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A Polarized Infrared and X-Ray Study of Lysine-Vermiculite

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Clays and Clay Minerals

Abstract

Lysine and vermiculite form a stable, ordered, interlamellar complex which has a well defined superlattice structure with respect to the ab-plane of vermiculite. The lysine molecules lie at a low angle to the silicate surfaces and establish a double layer network between such surfaces. I.R. and chemical data for the complex are given. The possible role of hydrogen bonds in linking the system together is considered.

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References

  • Adamowicz, R. and Fishman, E. (1972) Some observations of the vibrational spectrum of single crystalline b-alanine: Spectrochim, Acta 28A, 889–895.

    Article  Google Scholar 

  • Farmer, V. C. (1971) The characterization of adsorption bonds in clays by i.r. spectroscopy: Soil Sci. 112, 62–68.

    Article  Google Scholar 

  • Flournoy, P. A. and Schaffers, W. J. (1966) Attenuated total reflection spectra from surfaces of anisotropic, absorbing films: Spectrochim. Acta. 22, 5–13.

    Article  Google Scholar 

  • Fraser, R. D. B. and Suzuki, E. (1969) Resolution of overlapping bands: functions for simulating band shapes: Anal. Chem. 41, 37–39.

    Article  Google Scholar 

  • Fripiat, J. J., Pennequin, M., Poncelet, G. and Cloos, P. (1969) The influence of the Van Der Waals force on the i.r. spectra of short aliphatic alkylammonium cations held on montmorillonite: Clay Minerals 8, 119–134.

    Article  Google Scholar 

  • Garrett, W. (1962) Complexes of vermiculite with amino acids: 1st Australian Conf. on Clay Minerals and Related Topics, Melbourne. Abstracts of papers.

    Google Scholar 

  • Garrett, W. G. and Walker, G. F. (1962) Swelling of some vermiculite-organic complexes in water: Clays and Clay Minerals 9, 557–567.

    Article  Google Scholar 

  • Jang, S. D. and Condrate, R. A. (1972) The i.r. spectra of lysine adsorbed on several cation-substituted montmorillonites: Clays and Clay Minerals 20, 79–82.

    Article  Google Scholar 

  • Koetzle, T. F., Lehman, M. S., Verbist, J. J. and Hamilton, W. C. (1972) Precision neutron diffraction structure determination of protein and nucleic acid components—VII. The crystal and molecular structure of the amino acid l-lysine monohydrochloride dihydrate: Acta Cryst. B28, 3207–3213.

    Article  Google Scholar 

  • Mathieson, A. McL. and Walker, G. F. (1954) Crystal structure of magnesium vermiculite: Am. Miner. 39, 231–255.

    Google Scholar 

  • Mifsud, A., Fornes, V. and Rausell-Colom, J. A. (1970) Cationic complexes of vermiculite with l-ornithine: Reunion Hispano-Belga de Minérales de la Arcilla, Madrid. 121–127.

    Google Scholar 

  • Norrish, K. and Hutton, J. T. (1969) An accurate X-ray spectrographic method for the analysis of a wide range of geological samples: Geochim. Cosmochim. Acta 33, 431–453.

    Article  Google Scholar 

  • Norrish, K. (1972) Factors in the weathering of mica to vermiculite: Preprints, Int. Clay Conf., Madrid. 2, 83–101.

    Google Scholar 

  • Pearson, J. F. and Slifkin, M. A. (1972) The i.r. spectra of amino acids and dipeptides. Spectrochim. Acta 28A, 2403–2417.

    Article  Google Scholar 

  • Rausell-Colom, J. A. and Salvador, P. S. (1971). Gelification de vermiculite dans des solutions d’acide γ-amino-butyrique. Clay Minerals 9, 193–208.

    Article  Google Scholar 

  • Serratosa, J. M., Johns, W. D. and Shimoyama, A. (1970) I.r. study of alkylammonium vermiculite complexes: Clays and Clay Minerals 18, 107–113.

    Article  Google Scholar 

  • Suzuki, S. and Shimanouchi, T. (1963) Normal vibrations of glycine and deuterated glycine molecules: Spectrochim. Acta 19, 1195–1208.

    Article  Google Scholar 

  • Takenaka, T., Nogami, K., Gotoh, H. and Gotoh, R. (1971) Studies on built-up films by means of polarized infrared ATR spectrum—I. Built-up films of stearic acid: J. Colloid Interface Sci. 35, 395–402.

    Article  Google Scholar 

  • Tsuboi, M., Takenishi, T. and Nakamura, A. (1963) Some characteristic frequencies of amino acids: Spectrochim. Acta 19, 271–284.

    Article  Google Scholar 

  • Walker, G. F. (1960) Macroscopic swelling of vermiculite crystals in water: Nature, Land. 187, 312–313.

    Article  Google Scholar 

  • Walker, G. F. and Garrett, W. G. (1961) Complexes of vermiculite with amino-acids Nature, Lond. 191, 1389.

    Article  Google Scholar 

  • Walker, G. F. (1967) Interactions of n-alkylammonium ions with mica-type layer lattices: Clay Minerals 7, 129–143.

    Article  Google Scholar 

  • Zoltai, T. (1963) Double spots and their elimination in precession photography: Am. Miner. 48, 759–771.

    Google Scholar 

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Raupach, M., Slade, P.G., Janik, L. et al. A Polarized Infrared and X-Ray Study of Lysine-Vermiculite. Clays Clay Miner. 23, 181–186 (1975). https://doi.org/10.1346/CCMN.1975.0230303

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  • DOI: https://doi.org/10.1346/CCMN.1975.0230303

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