Skip to main content
Log in

Characterization of GaAs solar cells made by ion implantation and rapid thermal annealing using selective photoetching

  • Articles
  • Published:
Journal of Materials Research Aims and scope Submit manuscript

Abstract

Shallow n-p GaAs solar cells have been made by implantation of Si into Zn-doped (p-type) GaAs substrates followed by rapid thermal annealing. The structure of the GaAs crystal has been determined by the DSL photoetching method (Diluted Sirtl-like etchants used with Light). It was found that implantation-induced-damage (revealed by DSL as microroughness and craters) was not removed after annealing for energies exceeding 60 keV. This leads to substrates that contain many precipitates, which appears to be disastrous for the fabrication of good solar cells. In addition, good cell performance is hampered by compensation effects in the n-p transition region and in the n-type layer itself.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. H. Kressel, in Semiconductors and Semimetals, edited by R. K. Willardson and A. C. Beer (Academic Press, New York, 1981), Vol. 16, pp. 1–52.

  2. M. A. Green, Solar Cells: Operating Principles, Technology, and System Applications (Prentice Hall, New York, 1982).

    Google Scholar 

  3. D. Flood and H. Brandhorst, in Current Topics in Photovoltaics, edited by T. J. Couts and J. D. Meakin (Academic Press, New York, 1987), Vol. 2, pp. 143–202.

  4. R. K. Ahrenkiel, in Current Topics in Photovoltaics, edited by T. J. Couts and J. D. Meakin (Academic Press, New York, 1988), Vol. 3, pp. 1–78.

  5. O. Ueda, J. Electrochem. Soc. 135, 11C (1988).

    CAS  Google Scholar 

  6. A. K. Chin, J. Cryst. Growth 70, 582 (1984).

    Article  CAS  Google Scholar 

  7. Y. Nanishi, S. Miyazawa, and Y. Matsuoka, in Defect Recognition and Image Processing in III-V Compounds, edited by J. R. Fillard (Elsevier, Amsterdam, 1985), pp. 225–240.

  8. C. G. Michel, G. J. Vendura, and H. S. Marek, J. Electron. Mater. 16, 295 (1987).

    Article  CAS  Google Scholar 

  9. W. de Raedt, M. van Hove, M. de Potter, M. van Rossum, and J. L. Weyher, Inst. Phys. Conf. Ser. 91, 685 (1987).

    Google Scholar 

  10. J. C. C. Fan, C. O. Bolzer, and R. L. Chapman, Appl. Phys. Lett. 32, 390 (1978).

    Article  CAS  Google Scholar 

  11. S. J. Pearton, J. M. Poate, F. Sette, J. M. Gibson, D. C. Jacobson, and J. S. Wiliams, Nucl. Instr. and Meth. B19/20, 369 (1987).

    Article  Google Scholar 

  12. V. Graf and W. Heuberger, Nucl. Instr. and Meth. B19/20, 388 (1987).

    Article  Google Scholar 

  13. T. Saitoh, S. Matsubara, and S. Minagawa, J. Electrochem. Soc. 122, 670 (1975).

    Article  CAS  Google Scholar 

  14. J. L. Weyher and J. van de Ven, J. Cryst. Growth 63, 285 (1983).

    Article  CAS  Google Scholar 

  15. J. van de Ven, J. L. Weyher, J. E. A. M. van den Meerakker, and J. J. Kelly, J. Electrochem. Soc. 133, 799 (1986).

    Article  CAS  Google Scholar 

  16. M. de Potter, W. de Raedt, M. van Hove, M. van Rossum, and J. L. Weyher, Proc. of the E-MRS Meeting, June 1987, edited by Y. I. Nissim and P. A. Glasow (Les Editions de Physique, Paris, 1987), Vol. XVI, pp. 227–233.

