Skip to main content
SpringerLink
Log in

CZE Determination of Calixarenes and Related Derivatives Using Acetonitrile as a Modifier

  • Full Short Communication
  • Published:
Chromatographia Aims and scope Submit manuscript

Abstract

The applications of third-generation host compound calixarenes have been restricted due to their high price and shortage of supply. To obtain high pure calixarenes with high yield, synthesis strategy and analytical method investigations are necessary. The present work describes capillary zone electrophoresis (CZE) for the separation and determination of calixarene derivatives under the optimized CZE conditions within 20 min. The CZE method was evaluated with linear ranges, detection limits, recoveries and repeatability. The results indicated that the method was accurate and reproducible. As expected, it could be utilized to separate and evaluate calixarene derivatives during their synthesis and purification.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. Cadogan F, Kane P, McKervey MA, Diamond D (1999) Anal Chem 71:5544–5548

    Article  CAS  Google Scholar 

  2. Kimura K, Yajima S, Tatsumi K, Yokoyama M, Oue M (2000) Anal Chem 72:5290–5294

    Article  CAS  Google Scholar 

  3. Kim TH, Lee JK, Bok JH, Kim JS, Kim H (2004) Electrochim Acta 49:3759–3763

    Article  CAS  Google Scholar 

  4. Zheng H, Dong H, Yan Z, Wen L, Zhang SS, Ye BX (2006) Electrochemistry 18:2115–2120

    CAS  Google Scholar 

  5. Kivlehan F, Mace WJ, Moynihan HA, Arrigan DWM (2007) Anal Chim Acta 585:154–160

    Article  CAS  Google Scholar 

  6. Sakly H, Mlika R, Bonnamour I, Aouni F, Ben Ouada H, Jaffrezic N (2007) Electrochim Acta 52:3697–3703

    Article  CAS  Google Scholar 

  7. Shohat D, Grahka E (1994) Anal Chem 66:747–752

    Article  CAS  Google Scholar 

  8. Pena MS, Zhang Y, Warner IM (1997) Anal Chem 69:3239–3245

    Article  CAS  Google Scholar 

  9. Wang Z, Chen Y, Yuan H, Huang Z, Liu G (2000) Electrophoresis 21:1620–1626

    Article  CAS  Google Scholar 

  10. Wu X, Liu HX, Liu H, Zhang SS, Haddad PR (2003) Anal Chim Acta 478:191–197

    Article  CAS  Google Scholar 

  11. Sokoliess T, Gronau M, Menyes U (2003) Electrophoresis 24:1648–1657

    Article  CAS  Google Scholar 

  12. Lim HJ, Lee HS, Kim LW (1998) Chromatographia 48:422–427

    Article  CAS  Google Scholar 

  13. Kolchenko OL, Lipkowski J, Kalchenko VL (1998) J Chromatogr Sci 36:269–276

    Google Scholar 

  14. Yu XD, Fang H, Lin L, Han HM, Wu CY (2001) Chromatographia 53:519–526

    Article  CAS  Google Scholar 

  15. Li LS, Da SL, Feng YQ, Liu M (2004) J Chromatogr A 1040:53–58

    Article  CAS  Google Scholar 

  16. Dong C, Zeng Z, Li X (2005) Talanta 66:721–727

    Article  CAS  Google Scholar 

  17. Ding C, Qu K, Li Y, Hu K, Liu H, Ye B, Wu Y, Zhang SS (2007) J Chromatogr A 1170:73–81

    Article  CAS  Google Scholar 

  18. Ludwiq FJ, Bailie AG (1984) Anal Chem 56:2081–2085

    Article  Google Scholar 

  19. Saito Y, Ohta H, Terasaki H (1995) JHRC 19:475–477

    Article  Google Scholar 

  20. Bianco A, Gasparrini F, Maggini M (1997) J Am Chem Soc 119:7550–7554

    Article  CAS  Google Scholar 

  21. Kalchenko OI, Lipkowski J, Nowakowski R, Kalchenko VI, Visotsky MA, Markosky LN (1997) J Chromatogr Sci 35:49–54

    CAS  Google Scholar 

  22. Thibodeaux SJ, Sanchez PM, Zhang Y, Shamsi SA, Warner IM (1999) Chromatographia 49:142–147

    Article  CAS  Google Scholar 

  23. Zhang Y, Warner IM (1994) J Chromatogr A 688:293–300

    Article  CAS  Google Scholar 

  24. Ding C, Han P, Song J, Liu HX, Zhang SS, Ye B, Wu Y (2006) Anal Chim Acta 566:246–252

    Article  CAS  Google Scholar 

  25. Wang F, Khaledi MG (1999) J Chromatogr B 731:187–194

    Article  CAS  Google Scholar 

  26. Li Y, Cui S, Cheng Y, Chen X, Hu Z (2004) Anal Chim Acta 508:17–24

    Article  CAS  Google Scholar 

  27. Gutsche CD, Iqbal M (1990) Org Synth 68:234–237

    CAS  Google Scholar 

  28. Gutsche CD, Dhawan B, Leonis M, Stewart D (1990) Org Synth 68:238–242

    CAS  Google Scholar 

  29. Munch JH, Gutsche CD (1990) Org Synth 68:243–247

    CAS  Google Scholar 

  30. Gutsche CD, Lin LG (1986) Tetrahedron 42:1633–1639

    Article  CAS  Google Scholar 

  31. Zhang SS (2000) Postodctoral Report of Zhengzhou University of China

Download references

Acknowledgments

The authors would like to show their appreciation of the support of Henan University Innovation People Grant of 2004 and NSFs of China (20575060, 20775073). And also thank Dr. Julie Rimes for assistance with editing the text.

Author information

Authors and Affiliations

  1. Chemistry Department, Key Laboratory of Chemical Biology and Organic Chemistry of Henan, Zhengzhou University, Zhengzhou, 450052, China

    Hui Yang, Yanyan Lu, Baoxian Ye, Yangjie Wu & Shusheng Zhang

  2. Center of Disease Control and Prevention of Henan, Zhengzhou, 450000, China

    Rongjie Zhang

Authors
  1. Hui Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Rongjie Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yanyan Lu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Baoxian Ye
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yangjie Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Shusheng Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Shusheng Zhang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yang, H., Zhang, R., Lu, Y. et al. CZE Determination of Calixarenes and Related Derivatives Using Acetonitrile as a Modifier. Chroma 68, 123–127 (2008). https://doi.org/10.1365/s10337-008-0643-1

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1365/s10337-008-0643-1

Keywords

Search

Navigation