Abstract
The evolution of texture, structure and chemical composition of chloritic clays in coeval pairs of metabasites and metapelites of a prograde sequence from the Bükk Mountains has been investigated using electron microscopy techniques. Samples are from the Bükkium (innermost Western Carpathians, Hungary) that underwent Alpine metamorphism, ranging from late diagenesis to epizone for pelites and from prehnite-pumpellyite to greenschist facies for the metabasites.
Although bulk-rock compositions, textures and primary minerals are different, chlorite evolved at similar rates in coeval metabasites and metasediments, but along different paths. The principal similarities in the prograde sequence are a decrease in the percentage of interstratified material in both dioctahedral and trioctahedral phyllosilicates and increase in thicknesses of chlorite and illite crystallites. The principal difference is in the type of interstratification in chlorite, with berthierine in metapelites, and smectite (saponite) in metabasites, although smectitic mixed layers also occur in the former. The evolution of trioctahedral phyllosilicates is marked by a decrease in the number of mineral species with increasing grade, chlorite, sensu stricto, being the only trioctahedral mineral at higher grades. This is consistent with the trend in reaction progress where both metastable systems (metabasites and metapelites) tend toward the same end-member, thermodynamically stable chlorite, as well as texture (crystal size), and where all intermediate states are metastable, and determined by the Ostwald step rule.
Similar content being viewed by others
References
Abad-Ortega, M. M. and Nieto, F. (1995) Genetic and chemical relationships between berthierine, chlorite and cordi-erite in nodules associated to granitic pegmatites of Sierra Albarrana (Iberian Massif, Spain). Contributions to Mineralogy and Petrology, 120, 327–336.
Ahn, J. H. and Peacor, D. R. (1985) Transmission electron microscopic study of diagenetic chlorite in Gulf Coast argillaceous sediments. Clays and Clay Minerals, 33, 228–236.
Alt, J. C. (1999) Very low-grade hydrothermal metamorphism of basic igneous rocks. Pp. 169–226 in: Low-Grade Metamorphism (M. Frey and D. Robinson, editors). Blackwell Science, Oxford.
Amouric, M., Gianetto, I. and Proust, D. (1988) 7, 10 and 14 Å mixed-layer phyllosilicates studied structurally by TEM in pelitic rocks of the Piemontese zone (Venezuela). Bulletin Mineralogique, 111, 29–37.
Árkai, P. (1983) Very low- and low-grade Alpine regional metamorphism of the Paleozoic and Mesozoic formations of the Bükkium, NE-Hungary. Acta Geologica Hungarica, 26, 83–101.
Árkai, P. (1991) Chlorite crystallinity: An empirical approach and correlation with illite crystallinity, coal rank and mineral facies as exemplified by Palaeozoic and Mesozoic rocks of northeast Hungary. Journal of Metamorphic Geology, 9, 723–734.
Árkai, P. and Sadek Ghabrial, D. (1997) Chlorite crystallinity as an indicator of metamorphic grade of low-temperature meta-igneous rocks: A case study from the Bükk Mountains, northeast Hungary. Clay Minerals, 32, 205–222.
Árkai, P. and Tóth, M. (1990) Illite and chlorite “crystallinity” indices, I: an attempted mineralogical interpretation. Conference on “Phyllosilicates as indicators of very low-grade metamorphism and diagenesis”. IGCP 294, Manchester, Abstract.
Árkai, P., Balogh, K. and Dunkl, I. (1995) Timing of low-temperature metamorphism and cooling of the Paleozoic and Mesozoic formations of the Bükkium, innermost Western Carpathians, Hungary. Geologische Rundschau, 84, 334–344.
Árkai, P., Mata, M. P., Giorgetti, G., Peacor, D. R. and Tóth, M. (2000) Comparison of diagenetic and incipient metamorphic evolution of chlorites in associated pelitic sedimentary and basic igneous rocks: An integrated TEM and XRD study. Journal of Metamorphic Geology, 18, 531–550.
Bettison, L. A. and Schiffman, P. (1988) Compositional and structural variations of phyllosilicates from the Point Sal ophiolite, California. American Mineralogist, 73, 62–76.
Bons, A. J. (1988) Deformation of chlorite in naturally deformed low-grade rocks. Tectonophysics, 154, 149–165.
Bons, A. J. and Schryvers, D. (1989) High-resolution electron microscopy of stacking irregularities in chlorites from the central Pyrenees. American Mineralogist, 74, 1113–1123.
Bucher, K. and Frey, M. (1994) Petrogenesis of Metamorphic Rocks, 6th edition. Complete revision of Winkler’s textbook. Springer-Verlag, Berlin.
Cathelineau, M. and Nieva, D. (1985) A chlorite solid solution geothermometer. The Los Azufres (Mexico) geother-mal system. Contributions to Mineralogy and Petrology, 91, 235–244.
Coombs, D. S., Zhao, G. and Peacor, D. R. (2000) Manganoan berthierine, Meyers Pass, New Zealand: Occurrence in the prehnite-pumpellyite facies. Mineralogical Magazine, 64, 1037–1046.
