Skip to main content
Log in

C-alkylation of m-cresol with n- and iso-propanol over iron catalyst

  • Published:
Research on Chemical Intermediates Aims and scope Submit manuscript

Abstract

The gas-phase alkylation of m-cresol (3-methylphenol) with n-and iso-propanol was investigated. The reactions were carried out in a continuous process at atmospheric pressure over an iron catalyst that contains Cr, Si and K oxides. It is possible to obtain n and iso-propyl derivatives of m-cresol with satisfactory selectivity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. H.-G. Franc and J. W. Stadelhofer, Industrial Aromatic Chemistry. Springer-Verlag, Berlin, Heidelberg (1988).

    Google Scholar 

  2. R. Dowbenko, in: Kirk-Othmer Encyclopediaof Chemical Technology, 4th edn, J. I. Kroschowitz and M. Houl-Grant (Eds), p. 106. Wiley, New York (1992).

    Google Scholar 

  3. J. H. Gilks, J. of Institute of Petroleu m 50, 309 (1964).

    Google Scholar 

  4. J. Wrzyszcz and H. Grabowska, Polish J. Chem. Technol. 1, 50 (1999).

    Google Scholar 

  5. H. Grabowska, W. Miśta, L. Syper, J. Wrzyszcz and M. Zawadzki, J. Catal. 160, 134 (1996).

    Google Scholar 

  6. H. Grabowska, W. Kaczmarczyk and J. Wrzyszcz, Appl. Catal. 47, 351 (1989).

    Google Scholar 

  7. H. Grabowska and J. Wrzyszcz, Res. Chem. Intermed. 17, 263 (1992).

    Google Scholar 

  8. H. Grabowska, L. Syper and J. Wrzyszcz, Res. Chem. Intermed. 24, 47 (1998).

    Google Scholar 

  9. H. Grabowska, J. Wrzyszcz and S. Ch. Joshi, Res. Chem. Intermed. 25, 425 (1999).

    Google Scholar 

  10. H. Grabowska, W. Miśta, L. Syper, J. Wrzyszcz and M. Zawadzki, Angew. Chem. Int. Ed. Engl. 35, 1562 (1996).

    Google Scholar 

  11. S. Sato, R. Takahashi, T. Sodesawa, K. Matsumoto and Y. Kamimura, J. Catal. 184, 180 (1999).

    Google Scholar 

  12. N. V. Yanishlieva, E. M. Marinova, M. H. Gordon and V. G. Raneva, Food Chem. 64, 59 (1999).

    Google Scholar 

  13. T. Yamanaka, Bull. Chem. Soc. Jpn. 49, 2669 (1976).

    Google Scholar 

  14. M. Nitta, K. Yamaguchi and K. Aomura, Bull. Chem. Soc. Jpn. 47, 2897 (1974).

    Google Scholar 

  15. M. Nitta, K. Aomura and K. Yamaguchi, Bull. Chem. Soc. Jpn. 47, 2360 (1974).

    Google Scholar 

  16. S. Velu and S. Sivasanker, Res. Chem. Intermed. 24, 657 (1998).

    Google Scholar 

  17. J. Wrzyszcz, H. Grabowska, W. Miśta, L. Syper and M. Zawadzki, Appl. Catal. A: General 166, L249 (1998).

    Google Scholar 

  18. S. Velu and C. S. Swamy, Res. Chem. Intermed. 26, 295 (2000).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Grabowska, H., Wrzyszcz, J. C-alkylation of m-cresol with n- and iso-propanol over iron catalyst. Research on Chemical Intermediates 27, 281–285 (2001). https://doi.org/10.1163/156856701300356491

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1163/156856701300356491

Keywords

Navigation