Abstract
The non-radiative decay rates of triplet benzene and 2-chloronaphthalene were determined as a function of excitation energy. As the excitation energies were increased, the non-radiative decay rates increased gradually. In the case of 2-chloronaphthalene it increased rapidly for the excitation energies above about 38000 cm-1.
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References
A.P. Marchetti and D.R. Kearns, J. Am. Chem. Soc. 89, 768 (1967).
S. Kamei, H. Abe, N. Mikami, and M. Ito, J. Phys. Chem. 89, 3636 (1985).
T. Suzuki, M. Sato, N. Mikami, and M. Ito, Chem. Phys. Lett. 127, 292 (1986).
T. Ishizuya, T. Hikida, and Y. Mori, J. Photochem. and Photobiol. A: Chem. 48, 33 (1989).
C.S. Parmenter and M.W. Schuyler, Chem. Phys. Lett. 6, 339 (1970).
M.A. Duncan, T.G. Dietz, M.G. Liverman, and R.E. Smalley, J. Phys. Chem. 85, 7 (1981).
G.A. George and G.C. Morris, J. Molecul. Spectrosc. 26, 67 (1968).
J.C. Hsieh and E.C. Lim. J. Chem. Phys. 61, 736 (1974).
C.S. Parmenter and H.M. Poland, J. Chem. Phys. 51, 1551 (1969).
A.Z. Moss and J.T. Yardley, J. Chem. Phvs. 61, 2883 (1974).
M. Fujita, T. Ishizuya, T. Hikida, and Y. Mori, Chem. Phys. 139, 261 (1989).
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Hatai, M., Ide, Y. & Hikida, T. Non-radiative decay rate of vibrationally excited triplet molecules. Res Chem Intermed 19, 97–102 (1993). https://doi.org/10.1163/156856793X00019
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DOI: https://doi.org/10.1163/156856793X00019