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Wettability Contrasts in Kaolinite and Illite Clays: Characterization by Infrared and X-Ray Absorption Spectroscopies

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Clays and Clay Minerals

Abstract

A reservoir rock is a porous geological formation in contact with 2 liquids, brine and oil. An improved knowledge of rock wettability is of primary importance to estimate the amount of crude oil in underground resources. The petroleum industries have observed that wettability contrasts in sedimentary reservoir rocks are largely correlated to the presence of clays, illite and/or kaolinite in the rocks’ intergranular space.

More precisely, the grain surfaces of illite show a preference for brine. Kaolinite preferentially adsorbs oil, which imparts its hydrophobic characteristics to the mineral surface. Using X-ray absorption spectroscopy (XAS) and Fourier transform infrared (FTIR) spectroscopy, we studied the adsorption process of asphaltenes in the presence of water at the microscopic level. We demonstrate experimentally that the wettability contrasts observed in kaolinite and illite are related to structural differences between these 2 clays, and we show the role of the grain surface hydroxyls. With clay materials, the purity of the samples is the most important limitation of the quantitative use of extended X-ray absorption fine structure (EXAFS).

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References

  • Bantignies JL, Cartier dit Moulin C, Dexpert H, Flank AM, Williams G. 1995. Asphaltenes adsorption on kaolinite: Characterization by infrared microspectroscopy and X-ray absorption spectroscopy. CR Acad Sci, Ser II a:699–709.

    Google Scholar 

  • Barrios J, Plancon A, Cruz MI, Tchoubar C. 1977. Qualitative and quantitative study of stacking faults in a hydrazine treated kaolinite. Relationship with the infrared spectra. Clays Clay Miner 25:422–429.

    Article  Google Scholar 

  • Berhouet S. 1994. Modélisation moléculaire des intéractions entre minéraux et constituants lourds du pétrole [Ph.D. dissertation]. Paris, France: University of Paris IV. 187 p.

    Google Scholar 

  • Bish DL, Van Dreele RB. 1989. Rietvield refinement of non-hydrogene atomic positions in kaolinite. Clays Clay Miner 37:289–296.

    Article  Google Scholar 

  • Brindley GW, Kao C, Harrison JL, Lipsicas M, Raythatha R. 1986. Relation between structural disorder and other characteristics of kaolinites and dickites. Clays Clay Miner 34:239–249.

    Article  Google Scholar 

  • Briois V, Sainctavit Ph, Flank A-M. 1993. Polarization dependence of XANES of α-quartz: Experiments and full multiple-scattering calculations. Proc 7th Int Conf X-ray Absorption Fine Structure; Kobe, Japan. J Appl Phys 32, suppl 32-2:52–54.

    Google Scholar 

  • Brown GE, Calas G, Waychunas GA, Petiau J. 1988. X-ray absorption spectroscopy: Applications in mineralogy and geochemistry. In: Hawthorne FC, editor. Spectroscopic methods in mineralogy and geology. Rev Mineral 18:431–512.

    Article  Google Scholar 

  • Cabaret D, Sainctavit P, Ildefonse P, Flank AM. 1996. Full multiple scattering calculations on silicates and oxides at Al K-edge. J Phys Condens Matter 8:3691–3704.

    Article  Google Scholar 

  • Chisholm-Brause CJ, Hayes KF, Roe AL, Brown GE, Jr, Parks GA, Leckie JO. 1990. Spectroscopic investigation of Pb(II) complexes at the γ-Al2O3/water interface. Geo-chim Cosmochim Acta 54:1897–1909.

    Article  Google Scholar 

  • Chisholm-Brause CJ, O’Day PA, Brown GE, Jr, Parks GA. 1990. Evidence for multinuclear metal-ion complexes at solid/water interfaces from X-ray absorption spectroscopy. Nature 348:528–530.

    Article  Google Scholar 

  • Clementz DM. 1976. Interaction of petroleum heavy ends with montmorillonite. Clays Clay Miner 24:312–319.

    Article  Google Scholar 

  • Cuiec L. 1991. Evaluation of reservoir wettability and its effect on oil recovery. In: Morrow NR, editor. Interfacial phenomena in oil recovery 36. New York: Marcel Dekker. p 319–376.

    Google Scholar 

  • Czarnecka E, Gillott JE. 1980. Formation and characterization of clay complexes with bitumen from Athabasca oil sand. Clays Clay Miner 28:197–203.

    Article  Google Scholar 

  • Farmer VC. 1974. The layer silicates. In: Farmer VC, editor. The infrared spectra of minerals. London: Mineral Soc. p 331–363.

    Chapter  Google Scholar 

  • Fassi-Fihri O. 1991. Wettability studies at the pore level: A new approach by the use of cryo-scanning electron microscopy. Review of the French Institute of Petroleum. IFP report 38985. p 44.

    Google Scholar 

  • Heller-Kallai L, Huard E, Prost R. 1991. Disorder induced by de-intercalation of DMSO from kaolinite. Clay Miner 26:245–253.