  17. J. L. Weyher and J. van de Ven, J. Cryst. Growth 78, 191 (1986).

    Article  CAS  Google Scholar 

  18. J. L. Weyher and J. van de Ven, J. Cryst. Growth 88, 221 (1988).

    Article  CAS  Google Scholar 

  19. Courtesy of P. Montgomery, USTL-CEM, Montpellier, France.

  20. A. Polman, W. G. J. H. M. van Sark, W. C. Sinke, and F. W. Saris, Solar Cells 17, 241 (1986).

    Article  CAS  Google Scholar 

  21. A. Polman, A. M. Vredenberg, W. H. Urbanus, P. J. van Deenen, H. Alberda, H. Krop, I. Attema, E. de Haas, H. Kersten, S. Doom, J. Derks, J. ter Beek, S. Roorda, R. Schreutelkamp, J. G. Bannenberg, and F. W. Saris, Nucl. Instr. and Meth. B37/38, 935 (1989).

    Article  Google Scholar 

  22. W. A. Koelewijn, R. Koudijs, and W.C. Sinke, Mater. Sci. Eng. B2, 243 (1989).

    Article  CAS  Google Scholar 

  23. W. K. Chu, J. W. Mayer, and M-A. Nicolet, Backscattering Spectrometry (Academic Press, New York, 1978).

    Book  Google Scholar 

  24. B. R. Appleton and G. Foti, in Ion Beam Handbook for Material Analysis, edited by J. W. Mayer and E. Rimini (Academic Press, New York, 1977), pp. 69–107.

  25. D. K. Sadana, Nucl. Instr. and Meth. B7/8, 375 (1985).

    Article  Google Scholar 

  26. J. L. Weyher and C. Frigeri (unpublished results).

  27. D. B. Darby, P. D. Augustus, G. R. Booker, and D. J. Stirland, J. Microscopy 118, 343 (1980).

    Article  CAS  Google Scholar 

  28. X. Tang, H. G. M. Lochs, P. R. Hageman, M. H. J. M. de Croon, L. J. Giling, and A. J. Bons, J. Cryst. Growth 98, 827 (1989).

    Article  CAS  Google Scholar 

  29. C. P. Stewart, R. T. Blunt, G. R. Booker, and I. R. Sanders, Physica 116B, 635 (1983).

    Google Scholar 

  30. R. Gwilliam, R. S. Deol, R. T. Blunt, and B. J. Sealy, Inst. Phys. Conf. Ser. 87, 315 (1987).

    CAS  Google Scholar 

  31. M. G. Grimaldi, B. M. Paine, M-A. Nicolet, and D. Sadana, J. Appl. Phys. 52, 4038 (1981).

    Article  CAS  Google Scholar 

  32. J. L. Weyher and W. G. J. H. M. van Sark, PEO Report no. 27.21.004.10 (October 1988).

  33. X. Tang, W. G. J. H. M. van Sark, J. L. Weyher, M. H. J. M. de Croon, H. G. M. Lochs, and L. J. Giling, Proc. of the 8th E. C. Photovoltaic Solar Energy Conference, edited by I. Solomon, B. Equer, and P. Helm (Kluwer Academic Publ., Dordrecht, 1988), p. 1497.

  34. M. I. Nathan and T. N. Morgan, in Physics of Quantum Electronics, edited by P. L. Kelley, B. Lax, and P. E. Tannenwald (McGraw-Hill, New York, 1966), pp. 478–486.

  35. C. A. Warwick, S. S. Gill, P. J. Wright, and A. G. Cullis, Inst. Phys. Conf. Ser. 76, 365 (1985).

    CAS  Google Scholar 

  36. C. J. Keavney, S. M. Vernon, and V. E. Haven, Proc. of the 20th IEEE Photovoltaic Specialists Conference (1988), p. 654.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

van Sark, W., Weyher, J.L., Giling, L.J. et al. Characterization of GaAs solar cells made by ion implantation and rapid thermal annealing using selective photoetching. Journal of Materials Research 5, 1042–1051 (1990). https://doi.org/10.1557/JMR.1990.1042

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/JMR.1990.1042

Navigation