Commercial multi-walled carbon nanotubes (CNT) were functionalized by oxidation with HNO3, to introduce oxygen-containing surface groups, and by thermal treatments at different temperatures for their selective removal. The obtained samples were characterized by adsorption of N2 at -196°C, temperature-programmed desorption and determination of pH at the point of zero charge. CNT/poly(vinylidene fluoride) composites were prepared using the above CNT samples, with different filler fractions up to 1 wt%. It was found that oxidation reduced composite conductivity for a given concentration, shifted the percolation threshold to higher concentrations, and had no significant effect in the dielectric response.
Carbon nanotubes (CNTs) have attracted particular interest because of their remarkable mechanical and electrical properties . The combination of these properties with very low densities suggests that CNTs are ideal candidates for high-performance polymer composites . In order to increase the application range of polymers, highly conductive nanoscale fillers can be incorporated into the polymeric matrix. As CNTs present high electrical conductivity (103-104 S/cm), they have been widely used . Therefore, CNT/polymer composites are expected to have several important applications, namely, in the field of sensors and actuators . However, in order to properly tailor the composite material properties for specific applications, the relevant conduction mechanisms must be better understood.
The experimental percolation thresholds for CNT composites results in a wide range of values for the same type of CNT/polymer composites , being a deviation from the bounds predicted by the excluded volume theory and a dispersion for the values of the critical exponent (t) [6, 7]. It was demonstrated that the conductivity of CNT/polymer composites can be described by a single junction expression  and that the electrical properties also strongly depend on the characteristics of the polymer matrix . This article explores the effects of nanotubes surface modifications in the electrical response of the composites.
Preparation and characterization of the modified CNT samples
Commercial multi-walled CNTs (Nanocyl - 3100) have been used as received (sample CNTs). Further details on this material can be found elsewhere . CNTs sample was functionalized by oxidation under reflux with HNO3 (7 M) for 3 h at 130°C, followed by washing with distilled water until neutral pH, and drying overnight at 120°C (sample CNTox was obtained). The CNTox material was heat treated under inert atmosphere (N2) at 400°C for 1 h (sample CNTox400) and at 900°C for 1 h (sample CNTox900), to selectively remove surface groups. The obtained samples were characterized by adsorption of N2 at -196°C, temperature-programmed desorption (TPD) and determination of pH at the point of zero charge (pHPZC) from acid-base titration according to the method of the literature . The total amounts of CO and CO2 evolved from the samples were obtained by integration of the TPD spectra.
Polymer films with thicknesses between 40 and 50 μm were produced by mixing different amounts of CNT (from 0.1 to 1.0%) with N, N-dimethylformamide (DMF, Merck 99.5%) and PVDF (Solef 1010, supplied by Solvay Inc., molecular weight = 352 × 103 g/mol) according to the procedure described previously . Solvent evaporation, and consequent crystallization, was performed inside an oven at controlled temperature. The samples were crystallized for 60 min at 120°C to ensure the evaporation of all DMF solvents. After the crystallization process, the samples were heated until 230°C and maintained at that temperature for 15 min to melt and erase all polymer memory. This procedure produced α-PVDF crystalline phase samples .
Topography of the samples and CNT distribution was performed by scanning electron microscopy (SEM, FEI - NOVA NanoSEM 200). The dielectric response of the nanocomposites was evaluated by dielectric measurements with a Quadtech 1920. Circular gold electrodes of 5-mm diameter were evaporated by sputtering onto both sides of each sample. The complex permittivity was obtained by measuring the capacity and tan δ in the frequency range of 100 Hz to 100 kHz at room temperature. The volume resistivity of the samples was obtained by measuring the characteristic I-V curves at room temperature using a Keithley 6487 picoammeter/Voltage source.
Results and discussion
Characterization of CNT samples
Oxidations with HNO3 originate materials with large amounts of surface acidic groups, mainly carboxylic acids and, to a smaller extent, lactones, anhydrides, and phenol groups [10, 13, 14]. These oxygenated groups (Figure 1) are formed at the edges/ends and defects of graphitic sheets . The different surface-oxygenated groups created upon oxidizing treatments decompose by heating, releasing CO and/or CO2, during a TPD experiment. As this release occurs at specific temperatures, identification of the surface groups is possible [10, 13, 14]. It is well known that CO2 formation results from the decomposition of carboxylic acids at low temperature, and lactones at higher temperature; carboxylic anhydrides originate both CO and CO2; phenols and carbonyl/quinone groups produce CO [10, 13, 14].
Figure 2 shows the TPD spectra of the CNT before and after the different treatments. It is clear that the treatment with HNO3 produces a large amount of acidic oxygen groups, such as carboxylic acids, anhydrides, and lactones, which decompose to release CO2. Part of these groups (carboxylic acids) is removed by heating at 400°C. A treatment at 900°C removes all the groups, so that the obtained sample is similar to the original. The total amounts of CO and CO2 evolved from the samples, obtained by integration of the TPD spectra, are presented in Table 1.
