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Influence of Calixarenes on Chromatographic Separation of Benzene or Uracil Derivatives

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Abstract

The addition of calix[4]arenes to MeCN/H2O or MeOH/MeCN/THF/H2O mobile phases improves LC separation of benzene or uracil derivatives on Separon SGX C18 or Separon SGX NH2 supports. Structure of the calixarenes and their host–guest supramolecular complexes with the analytes are discussed in context of the LC separation.

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Acknowledgment

The work is supported by the National Academy of Sciences of Ukraine through the project “Functionalized calixarenes for recognition, reception and transport of biomolecules”.

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Authors and Affiliations

  1. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Murmanska Str. 5, 02660, Kyiv, 94, Ukraine

    Olga I. Kalchenko, Sergiy O. Cherenok, Andriy V. Solovyov & Vitaly I. Kalchenko

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  1. Olga I. Kalchenko
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  2. Sergiy O. Cherenok
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  3. Andriy V. Solovyov
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  4. Vitaly I. Kalchenko
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Correspondence to Sergiy O. Cherenok.

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Kalchenko, O.I., Cherenok, S.O., Solovyov, A.V. et al. Influence of Calixarenes on Chromatographic Separation of Benzene or Uracil Derivatives. Chroma 70, 717–721 (2009). https://doi.org/10.1365/s10337-009-1229-2

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  • DOI: https://doi.org/10.1365/s10337-009-1229-2

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