot-filament chemical-vapor-deposition (HFCVD) method using high-resolution-electron microscopy (HREM). Atomic scale study of the diamond/Si interface reveals that on the top of the amorphous intermediate layer, there exists a precursor phase which seems to be a diamond-like structure, which provides a suitable site for subsequent diamond nucleation. High density crystal defects directly originate from the precursor phase. HREM images also reveal that during the deposition Si recrystallizes in some damaged areas left by pretreatment, such as scratching grooves. In the recrystallization process twins and microtwins can be formed, and amorphous solid is left in the Si crystals.

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References

  1. K. Kobayashi, S. Karasawa, and T. Watanabe, J. Cryst. Growth 99, 1211 (1990).

    Article  CAS  Google Scholar 

  2. B. E. Williams and J. T. Glass, J. Mater. Res. 4, 373 (1989).

    Article  CAS  Google Scholar 

  3. C. P. Sung and H. C. Shih, J. Mater. Res. 7, 105 (1992).

    Article  CAS  Google Scholar 

  4. N. Jiang, B. W. Sun, Z. Zhang, and Z. Lin, J. Mater. Res. 9, 2702 (1994).

    Google Scholar 

  5. M. A. George, A. Burger, W. E. Collins, J.L. Davidson, A. V. Barnes, and N. H. Tolk, J. Appl. Phys. 76, 4099 (1994).

    Article  CAS  Google Scholar 

  6. J. Singh and M. Vellaikal, J. Appl. Phys. 73, 2883 (1993).

    Google Scholar 

  7. B. R. Stoner, G-H.M. Ma, S. D. Wottetr, and J. T. Glass, Phys. Rev. B 45, 11 067 (1992).

    Google Scholar 

  8. H. Kawarda, J.S. Ma, J. T. Suzuki, T. Ito, H. Mori, H. Fujita, and A. Hiraki, Jpn. J. Appl. Phys. 26, 1963 (1987).

    Google Scholar 

  9. A. Saeed, P.A. Gaskell, and D. A. Jefferson, Philos. Mag. B 66, 174 (1992).

    Google Scholar 

  10. J. C. Angus, M. Ssunkara, S. R. Sahaida, and J.T. Glass, J. Mater. Res. 7, 3001 (1992).

    Article  CAS  Google Scholar 

  11. N. Jiang, Z. Zhang, B. W. Sun, and D. Shi, Appl. Phys. Lett. 63, 329 (1993).

    Google Scholar 

  12. G-H. M. Ma, Y. H. Lee, and J. T. Glass, J. Mater. Res. 5, 2373 (1990).

    Article  Google Scholar 

  13. K. Minowa and K. Sumino, Phys. Rev. Lett. 69, 320 (1992).

    Article  CAS  Google Scholar 

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Jiang, N., Hatta, A., Ito, T. et al. Electron microscopic interfacial analysis of diamond film grown on silicon substrate. Journal of Materials Research 11, 1783–1786 (1996). https://doi.org/10.1557/JMR.1996.0223

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  • DOI: https://doi.org/10.1557/JMR.1996.0223

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