Curtis, C. D., Hughes, C. R., Whiteman, J. A. and Whittle, C. K. (1985) Compositional variations within some sedimentary chlorites and some comments on their origin. Mineralogi-cal Magazine, 49, 375–386.
Dalla Torre, M., Livi, K. J. T. and Frey, M. (1996) Chlorite textures and compositions from high-pressure/low-temperature metashales and metagraywackes, Franciscan Complex, Diablo Range, California, USA. European Journal of Mineralogy, 8, 825–846.
Downes, H., Pantó, Gy., Árkai, P. and Thirlwall, M. F. (1990) Petrology and geochemistry of Mesozoic igneous rocks, Bükk Mountains, Hungary. Lithos, 24, 201–215.
Essene, E. J. and Peacor, D. R. (1995) Clay mineral thermometry—a critical perspective. Clays and Clay Minerals, 43, 540–553.
Frey, M. (1987) Very low-grade metamorphism of clastic sedimentary rocks. Pp. 9–58 in: Low Temperature Metamorphism (M. Frey, editor). Blackie, Glasgow and London, UK.
Hillier, S. (1993) Origin, diagenesis, and mineralogy of chlorite minerals in Devonian lacustrine mudrocks, Orcadian Basin, Scotland. Clays and Clay Minerals, 41, 240–259.
Hillier, S. (1994) Pore-lining chlorites in siliciclastic reservoir sandstones: electron microprobe, SEM and XRD data, and implications for their origin. Clay Minerals, 29, 665–679
Hillier, S. and Velde, B. (1992) Chlorite interstratified with a 7 A mineral: an example from offshore Norway and possible implications for the interpretation of the composition of diagenetic chlorites. Clay Minerals, 27, 475–486.
Ijima, A. and Matsumoto, R. (1982) Berthierine and chamo-site coal measures of Japan. Clays and Clay Minerals, 30, 264–274.
Jiang, W. T. and Peacor, D. R. (1994a) Prograde transitions of corrensite and chlorite in low-grade pelitic rocks from Gaspe Peninsula, Quebec. Clays and Clay Minerals, 42, 497–517.
Jiang, W. T. and Peacor, D. R. (1994b) Formation of corrensite, chlorite and chlorite mica stacks by replacement of detrital biotite in low-grade pelitic rocks. Journal of Metamorphic Geology, 12, 867–884.
Jiang, W. T., Peacor, D. R., Merriman, R. J. and Roberts, B. (1990) Transmission and analytical electron microscopic study of mixed-layer illite/smectite formed as an apparent replacement product of diagenetic illite. Clays and Clay Minerals, 38, 449–468.
Jiang, W. T., Peacor, D. R. and Slack, J. F. (1992) Microstructures, mixed layering, and polymorphism of chlorite and retrograde berthierine in the Kidd Creek massive sulphide deposit, Ontario. Clays and Clay Minerals, 40, 501–514.
Jiang, W.-T., Peacor, D. R. and Buseck, P. R. (1994) Chlorite geothermometry?—contamination and apparent octahedral vacancies. Clays and Clay Minerals, 42, 593–605.
Kovács, S. (1989) Major events of the tectono-sedimentary evolution of the North Hungarian Paleo-Mesozoic: history of the northwestern termination of the Late Paleozoic-Early Mesozoic Tethys. Pp. 93–108 in: Tectonic Evolution of the Tethyan Region (A. M. C. Sengor, editor). Kluwer Academic Publishers, Dordrecht.
Kovács, S., Szederkényi, T., Árkai, P., Buda, Gy., Lelkes-Felvári, Gy. and Nagymarosi, A. (1996-97) Explanation to the terrane map of Hungary. Annales Géologiques des Pays Helléniques, 37, 271–330.
Laird, J. (1988) Chlorites: Metamorphic petrology. Pp. 405–453 in: Hydrous Phyllosilicates (P. H. Ribbe, editor). Reviews in Mineralogy, 19. Mineralogical Society of America, Washington, D.C.
Lee, J. H. and Peacor, D. R. (1983) Intralayer transitions in phyllosilicates of the Martinsburg Shale. Nature, 303, 608–609.
Li, G., Peacor, D. R., Merriman, R. J., Roberts, B. and van der Pluijm, B. A. (1994) TEM and AEM constraints on the origin and significance of chlorite-mica stacks in slates: An example from Central Wales, U.K. Journal of Structural Geology, 16, 1139–1157.
Li, G., Peacor, D. R. and Coombs, D. S. (1997) Transformation of smectite to illite in bentonite and associated sediments from Kaka point, New Zealand: contrast in rate and mechanism. Clays and Clay Minerals, 45, 54–67.
López-Munguira, A. and Nieto, F. (2000) Transmission electron microscopy study of very-low grade metamorphic rocks in Cambrian sandstones and shales, Ossa-Morena zone, Southwest Spain. Clays and Clay Minerals, 48, 213–223.
