Fabrication of Periodic Plasmonic Structures Using Interference Lithography and Chalcogenide Photoresist
- 957 Downloads
This study reports on the employment of the interference lithography (IL) technique, using photoresist based on the chalcogenide glass (ChG) films, for fabrication of one-dimensional (gratings) and two-dimensional (arrays) periodic plasmonic structures on the surface of glass plates. The IL technique was optimized for patterning of the Au and Al layers and formation of gratings and arrays with a spatial frequency of 2000 mm−1. Optical properties of obtained structures were studied using measurements of spectral and angular dependence of transmission and reflection of polarized light. It was shown that the spectral and angular position of the surface plasmon polariton and local surface plasmon resonance, which are observed in these samples, can be adjusted over a wide range by selecting the geometric parameters of structures and technological modes of their manufacturing.
KeywordsPlasmonic structures Plasmon resonance Chalcogenide photoresist Interference lithography
atomic force microscope
surface plasmon polaritons
PACS73.20 Mf 85.40 Hp 42.79.Dj
In recent years the attention of many researchers has attracted by metal plasmonic structures that play an important role in numerous fields of research and applications, for example, as a substrate for optical sensors based on plasmon resonance , or surface-enhanced Raman spectroscopy  as sub-wavelength optical elements , and others. These structures are formed by modern lithographic technologies: electron-beam or ion-beam lithography [4, 5], nanosphere lithography , nanoimprint lithography , deep ultraviolet lithography , and others. But all this techniques are expensive and poorly suitable for large area processing.
At the same time, the more simple and technological are interference lithography (IL), which can be used for the rapid fabrication of wafer-scale periodic nanostructures [9, 10]. IL is a large area fabrication technique that uses laser interference patterns for rapid formation of periodic structures such as gratings and bi-gratings (arrays). The total processed area depends on the beam intensity and coherence length of the laser and can be up to dozens, or even hundreds of square centimeters. For electron and ion processes, the one write-field typically is equal to several hundreds of square micrometers. For nanoimprint lithography based on the replication of nanostructures inscribed in a stamp using the same electron-beam lithography, the fabrication of the stamps is a slow and costly process. In addition, these stamps’ lifetime is no more than 100 prints . And even for nanosphere lithography, due to the non-zero size dispersion of the nanospheres, formed two-dimensional structure is divided into differing domains with sizes less than 100 μm.
In previous studies the authors have shown that IL with the use of chalcogenide photoresist is a promising technology for the formation of one- and two-dimensional submicron periodic structures on the surface of semiconductors and dielectrics [9, 12]. Chalcogenide photoresists based on thermal evaporated amorphous films of chalcogenide glasses (ChG) are characterized by high-resolution, optical uniformity, wide spectral range of photosensitivity [13, 14]. In addition, these photoresists possess a high refractive index ranging from 2.0 to 3.0 and are very perspective for immersion IL .
Photostimulated structural changes in vacuum-deposited films of chalcogenide glass have three components: reversible, irreversible, and transient (which occurs only during exposure of the photoresist and rapidly relax after switching off the light) [14, 15]. Using of chalcogenide films as photoresist traditionally was associated exactly with irreversible changes in their solubility. Recently, the possibility of realization IL on the reversible and transient photoinduced structural change of chalcogenide films was shown by authors of works [16, 17].
In this paper, we present investigations of the formation processes of one-dimensional (gratings) and two-dimensional (arrays) periodic metal structures on the surface of glass plates using IL and chalcogenide photoresist. The paper also studies the influence of thermal treatments on morphological characteristics and features of excited plasmons in golden submicron periodic structures.
The samples for our experiments were prepared by successive thermal vacuum deposition of 3-nm-thick (effective thickness) Cr adhesive layer, a layer of metal (Au) with a thickness of 20–120 nm and photoresist layer (As2S3 or GeSe3) with thicknesses from 50 to 300 nm onto polished glass substrates with a size of 50 mm × 50 mm at a residual pressure of 2 × 10−3 Pa. The deposition rate and films thicknesses were monitored in situ with a KIT-1 quartz thickness meter. After deposition, the film thicknesses were controlled using a MII-4 microinterferometer.