    Article  Google Scholar 

  • Henderson CMB, Cressey G, Redfern SAT. 1995. Geological applications of synchrotron radiation. Radiat Phys Chem 45:459–481.

    Article  Google Scholar 

  • Ildefonse P, Calas G, Flank AM, Lagarde P. 1995. Low Z elements K-edge X-ray absorption spectroscopy in minerals and disordered systems. Nucl Instrum Methods Phys Res, Sect B 97:172–175.

    Article  Google Scholar 

  • Ildefonse P, Calas G, Kirkpatrick RJ, Montez B, Flank AM, Lagarde P. 1992. Local environment of aluminum in amorphous alumino-silicates by using XANES and MAS NMR. In: Kharada H, Maest D, editors. Proc 7th Int Symp on Water-rock Interaction; Rotterdam, The Netherlands. Rotterdam: Balkema. p 153–158.

  • Ildefonse P, Calas G, Kirkpatrick RJ, Montez B, Flank AM, Lagarde P. 1994. 27Al MAS NMR and aluminum X-ray absorption near edge structure study of imogolite and allophanes. Clays Clay Miner 42:276–287.

    Article  Google Scholar 

  • Jerauld GR, Rathmell JJ. 1994. Wettability and relative permeability of Prudhoe bay: A case study in mixed-wet reservoirs. Proc 3rd Int Symp on Evaluation of Reservoir Wettability and its Effect on Oil Recovery; Laramie, Wyoming. Laramie: Modern Printing. p 1.

    Google Scholar 

  • Johnston CT, Sposito G, Agnew SF, Bish DL. 1990. Polarized single-crystal Fourier-transform infrared microscopy of Ouray dickite and Keokuk kaolinite. Clays Clay Miner 38:573–583.

    Article  Google Scholar 

  • Johnston CT, Sposito G, Birge RR. 1985. Raman spectroscopic study of kaolinite in aqueous suspension. Clays Clay Miner 33:483–489.

    Article  Google Scholar 

  • Kamijo N, Umesaki N, Fukui K, Guy C, Tadanaga K, Tat-sumisago M, Minami T. 1994. Soft X-ray XAFS: Local structure of mullite gels prepared from modified aluminum alkoxides. J Non-Cryst Solids 177:187–192.

    Article  Google Scholar 

  • Keller-Besrest F, Benazeth S, Souleau C. 1994. Pharmatical silver doped clays: An EXAFS study from silver to silicon K-edges absorption. J Phys IV, colloque C9 4:299–302.

    Google Scholar 

  • Koningsberger DC, Miller JT. 1994. Local structure determination of aluminum in Y zeolite: Application of low energy X-ray absorption fine structure spectroscopy. Catal Lett 29:77–90.

    Article  Google Scholar 

  • Koningsberger DC, Prins R, editors. 1987. X-ray absorption: Principles, applications, techniques of EXAFS, SEXAFS, and XANES in chemical analysis. New York: J Wiley. 238 p.

    Google Scholar 

  • Laffon, C. 1990. Etude par absorption X de matériaux céramiques obtenus par pyrolyse de précurseurs organosilicies [Ph.D. dissertation]. Orsay, France: University of Paris-Sud. 141 p.

    Google Scholar 

  • Lagarde P, Flank A-M, Tourillon G, Liebermann R-C, Itie J-P. 1992. X-ray absorption near edge structure of quartz. Application to the structure of densified silica. J Phys 1:1043–1050.

    Google Scholar 

  • Landron C, Cote B, Massiot D, Coutures JP, Flank AM. 1992. Aluminum XAS and NMR spectroscopic studies of calcium aluminosilicate glasses. Phys Status Solid: B 171:9–20.

    Article  Google Scholar 

  • Ledoux R, White JL. 1964. Infrared study of the OH groups in expanded kaolinite. Science 143:244–246.

    Article  Google Scholar 

  • McKeown DA. 1989. Aluminum X-Ray absorption nearedge spectra of some oxyde minerals: Calculation versus experimental data. Phys Chem Miner 16:678–683.

    Article  Google Scholar 

  • McKeown DA, Waychunas GA, Brown GE. 1985. EXAFS study of the coordination environment of aluminum in a series of silica-rich glasses and selected minerals within the Na2O-Al2O3-SiO2 system. J Non-Cryst Solids 74:349–371.

    Article  Google Scholar 

  • Mercier F. 1994. Caracterisation par différentes techniques de surface des associations organominérales dans des milieux modèles des roches réservoir de pétrole [Ph.D. dissertation]. Orsay, France: University of Paris-Sud. 150 p.

    Google Scholar 

  • Michalowicz A. 1991. EXAFS pour le MAC. Logiciels pour la chimie. Paris: Société Française de Chimie, p 116–117.