Masuda, H., O’Neil, J. R., Jiang, W.-T. and Peacor, D. R. (1996) Relation between interlayer composition of authi-genic smectite, mineral assemblages, I/S reaction rate and fluid composition in silicic ash of the Nankai Trough. Clays and Clay Minerals, 44, 460–469.
Mata, M. P., Arkai, P., Giorgetti, G. and Peacor, D. R. (2000) Retrogression of metamorphic phyllosilicates in low-grade rocks. 31st International Geological Congress (Brazil, 2000).
Merriman, R. J. and Frey, M. (1999) Patterns of very low-grade metamorphism in metapelitic rocks. Pp. 61–107 in: Low-Grade Metamorphism (M. Frey and D. Robinson, editors). Blackwell Science, Oxford.
Merriman, R. J. and Peacor, D. R. (1999) Very low-grade me-tapelites: Mineralogy, microfabrics and measuring reaction progress. Pp. 10–60 in: Low-Grade Metamorphism (M. Frey and D. Robinson). Blackwell Science, Oxford.
Merriman, R. J. Roberts, B., Peacor, D. R. and Hirons, S. R. (1995) Strain-related differences in the crystal growth of white mica and chlorite: A TEM and XRD study of the development of metapelite microfabrics in the Southern Uplands thrust terrane, Scotland. Journal of Metamorphic Geology, 13, 559–576.
Morse, J. S. and Casey, W. H. (1988) Ostwald processes and mineral paragenesis in sediments. American Journal of Science, 288, 537–560.
Nieto, F., Velilla, N., Peacor, D. R. and Huertas, M. (1994) Regional retrograde alteration of sub-greenschist facies chlorite to smectite. Contributions to Mineralogy and Petrology, 115, 243–252.
Robinson, D. and Bevins, R. E. (1999) Patterns of regional low-grade metamorphism in metabasites. Pp. 143–168 in: Low-Grade Metamorphism (M. Frey and D. Robinson, editors). Blackwell Science, Oxford.
Robinson, D. and Merriman, R. J. (1999) Low-temperature metamorphism: An overview. Pp. 1–9 in: Low-Grade Metamorphism (M. Frey and D. Robinson, editors). Black-well Science, Oxford.
Sadek-Ghabrial, D., Árkai, P. and Nagy, G. (1994) Magmatic features and metamorphism of plagiogranite associated with a Jurassic MORB-like basic-ultrabasic complex, Bükk Mountains, Hungary. Acta Mineralogia et Petrographia Szegediensis, 35, 41–69.
Sadek-Ghabrial, D., Árkai, P. and Nagy, G. (1996) Alpine polyphase metamorphism of the ophiolitic Szarvaskõ complex, Bükk Mountains, Hungary. Acta Mineralogia et Petrographia Szegediensis, 37, 99–128.
Schiffman, P. and Day, H. W. (1999) Petrological methods for the study of very low-grade metabasites. Pp. 18–142 in: Low-Grade Metamorphism (M. Frey and D. Robinson, editors). Blackwell Science, Oxford.
Schmidt, D., Livi, K. J. T. and Frey, M. (1999) Reaction progress in chloritic mineral: An electron microbeam study of the Taveyanne greywacke, Switzerland. Journal of Metamorphic Geology, 17, 229–241.
Shau, Y.-H. and Peacor, D. R. (1992) Phyllosilicates in hydro-thermally altered basalts from DSDP hole 504B, leg 83 a TEM and AEM study. Contributions to Mineralogy and Petrology, 112, 119–133.
Slack, J. F., Jiang, W. T., Peacor, D. R. and Okita, P. M. (1992) Hydrothermal and metamorphic berthierine from the Kidd Creek volcanogenic massive sulphide deposit, Timmins, Ontario. Canadian Mineralogist, 30, 1127–1142.
Van Houten, F. B. and Purucker, M. E. (1984) Glauconitic peloids and chamositic ooids—favorable factors, constraints, and problems. Earth Science Reviews, 20, 211–243.
Wiewióra, A. and Weiss, Z. (1990) Crystallochemical classification of phyllosilicates based in the unified system of projection of chemical composition. II. The chlorite group. Clay Minerals, 25, 83–92.
Xu, H. and Veblen, D. R. (1996) Interstratification and other reaction microstructures in the chlorite-berthierine series. Contributions to Mineralogy and Petrology, 124, 291–301.
Zane, A and Weiss Z. (1998) A procedure for classification of rock-forming chlorites based on microprobe data. Rend. Fis. Accad. Lincei, 9, 51–56.
Zhao, G., Peacor, D. R. and McDowell, S. D. (1999) Retrograde diagenesis of Clay Minerals of the Freda Sandstone, Wisconsin. Clays and Clay Minerals, 47, 119–130.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Mata, M.P., Giorgetti, G., Árkai, P. et al. Comparison of Evolution of Trioctahedral Chlorite/Berthierine/Smectite in Coeval Metabasites and Metapelites from Diagenetic to Epizonal Grades. Clays Clay Miner. 49, 318–332 (2001). https://doi.org/10.1346/CCMN.2001.0490406
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1346/CCMN.2001.0490406