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Static Headspace Sampling and Solid-Phase Microextraction for Assessment of Edible Oils Stability

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Abstract

Static headspace sampling and headspace solid-phase microextraction have been applied for the determination of the low molecular mass aldehydes—markers of edible oil oxidation. Preconcentration and determination conditions for the two procedures were optimized. LODs LOQs and repeatability of a standard mixture were established for all investigated compounds. Both methods of sampling were applied to the analysis of samples of rapeseed and sunflower oils. It appears that solid-phase microextraction is better than headspace sampling for the analysis of volatile oxidation products. Solid-phase microextraction can be conducted at a much lower temperature and has lower LOD values and better repeatability than headspace sampling.

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Acknowledgments

This research was financially supported by the European Union within the European Social Fund in the project Ventures and by the Polish Ministry of Science and Higher Education (Grant No 312 056 31 and Grant No 312 227 936).

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Authors and Affiliations

  1. Department of Analytical Chemistry, Chemical Faculty, Gdansk University of Technology, Narutowicza 11/12, 80-233, Gdansk, Poland

    Justyna Gromadzka & Waldemar Wardencki

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  1. Justyna Gromadzka
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  2. Waldemar Wardencki
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Correspondence to Justyna Gromadzka.

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Gromadzka, J., Wardencki, W. Static Headspace Sampling and Solid-Phase Microextraction for Assessment of Edible Oils Stability. Chroma 71 (Suppl 1), 81–86 (2010). https://doi.org/10.1365/s10337-010-1516-y

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  • DOI: https://doi.org/10.1365/s10337-010-1516-y

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