    Google Scholar 

  • Nutting PG. 1934. Some physical and chemical properties of reservoir rocks bearing on the accumulation discharge of oil. In: Wrather WE, Lahee FH, editors. Problems of petroleum geology. Tulsa, OK: Amer Assoc Petrol Geol. p 825–832.

    Google Scholar 

  • Oinuma K, Hayashi H. 1965. Infrared study of mixed-layer clay minerals. Am Min 50:1213–1227.

    Google Scholar 

  • Prost R, Dameme A, Driard J, Leydecker JP. 1989. Infrared study of structural OH in kaolinite, dicktite, nacrite and poorly crystalline kaolinite at 5 to 600 K. Clays Clay Miner 37:464–468.

    Article  Google Scholar 

  • Raupach M, Barron PF, Thompson JG. 1987. Nuclear magnetic resonance, infrared, and X-ray powder diffraction study of dimethylselenoxyde intercalates with kaolinite. Clays Clay Miner 35:208–219.

    Article  Google Scholar 

  • Robert M, Tessier D. 1974. Méthode de préparation des argiles des sols pour des études minérologiques. Ann Agron 25:859–882.

    Google Scholar 

  • Roberts KJ, Robinson J, Davies TW, Hooper RM. 1993. Using soft X-ray adsorption spectroscopy to examine the structural changes taking place around Si and Al atoms in kaolinite following flash calcination. J Appl Phys 32:652–654.

    Article  Google Scholar 

  • Rothbauer R. 1971. Untersuchung eines 2MrMuscovits mit Neutronenstrahlen. Neues Jahrbuch fuer Mineralogie. Frankfurt: Institut f. Kristallographie, p 143–144.

    Google Scholar 

  • Saada A. 1995. Origine des différences de propriétés de surface responsables des contrastes de mouilabilité des minéraux argileux des gisements pétroliers [Ph.D. dissertation]. Mulhouse, France: University of Haute-Alsace. 143 p.

    Google Scholar 

  • Saada A, Siffert B, Papirer E. 1995. Comparison of the hy-drophilicity/hydrophobicity of illites and kaolinites. J Colloid Interface Sci 174:185–190.

    Article  Google Scholar 

  • Siffert B, Jada A, Wersinger E. 1992. Anionic surfactant adsorption on to asphalt-covered clays. Colloids Surf 69:41–45.

    Article  Google Scholar 

  • Sugahara Y, Satokawa S, Kuroda K, Kato C. 1988. Evidence for the formation of interlayer polyacrylonitrile in kaolinite. Clays Clay Miner 36:343–348.

    Article  Google Scholar 

  • Sugahara Y, Satokawa S, Kuroda K, Kato C. 1990. Preparation of a kaolinite-polyacrylamide intercalation compound. Clays Clay Miner 37:137–143.

    Article  Google Scholar 

  • Teo BK. 1986. EXAFS: Basic principles and data analysis. Inorganic chemistry concepts, vol 9. New York: Springer-Verlag. 349 p.

    Book  Google Scholar 

  • Tunney JJ, Detellier C. 1994. Preparation and characterization of two distinct ethylene glycol derivatives of kaolinite. Clays Clay Miner 42:552–560.

    Article  Google Scholar 

  • Van Oss CJ. 1992. Determination of contact angles and pores sizes of porous media by column and thin-layer wicking. J Adhesion Sci Technol 6:413–428.

    Article  Google Scholar 

  • Van Oss CJ. 1993. Acid-base interfacial interactions in aqueous media. Colloids Surf 78:1–49.

    Article  Google Scholar 

  • Yan N, Masliyah JH. 1994. Adsorption and desorption of clay particles at the oil-water interface. J Colloid Interface Sci 168:386–392.

    Article  Google Scholar 

  • Yariv S. 1992. Wettability of clay minerals. In: Schrader ME, Loeb GI, editor. Modern approach to Wettability, theory and applications, vol 11. tNew York: Plenum Pr. p 279–326.

    Article  Google Scholar 

  • Zoungrana T. 1994. Aspect énergétique de l’interface solideliquide et étude de l’altération de mouillabilité des solides [Ph.D. dissertation]. Montpellier, France: University of Montpellier II. p 82–88.

    Google Scholar 

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  1. Laboratoire pour l’Utilisation du Rayonnement Electromagnétique, CNRS-CEA-MENESRIP, bâtiment 209D, Université Paris-Sud, 91 405, Orsay, France

    Jean-Louis Bantignies, Christophe Cartier dit Moulin & Hervé Dexpert

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  1. Jean-Louis Bantignies
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  2. Christophe Cartier dit Moulin
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  3. Hervé Dexpert
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Bantignies, JL., Cartier dit Moulin, C. & Dexpert, H. Wettability Contrasts in Kaolinite and Illite Clays: Characterization by Infrared and X-Ray Absorption Spectroscopies. Clays Clay Miner. 45, 184–193 (1997). https://doi.org/10.1346/CCMN.1997.0450206

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  • DOI: https://doi.org/10.1346/CCMN.1997.0450206

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