All the samples release higher amounts of CO than CO2 groups (Table 1). The CNTox sample has the highest amount of surface oxygen. This sample also presents the lowest ratio CO/CO2 and the lowest value of pHPZC, indicating that this is the most acidic sample. CNTox900 presents the highest CO/CO2 ratio, suggesting the less-acidic characteristics, which matches well with the pHPZC results (Table 1). The acidic character of the samples decreases by increasing the thermal treatment temperature, since the acidic groups are removed at lower temperatures than neutral and basic groups, as seen in previous studies [10, 13, 14].
The CNT samples have N2 adsorption isotherms of type II (not shown), as expected for non-porous materials . The surface areas of the samples, calculated by the BET method (SBET), are included in Table 1. It can be observed that the oxidation treatments lead to an increase of the specific surface area. This occurs because the process opens the endcaps of CNTs and creates sidewall openings . The specific surface areas of the samples slightly increase as the thermal treatment temperature increases, since carboxylic acids and other groups, introduced during oxidation, are removed.
Composites processing and characterization
The morphology and fiber distribution of the composite samples were analyzed by SEM to evaluate the CNT dispersion in the polymeric matrix and determine how the composites influence the polymer crystallization microstructure. Figure 3 shows the SEM images for the PVDF/CNT composites. The main relevant microstructural feature of the composite is that the CNT are randomly distributed into the polymeric matrix. The spherulitic structure characteristic of the pure PVDF is still present in all the composites samples [12, 18].
CNT agglomerates are nevertheless more often observed for the CNTox composites samples, especially for the ones treated at the highest temperatures. With respect to the electrical properties, oxidation reduces the composite conductivity for a given concentration and shifts the percolation threshold to higher concentrations (Figure 4). This behavior is mainly due to the reduction of the surface conductivity of the CNTs due to the oxidation process , and is similar for all the functionalized composites. Further, the increase of surface area due to the functionalization treatment certainly causes surface defects on the CNTs that also reduced electrical conductivity. The increase of agglomerations for the treated samples should not have, on the other hand, a large influence in the electrical response . A change of several orders of magnitude of the electrical resistivity with increasing CNTs concentration was observed for all samples, indicating a percolative behavior of the nanocomposites. In general, both in surface (not shown) and in bulk resistivity (Figure 4a), the percolation threshold appears between 0.2 wt.% for the original CNT samples and shifts to 0.5 wt.% CNTs for the functionalized nanocomposites.
Dielectric measurements show that the incorporation of the CNT in the PVDF matrix but leads to a gradual increase of the dielectric constant (ε') as the amount of the filler is increased (Figure 4b). The increase of the ε' is larger for the pristine CNT. A maximum for the 0.5% pristine CNT sample with ε' 22 at a frequency of 10 kHz at room temperature was found, whereas for the functionalized nanocomposites the value is 16. The frequency behavior of the dielectric permittivity is similar to the one obtained for the pure polymer, except for an increase of the low frequency dielectric constant and dielectric loss (not shown) with increasing CNT loading due to interfacial polarization effects (Figure 4b). No noticeable differences have been observed for the different oxidation treatments in terms of the dielectric response. In a previous study , it was demonstrated that an increase in the dielectric constant is related with the formation of a capacitor network.
The effect of surface modifications of multi-walled CNTs on the electrical response of CNT/PVDF nanocomposites has been investigated. The main effect of oxidation is a reduction of the composite conductivity for a given concentration and a shift of the percolation threshold to higher concentrations. On the other hand, no significant differences have been observed between the nanocomposites prepared with the different functionalized CNTs. The reduction of the electrical surface conductivity of the CNT due to the oxidation process, together with an increase of the surface area and defect formation, is at the origin of the observed effects.
scanning electron microscopy.
Serp P, Corrias M, Kalck P: 'Carbon nanotubes and nanofibers in catalysis'. Appl Catal A 2003, 253: 337. 10.1016/S0926-860X(03)00549-0
Shaffer MSP, Sandler JKW: Carbon Nanotube/Nanofibre Polymer Composites, in Processing and Properties of Nanocomposites. New York: World Scientific; 2006.
Al-Saleh MH, Sundararaj U: 'A review of vapor grown carbon nanofiber/polymer conductive composites'. Carbon 2009, 47: 2. 10.1016/j.carbon.2008.09.039
Thostenson ET, Li CY, Chou TW: 'Nanocomposites in context'. Compos Sci Technol 2005, 65: 491. 10.1016/j.compscitech.2004.11.003
Bauhofer W, Kovacs JZ: 'A review and analysis of electrical percolation in carbon nanotube polymer composites'. Compos Sci Technol 2009, 69: 1486. 10.1016/j.compscitech.2008.06.018
Stauffer D, Aharony A: Introduction to Percolation Theory. London: Taylor and Francis; 1992.
