Abstract
Monoclinic βZnP2 (black ZnP2) single crystals, synthesized in the presence of excess P, contain regions of polysynthetic lamellar-twinned structure, with dislocations and stacking fault-like features. The twin law is a* twin axis, (100) composition plane: (100) is also the slip plane. The twin composition plane migrates across (100) lattice fringes. In the revised βZnP2 crystal structure, Zn(1) and P(4) positions are related across a (100) twin composition plane at x = 0.84 by two twin operations, with axes through is also a possible slip plane, with three partial dislocations, ½[001], ½[001], and ½[001]. A third possible twin operation relates Zn(2) and P(1) positions across a (100) twin plane at x = 0.5, with twin axis through All twin and slip operations result in very little distortion in nearest- and nextnearest-neighbor coordination geometries. Twin and stacking fault mistakes may be facilitated by approach of the monoclinic cell parameter ratio c[α sin(β — π/2)] to 4 (which yields a pseudo-orthorhombic unit cell) and by Zn1-xP2 nonstoichiometry.
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K. B. Aleinikova, N. S. Rabotkina, A. V. Arsenov, and E. I. Zavalishin, in Proceedings of the 1st International Symposium on Physics and Chemistry of II-V Compounds, edited by M. J. Gelten and L. Zdanowicz (Eindhoven University of Technology, Eindhoven, The Netherlands, 1980), pp. 39–42.
M. E. Fleet, Acta Crystallogr. B 30, 122 (1974).
M. E. Fleet and T. A. Mowles, Acta Crystallogr. C 40, 1778 (1984).
V. Ya. Shevchenko, in Ref. 1, pp. 15–32.
I. J. Hegyi, E. E. Loebner, E. W. Poor, Jr., and J. G. White, J. Phys. Chem. Solids 24, 333 (1963).
M. Stackelberg and R. Paulus, Z. Phys. Chem. B 28, 427 (1935).
B. I. Sysoev, K. B. Aleinikova, L. A. Bityutskaya, V. F. Synorov, and Ya. A. Ugai, in Protessy Rosta I Sinteza Poluprovodn. Kristallov I Plenok, edited by L. N. Aleksandrov and F. A. Kuznetsov (Akademii Nauk SSSR, Novosibirsk, 1975), Vol. 2, pp. 252–255.
O. Olofsson, Acta Chem. Scand. 19, 229 (1965).
A. U. Sheleg and V. V. Zaretzskii, Fiz. Tverd. Tela (Leningrad) 25, 3174 (1983).
M. E. Senko, H. M. Dunn, J. Weidenborner, and H. Cole, Acta Crystallogr. 12, 76 (1959).
N. N. Sirota, A. M. Antyukohov, and E. M. Smolyarenko, Izv. Akad. Nauk SSSR, Neorg. Mater. 13, 358 (1977).
T. A. Mowles, Ph.D. thesis, University of California at Berkeley, 1981.
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Fleet, M.E., White, J.C. Twinning and crystal slip in black monoclinic ZnP2. Journal of Materials Research 1, 187–192 (1986). https://doi.org/10.1557/JMR.1986.0187
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DOI: https://doi.org/10.1557/JMR.1986.0187