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Generalized Bogue calculations for determining phase compatibility/equilibria: Assessing potential use of inorganic industrial by-products

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Abstract

A method has been developed for determining the equilibrium phase composition of multicomponent systems at subsolidus conditions and atmospheric pressure, based on the knowledge of binary phase compatibilities and on information concerning the existence and stoichiometry of ternary and higher order compounds. The method, combined with material balance, enables computation of the changes of equilibrium phase compositions of fired products dependent on the proportions of multicomponent raw materials; the procedure is useful for assessing the exploitability of industrial wastes for production of binding materials and ceramics. It is also possible to find the raw material mixture composition needed for the desired phase composition of the fired product.

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Authors and Affiliations

  1. Department of Chemical Technology of Silicates, Slovak Technical University, 812 37, Bratislava, Czechoslovakia

    J. Majling & V. Jesenák

  2. Materials Research Laboratory, The Pennsylvania State University, Pennsylvania, 16801, University Park, USA

    Della M. Roy & Rustum Roy

Authors
  1. J. Majling
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  2. V. Jesenák
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  3. Della M. Roy
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  4. Rustum Roy
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Majling, J., Jesenák, V., Roy, D.M. et al. Generalized Bogue calculations for determining phase compatibility/equilibria: Assessing potential use of inorganic industrial by-products. Journal of Materials Research 4, 447–451 (1989). https://doi.org/10.1557/JMR.1989.0447

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  • DOI: https://doi.org/10.1557/JMR.1989.0447

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