The recording of periodic structures on annealed ChG films was carried out using the interference pattern formed with a helium-cadmium laser (wavelength λ = 440 nm). The exposition value for the gratings recording (1D structures) was 0.2–0.5 J/cm2, and during the recording of the bi-gratings (2D structures), each exposition was decreased by 1.3–1.5 times. Two-dimensional periodic structures were formed by double exposure with the rotation of the sample between expositions on 90° around the normal. After exposure, the samples were chemically treated in non-water alkaline organic solutions to form a resistive mask in photoresist layer, through which the metal film was etched. After removing the photoresist residues in alkaline solution, washing and drying the metal periodic structure was obtained.
The surface patterns of obtained structures were examined with a Dimension 3000 Scanning Probe atomic force microscope (Digital Instruments Inc., Tonawanda, NY, USA) in the atomic force microscope (AFM) tapping mode.
Optical properties of fabricated 1D and 2D structures were studied using measurements of spectral and angular dependence of transmission and reflection of polarized light in the wavelength range 0.4–1.1 μm and angles of incidence of 10°–80°. The automated setup for such measurements consists of illuminator, a mechanical light chopper, a monochromator with Glan prism at the exit, and rotary table for samples. The intensity of the light reflection or transmission is measured by silicon photodetector; signal of which after amplification and demodulation is applied to the input of analog-to-digital converter. Such measurements allow to build the dispersion curves of excited optical modes and to identify their type.
Results and Discussion
To create a chalcogenide lithographic mask with specified parameters using IL, you must select the optimal thickness of photoresist, exposure time, selectivity of etchant, and time of the post-exposure etching. IL technology was applied in a mode of little over exposure of photoresist to provide a cycloid form of groove profile of periodic chalcogenide mask. By changing the time of selective etching of photoresist, it is possible to change the width of the elements of lithographic masks and, accordingly, the width of opened intervals between the elements of the mask through which there is a further etching of the metal layer. Etching of the photoresist was monitored in situ by registration of non-photoactive long wavelength light diffracted from relief structure which is formed in photoresist layer. For a given photo-resistive mask, a form of profile and duty cycle (the ratio of width to period) of the elements in the periodic structure, obtained as a result of wet etching of the metal layer through chalcogenide mask, were determined also by rate and time of metal etching.
Another method for controlling form of elements in periodic metallic structures is thermal treatment (annealing). Most clear effect of annealing manifested in the gold plasmonic structures. In  samples of thermally deposited gold layers with an effective thickness from 1 to 12 nm were investigated in detail, in particular, the effect of annealing in air at temperatures from 250 to 450 °C on morphological and optical properties of disordered Au nanoislands. It was found that in the temperature range 350–450 °C, Au nanoislands of the spherical and ellipsoidal shapes are formed, and the morphology of the Au island film and their plasmon resonance spectrum depends noticeably on the nominal Au thickness and post-annealing temperature, while the duration of annealing is of minor importance.
This paper studied the effect of annealing in vacuum at temperatures from 350 to 450 °C on morphological and optical properties of Au periodic structures, formed by IL using chalcogenide photoresist. It was found that the optimum temperature for our samples with Au thicknesses from 30 to 60 nm is 400 °C—at lower temperatures insufficient effect of annealing, at 450 °C begins formation of agglomerates and disordering of the structure.
By using the expressions (1–2), the dispersion curves for SPPs, excited at interfaces metal/air or metal/substrate, were built in the coordinates “angle of excitation” versus “wavelength,” which is shown in Figs. 7 and 8. For calculations, the optical constants of gold from  were used, and the refractive index of the substrate was taken equal to ns = 1.48. For a given gratings geometry and optical constants, it is possible excitation of modes with m = +1 (1, 1s); m = +2 (2, 2s); m = −1 (1′, 1s′); m = −2 (2′, 2s′); at the interface air/gold (1, 1′, 2, 2′) and gold/substrate (1s, 1s′, 2s, 2s′).
