Abstract
Lattice-matched InGaAs/lnP heterostructures have been grown by using metalorganic vapor phase epitaxy (MOVPE) with tertiarybutylarsine (TBAs), tertiarybutylphosphine (TBP) as the group V sources. The results of X-ray diffraction on InGaAs/lnP single herterostructure show that there is a compressive-strained interfacial layer at the InP-to-InGaAs interface. X-ray diffraction of InGaAs/ InP superlattices is successfully simulated by using the same interfacial layer. TBAs purging of InP surface has a significant influence on the interfacial strain. A novel gas switching sequence, which switches group III to the run line earlier than TBAs, is proposed to reduce this interfacial strain. As a result, the average compressive strain of superlattices decreases, and a blue shift of photoluminescence ( PL) peak energy and narrowing in PL width are obtained.
Similar content being viewed by others
References
Ryu, S. W., Jeong, W. G., Kim, I. et al., Reduction of As carryover by pH3 overpressure in MOVPE, J. Crystal Growth, 1997, 179: 26–29.
Nakamura, T., Ae, S., Terakado, T. et al., Highly controlled InGaAs(P)/InP MQW interface grown by using TBAs and TBP precursors, J. Electronic Materials, 1996, 25: 457–460.
Holmes, A. L., Hermbuch, M. E., Fish, G. et al., InP-based MQW structures grown with TBAs TBP, J. Electronic Materials, 1996, 25: 965–969.
Jiang, X. S., Clawson, A. R., Yu, P. K. L., InP-on-InGaAs interface with Ga and In coverage in MOVPE of InGaAs/InP superlattices, J. Crystal Growth, 1995, 147: 8–12.
Seifer, W., Hessman, D., Liu, X. et a1., Formation of interface layers in GaInAs/InP heterostmctures: A re-evalution using ultrathin quantum wells as a probe, J. Appl. Phys., 1994, 75: 1501 -1506.
Meyer, R., Hollfelder, M., Hardtdegen, H. et al., Characterization of interface structure in GaInAs/InP superlattice by means of X-ray diffraction, J. Crystal Growth, 1992, 124: 583–587.
Kamei, H., Hayashi, H., MOVPE growth of InGaAs/InP and gaInAs/GaInAsP quantum wells, J. Crystal Growth, 1991, 107: 567–570.
Hybertsen, M. S., Interface strain at the lattice-matched InGaAs/InP heterointerface, J. Vac. Sci. Techno1., 1990, B8: 773–778.
Vanelle, E., Mesrine, M., Grandjean, N. et al., Interface effects on the photoluminescence of GaAs/GaInP quantum wells, J. Appl. Phys., 1998, 37: 15–20.
Vignaud, D., Wallart, X., Mollot, F., Direct and inverse equivalent InAlAs-InP interfaces grown by gas-source molecular beam epitaxy, Appl. Phys. Lett., 1998, 72: 1075–1079.
Vandenberg, J. M., Harnm, R. A., Chu, S. N. G., Interface structure of large-period lattice matched InGaAs/InP superlattice grown by MOMBE: A high-resolution X-ray diffraction study, J. Crystal Growth, 1994, 144: 9–12.
Böhrer, J., Krost, A., Bimberg, D., InAsP islands at the lower interface of InGaAs/InP quantum wells grown by MOCVD, Appl. Phys. Lett., 1992, 60: 2258–2262.
Xu, X. G., Giesen, C., Xu, J. et al., Si2,H6 doping of InGaAs by using TBAs, J. Crystal Growth, 1997, 181: 26–30.
He, X. G., Erdtmann, M., Williams, R. et al., Correlation between X-ray diffraction patterns and strain distribution inside GaInPIGaAs superlattices, Razeghi, Appl. Phys. Lett., 1994, 65: 2812–2816.
Wie, C. R., High-resolution X-ray diffraction characterization of semiconductor structures, Materials Science and Engineering, 1994, R13: 1–5.
Jonsson, J., Reinhardt, F., Zom, M. et al., In-situ time-resovled monitoring of pH3 induced exchange reactions on GaAs under MOVPE conditions, Appl. Phys. Lett., 1994, 64: 1998–2001.
Yates, M. J., Aylett, M. R., Pemn, S. D. et al., Charaterization of InP to GaInAs and GaInP to InP interfaces using tilted cleaved comer TEM, J. Crystal Growth, 1992, 124: 604–609.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Xu, X., Cui, D., Tang, Z. et al. InP-to-InGaAs interfacial strain grown by using tertiarybutylarsine and tertiarybutylphosphine. Sci. China Ser. A-Math. 45, 655–660 (2002). https://doi.org/10.1360/02ys9071
Received:
Issue Date:
DOI: https://doi.org/10.1360/02ys9071