Abstract
Lysine and vermiculite form a stable, ordered, interlamellar complex which has a well defined superlattice structure with respect to the ab-plane of vermiculite. The lysine molecules lie at a low angle to the silicate surfaces and establish a double layer network between such surfaces. I.R. and chemical data for the complex are given. The possible role of hydrogen bonds in linking the system together is considered.
Similar content being viewed by others
References
Adamowicz, R. and Fishman, E. (1972) Some observations of the vibrational spectrum of single crystalline b-alanine: Spectrochim, Acta 28A, 889–895.
Farmer, V. C. (1971) The characterization of adsorption bonds in clays by i.r. spectroscopy: Soil Sci. 112, 62–68.
Flournoy, P. A. and Schaffers, W. J. (1966) Attenuated total reflection spectra from surfaces of anisotropic, absorbing films: Spectrochim. Acta. 22, 5–13.
Fraser, R. D. B. and Suzuki, E. (1969) Resolution of overlapping bands: functions for simulating band shapes: Anal. Chem. 41, 37–39.
Fripiat, J. J., Pennequin, M., Poncelet, G. and Cloos, P. (1969) The influence of the Van Der Waals force on the i.r. spectra of short aliphatic alkylammonium cations held on montmorillonite: Clay Minerals 8, 119–134.
Garrett, W. (1962) Complexes of vermiculite with amino acids: 1st Australian Conf. on Clay Minerals and Related Topics, Melbourne. Abstracts of papers.
Garrett, W. G. and Walker, G. F. (1962) Swelling of some vermiculite-organic complexes in water: Clays and Clay Minerals 9, 557–567.
Jang, S. D. and Condrate, R. A. (1972) The i.r. spectra of lysine adsorbed on several cation-substituted montmorillonites: Clays and Clay Minerals 20, 79–82.
Koetzle, T. F., Lehman, M. S., Verbist, J. J. and Hamilton, W. C. (1972) Precision neutron diffraction structure determination of protein and nucleic acid components—VII. The crystal and molecular structure of the amino acid l-lysine monohydrochloride dihydrate: Acta Cryst. B28, 3207–3213.
Mathieson, A. McL. and Walker, G. F. (1954) Crystal structure of magnesium vermiculite: Am. Miner. 39, 231–255.
Mifsud, A., Fornes, V. and Rausell-Colom, J. A. (1970) Cationic complexes of vermiculite with l-ornithine: Reunion Hispano-Belga de Minérales de la Arcilla, Madrid. 121–127.
Norrish, K. and Hutton, J. T. (1969) An accurate X-ray spectrographic method for the analysis of a wide range of geological samples: Geochim. Cosmochim. Acta 33, 431–453.
Norrish, K. (1972) Factors in the weathering of mica to vermiculite: Preprints, Int. Clay Conf., Madrid. 2, 83–101.
Pearson, J. F. and Slifkin, M. A. (1972) The i.r. spectra of amino acids and dipeptides. Spectrochim. Acta 28A, 2403–2417.
Rausell-Colom, J. A. and Salvador, P. S. (1971). Gelification de vermiculite dans des solutions d’acide γ-amino-butyrique. Clay Minerals 9, 193–208.
Serratosa, J. M., Johns, W. D. and Shimoyama, A. (1970) I.r. study of alkylammonium vermiculite complexes: Clays and Clay Minerals 18, 107–113.
Suzuki, S. and Shimanouchi, T. (1963) Normal vibrations of glycine and deuterated glycine molecules: Spectrochim. Acta 19, 1195–1208.
Takenaka, T., Nogami, K., Gotoh, H. and Gotoh, R. (1971) Studies on built-up films by means of polarized infrared ATR spectrum—I. Built-up films of stearic acid: J. Colloid Interface Sci. 35, 395–402.
Tsuboi, M., Takenishi, T. and Nakamura, A. (1963) Some characteristic frequencies of amino acids: Spectrochim. Acta 19, 271–284.
Walker, G. F. (1960) Macroscopic swelling of vermiculite crystals in water: Nature, Land. 187, 312–313.
Walker, G. F. and Garrett, W. G. (1961) Complexes of vermiculite with amino-acids Nature, Lond. 191, 1389.
Walker, G. F. (1967) Interactions of n-alkylammonium ions with mica-type layer lattices: Clay Minerals 7, 129–143.
Zoltai, T. (1963) Double spots and their elimination in precession photography: Am. Miner. 48, 759–771.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Raupach, M., Slade, P.G., Janik, L. et al. A Polarized Infrared and X-Ray Study of Lysine-Vermiculite. Clays Clay Miner. 23, 181–186 (1975). https://doi.org/10.1346/CCMN.1975.0230303
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1346/CCMN.1975.0230303