Excited SPP waves with m = −1 are most intense on the unannealed samples of diffraction gratings (1′, 1s′ Fig. 7a), because the edges of grating grooves (nanowires) are closer to each other, than in annealed structures, and SPP meets with less resistance when spread along the surface. Due to considerable contact area between nanowires and substrate for the unannealed samples, the mode, which excited on the gold-substrate interface (1s′ on Fig. 7a), is intense. Excitation of LP is hardly noticeable on the background of intense SPPs.
After annealing, due to «shrinkage» of Au nanowires and islands in a more compact structure and, consequently, increase the distance between the edges of nanowires or nanodots, the intensity of SPP decreases, especially decreases mode 1s′, while mode 1′ (excited on the gold/air interface) remains moderately intense (Fig. 7b). Also, after annealing on the background of a significant reduction of SPP intensity, the LP intensity increases significantly, which is most clearly seen on the annealed 2D structure (Fig. 8b) in spectral region λ = 0.6–0.8 μm.
It is shown that IL technology using vacuum chalcogenide photoresist in combination with additional thermal treatment enabled the successful fabrication of uniform plasmonic structures with required characteristics (spatial frequency, depth of relief, a form of element profile) on a large area substrates (up to 25 cm2). The results of optical measurement confirm the excitation of surface plasmon polariton and local surface plasmon resonance in fabricated samples, spectral, and angular position of which coincides with the predictions of the theory and can be adjusted over a wide range by selecting the geometric parameters of structures and technological modes of their manufacturing.
- 12.Indutnyi I, Min’ko V, Shepelyavyi P, Sopinskyy M, Tkach V, Dan’ko V (2011) Growth of the photonic nanostructures using interference lithography and oblique deposition in vacuum. Optoelectronika I Poluprovodnikova Tehnika (Ukraine) 46:47–54Google Scholar
- 14.Indutnyy I, Kostyshyn M, Kasjarum I, Min’ko V, Michailovska E, Romanenko P (1992) Photostimulated interactions in metal-semiconductor structures. Naukova Dumka, Kyiv, p 240Google Scholar
- 15.Kolobov AV, Tanaka K (1998) Nanoscale mechanism of photo-induced metastability and reversible photodarkening in chalcogenide vitreous semiconductors. Phizika i Tehnika Poluprovodnikov (Russia) 32:899–904Google Scholar
- 17.Dan’ko V, Indutnyi I, Min’ko V, Shepeliavyi P, Lykanyuk M, Litvin O (2012) Interference photolithography using photoetching effect in chalcogenide films. J Non-Oxide Glasses 3:13–18Google Scholar
- 18.Yukhymchuk VO, Kostyukevych SA, Dzhagan VM, Milekhin AG, Rodyakina EE, Yanchuk IB, Shepeliavy PY, Valakh MY, Kostyukevych KV, Lysiuk VO, Tverdokhlib IV (2012) SERS of Rhodamine 6G on substrates with laterally ordered and random gold nanoislands. Semicond Phys Quantum Electron Optoelectron 15:232–238CrossRefGoogle Scholar
- 19.Dmitruk NL, Litovchenko VG, Strygewskyy VL (1989) Surface polaritons in semiconductors and dielectrics. Naukova Dumka, Kyiv, p 375Google Scholar
- 20.Surface polaritons. Electromagnetic waves on the surfaces and interfaces Under. Agranovich VM, Mills DL (ed). Nauka, Moscow; 1985. p 525Google Scholar
- 24.Dmitruk NL, Malinich SZ (2014) Surface plasmon resonances and their manifestation in the optical properties of nanostructures of noble metals. Ukr J Phys Rev 9:3–37Google Scholar
Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.