Celzard A, Mcrae E, Deleuze C, Dufort M, Furdin G, Mareche JF: 'Critical concentration in percolating systems containing a high-aspect-ratio filler'. Phys Rev B 1996, 53: 6209. 10.1103/PhysRevB.53.6209
Cardoso P, Silva J, Paleo AJ, Van Hattum FWJ, Simões R, Lanceros-Mendez S: 'The dominant role of tunneling in the conductivity of carbon nanofiber-epoxy composites'. Phys Status Solidi A Appl Mater Sci 2010, 207: 407. 10.1002/pssa.200925334
Costa P, Silva J, Sencadas V, Costa CM, Van Hattum FWJ, Rocha JG, Lanceros-Mendez S: 'The effect of fibre concentration on the alpha to beta-phase transformation, degree of crystallinity and electrical properties of vapour grown carbon nanofibre/poly(vinylidene fluoride) composites'. Carbon 2009, 47: 2590. 10.1016/j.carbon.2009.05.011
Gonçalves AG, Figueiredo JL, Órfão JJM, Pereira MFR: 'Influence of the surface chemistry of multi-walled carbon nanotubes on their activity as ozonation catalysts'. Carbon 2010, 48: 4369.
Rivera-Utrilla J, Bautista-Toledo I, Ferro-García MA, Moreno-Castilla C: 'Activated carbon surface modifications by adsorption of bacteria and their effect on aqueous lead adsorption'. J Chem Technol Biotechnol 2001, 76: 1209. 10.1002/jctb.506
Sencadas V, Gregorio R, Lanceros-Méndez S: 'alpha to beta Phase Transformation and Microestructural Changes of PVDF Films Induced by Uniaxial Stretch'. J Macromol Sci B Phys 2009, 48: 514. 10.1080/00222340902837527
Figueiredo JL, Pereira MFR, Freitas MMA, Órfão JJM: 'Characterization of active sites on carbon catalysts'. Ind Eng Chem Res 2007, 46: 4110. 10.1021/ie061071v
Figueiredo JL, Pereira MFR, Freitas MMA, Órfão JJM: 'Modification of the surface chemistry of activated carbons'. Carbon 1999, 37: 1379. 10.1016/S0008-6223(98)00333-9
Banerjee S, Hemraj-Benny T, Wong S: 'Covalent surface chemistry of single-walled carbon nanotubes'. Adv Mater 2005, 17: 17. 10.1002/adma.200401340
Sing KSW, Everett DH, Haul RAW, Moscou L, Pierotti RA, Rouquerol J, Siemieniewska T: 'Reporting physisorption data for gas solid systems with special reference to the determination of surface-area and porosity'. Pure Appl Chem 1985, 57: 603. 10.1351/pac198557040603
Monthioux M, Smith BW, Burteaux B, Claye A, Fischer JE, Luzzi DE: 'Sensitivity of single-wall carbon nanotubes to chemical processing: An electron microscopy investigation'. Carbon 2001, 39: 1251. 10.1016/S0008-6223(00)00249-9
Silva MP, Sencadas V, Botelho G, Machado AV, Rolo AG, Rocha JG, Lanceros-Mendez S: 'alpha- and gamma-PVDF: Crystallization kinetics, microstructural variations and thermal behaviour'. Mater Chem Phys 2010, 122: 87. 10.1016/j.matchemphys.2010.02.067
Simões R, Silva J, Vaia R, Sencadas V, Costa P, Gomes J, Lanceros-Méndez S: 'Low percolation transitions in carbon nanotube networks dispersed in a polymer matrix: dielectric properties, simulations and experiments'. Nanotechnology 2009, 20: 035703.
The authors thank the Fundação para a Ciência e a Tecnologia (FCT), Portugal, for financial support through the projects PTDC/CTM/69316/2006 and NANO/NMed-SD/0156/2007), and CIENCIA 2007 program for SAC. V.S. and J.N.P. also thank FCT for the SFRH/BPD/63148/2009 and SFRH/BD/66930/2009 grants.
The authors declare that they have no competing interests.
SACC performed the functionalisation and characterisation of carbon nanotubes samples and drafted the manuscript. JNP, CP, and VS participated in the nanocomposite samples processing, experimental measurements, analysis and interpretation of the results. MFRP and SL-M conceived and coordinated the research work and carried out analysis and interpretation of the experimental results. All authors read and approved the final manuscript.
About this article
Cite this article
Carabineiro, S.A., Pereira, M.F., Pereira, J.N. et al. Effect of the carbon nanotube surface characteristics on the conductivity and dielectric constant of carbon nanotube/poly(vinylidene fluoride) composites. Nanoscale Res Lett 6, 302 (2011). https://doi.org/10.1186/1556-276X-6-302
- Percolation Threshold
- Surface Group
- Dielectric Response
- Vinylidene Fluoride
- Composite Conductivity