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Separation and Simultaneous Determination of Enantiomers of Tau-fluvalinate and Permethrin in Drinking Water

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Abstract

The chiral liquid chromatographic separation of two pyrethroid insecticides, tau-fluvalinate and permethrin, on different polysaccharide-based chiral stationary phases (CSPs) has been investigated. Complete separation of these compounds was achieved with Chiralcel OJ under normal phase mode and a mobile phase of n-hexane:ethanol (90:10, v/v). This method has been used for determining these compounds in drinking water at ppb levels after solid-phase extraction (SPE) with C-18 cartridges. Recoveries ranged between 103–113% and precision values (expressed as relative standard deviations) were lower than 10%.

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References

  • Narahashi T (1992). TIPS, 13, pp. 236–241

  • Elliott M (1976) In: Elliott M (Ed.), Synthetic Pyrethroids, ACS Symposium Series, no.42, Washington, D.C., Ch.1

  • Leicht W, Fuchs R, Londershausen M (1996) Pestic Sci 48(4):325–332

    Article  CAS  Google Scholar 

  • Burt PE, Elliott M, Farnham AW, Jones NF, Needham PH, Pulman DA (1974) Pestic Sci 5(6):791–799

    CAS  Google Scholar 

  • Elliott M, Farnham AW, Jones NF, Soderlund DM (1978) Pestic Sci 9:12–19

    Google Scholar 

  • Zong-Mao Ch, Yun-Hao W (1996) J Chromatogr A 754:367–395

    Article  PubMed  Google Scholar 

  • Jibao C, Baizhan L, Xiaolan Z, Qingde S (2002) J Chromatogr A 964:205–211

    Article  PubMed  Google Scholar 

  • Ma XD, Li CJ, Tao CJ, Liu W, Zheng SS (2001) Rapid Commun Mass Sp 15(1): 15–19

    Article  CAS  Google Scholar 

  • Hancock PM, Yasin M, Baugh PJ, Bonwick GA, Davies DH (1997) Int J Environ Anal Chem 67(1–4):81–95

    Google Scholar 

  • Pang GF, Chao YZ, Fan CL, Zhang JJ, Li XM, Zhao TS (1995) J AOAC Int 78(6):1481–1488

    CAS  PubMed  Google Scholar 

  • Waliszewski SM, Pardio VT, Waliszewski KN, Ochoa A, Infanzon RM (1998) J Sci Food Agric 77:149–152

    Article  CAS  Google Scholar 

  • Edwards DP, Ford MG (1997) J Chromatogr A 777:363–369

    Article  CAS  Google Scholar 

  • Lisseter SG, Hambling SG (1991) J Chromatogr 539(1):207–210

    Article  CAS  Google Scholar 

  • Oi N, Kitahara H, Kira R (1990) J Chromatogr 515:441–450

    Article  CAS  Google Scholar 

  • Cayley GR, Simpson BW (1986) J Chromatogr 356:123–134

    CAS  PubMed  Google Scholar 

  • Sevcik J, Lemr K, Stransky Z, Vecera T, Hlavac J (1997) Chirality 9:162–166

    Article  CAS  Google Scholar 

  • O’Mahony T, Moore S, Brosnan B, Glennon JD (2003) Int J Environ Anal Chem 83(7–8):681–691

    Google Scholar 

  • Cuadros Rodríguez L, García Campaña AM, Jiménez Linares C, Román Ceba M (1993) Anal Lett 26:1243–1258

    Google Scholar 

  • Long GL, Winerfordner JD (1983) Anal Chem 55:712A–724A

    CAS  Google Scholar 

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Authors and Affiliations

  1. Shandong Key Laboratory of Chemical Function Materials, Shandong Normal University, Jinan, P.R. China

    Guo-Sheng Yang

  2. Department of Analytical Chemistry, University of Almería, La Cañada, 04120, Almería, Spain

    Guo-Sheng Yang, P. Parrilla Vázquez, A. Garrido Frenich & J.L. Martínez Vidal

  3. Pharmaceutical Analysis Laboratory, Biological and Medical Research Department (MBC-03-65), King Faisal Specialist Hospital and Research Centre, 3354, Riyadh, 11211, Saudi Arabia

    H.Y. Aboul-Enein

Authors
  1. Guo-Sheng Yang
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  2. P. Parrilla Vázquez
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  3. A. Garrido Frenich
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  4. J.L. Martínez Vidal
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  5. H.Y. Aboul-Enein
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Corresponding author

Correspondence to P. Parrilla Vázquez.

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Revised: 14 April, 2 June and 16 June 2004

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Yang, GS., Vázquez, P., Frenich, A. et al. Separation and Simultaneous Determination of Enantiomers of Tau-fluvalinate and Permethrin in Drinking Water. Chromatographia 60, 523–526 (2004). https://doi.org/10.1365/s10337-004-0404-8

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  • DOI: https://doi.org/10.1365/s10337-004-0404-8

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