Abstract.
We discuss the symmetry properties as well as the macroscopic behavior of the cubic liquid crystal phases showing large chiral domains of either hand in some non-chiral compounds reported recently in the group of Tschierske. These phases are tricontinuous. While they have O or I432 symmetry in each chiral domain, the overall symmetry is \( I m \bar{3} m\) as there is no net chirality for compounds composed of non-chiral molecules. It turns out that a rather similar type of phase has also been reported for triblock copolymers. Here we analyze in detail the macroscopic static and dynamic behavior of such phases and we predict, among other results, that they show the analog of static and dissipative Lehmann-type effects in their chiral domains. A description of a cubic liquid crystalline phase of Th symmetry, which has not yet been found experimentally, is also included. Suggestions for experiments are outlined to identify such a phase. In addition, we discuss tetragonal liquid crystalline phases of D4h and D4 (I422) symmetry as they have been reported last year experimentally in connection to the Q phase.
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References
C. Dressel, F. Liu, M. Prehm, X. Zeng, G. Ungar, C. Tschierske, Angew. Chem. Int. Ed. 53, 13115 (2014)
M. Alaasar, S. Poppe, Q. Dong, F. Liu, C. Tschierske, Chem. Commun. 52, 13869 (2016)
C. Tschierske, G. Ungar, ChemPhysChem 17, 9 (2016)
C. Tschierske, Liq. Cryst. 45, 2221 (2018)
P.G. de Gennes, The Physics of Liquid Crystals (Clarendon, Oxford, 1975)
T.C. Lubensky, Phys. Rev. A 6, 452 (1972)
H. Pleiner, H.R. Brand, Phys. Rev. Lett. 54, 1817 (1985)
G.W. Gray, J.W. Goodby, Smectic Liquid Crystals, Textures and Structures (Leonard Hill, London, 1984)
V. Luzzati, P.A. Spegt, Nature 215, 701 (1967)
V. Luzzati, A. Tardieu, T. Gulik-Krzywicki, E. Rivas, F. Reiss-Husson, Nature 220, 485 (1968)
P.E. Cladis, P. Pieranski, M. Joannicot, Phys. Rev. Lett. 52, 542 (1984)
R. Barbet-Massin, P.E. Cladis, P. Pieranski, Phys. Rev. A 31, 3912 (1985)
H. Stegemeyer, K. Bergmann, in Liquid Crystal of One- and Two-Dimensional Order, edited by W. Helfrich, K. Heppke (Springer, N.Y., 1980) p. 161 ff
P. Göring, S. Diele, S. Fischer, A. Wiegeleben, G. Pelzl, H. Stegemyer, W. Thyen, Liq. Cryst. 25, 467 (1998)
M.W. Matsen, J. Chem. Phys. 108, 785 (1998)
V. Abetz, T. Goldacker, Macromol. Rapid Commun. 21, 16 (2000)
J. Suzuki, M. Seki, Y. Matsushita, J. Chem. Phys. 112, 4862 (2000)
D.R. Nelson, J. Toner, Phys. Rev. B 24, 363 (1981)
L.G. Fel, Phys. Rev. E 52, 702 (1995)
H.R. Brand, K. Kawasaki, Physica A 324, 484 (2003)
M. Tinkham, Group Theory and Quantum Mechanics (McGraw-Hill, New York, 1964)
W.P. Mason, Physical Acoustics and the Properties of Solids (D. Van Nostrand, New York, 1958)
L. Radzihovsky, T.C. Lubensky, Europhys. Lett. 54, 206 (2001)
L. Radzihovsky, T.C. Lubensky, Phys. Rev. E 66, 031704 (2002)
H.R. Brand, H. Pleiner, P.E. Cladis, Eur. Phys. J. E 7, 163 (2002)
H.R. Brand, H. Pleiner, Eur. Phys. J. E 31, 37 (2010)
H. Pleiner, H.R. Brand, Eur. Phys. J. E 37, 11 (2014)
H.R. Brand, P.E. Cladis, H. Pleiner, Eur. Phys. J. B 6, 347 (1998)
H.R. Brand, P.E. Cladis, H. Pleiner, Eur. Phys. J. B 31, 147 (2003)
P.E. Cladis, H.R. Brand, H. Pleiner, Liq. Cryst. Today 9, 1 (1999) issue No. 3/4
H. Lu, X. Zeng, G. Ungar, C. Dressel, C. Tschierske, Angew. Chem. Int. Ed. 57, 2835 (2018)
A.M. Levelut, C. Germain, P. Keller, L. Liebert, J. Billard, J. Phys. (Paris) 44, 623 (1983)
A.M. Levelut, E. Hallouin, D. Bennemann, G. Heppke, D. Loetzsch, J. Phys. II 7, 981 (1997)
B. Pansu, Y. Nastishin, M. Imperor-Clerc, M. Veber, H.T. Nguyen, Eur. Phys. J. E 15, 225 (2004)
H. Brand, H. Pleiner, Phys. Rev. A 24, 2777 (1981) sect. III
M. Liu, Phys. Rev. A 24, 2720 (1981)
H. Pleiner, H.R. Brand, Braz. J. Phys. 46, 565 (2016)
N.D. Mermin, T.L. Ho, Phys. Rev. Lett. 36, 594 (1976)
P.C. Martin, O. Parodi, P.S. Pershan, Phys. Rev. A 6, 2401 (1972)
H. Pleiner, H.R. Brand, Hydrodynamics and Electrohydrodynamics of Liquid Crystals, Pattern Formation in Liquid Crystals, edited by A. Buka, L. Kramer (Springer, New York, 1996) p. 15 ff
P. Saidachmetov, J. Phys. (Paris) 45, 761 (1984)
H.R. Brand, H. Pleiner, Phys. Rev. A 37, 2736 (1988)
H.R. Brand, H. Pleiner, D. Svenšek, Phys. Rev. E 88, 024501 (2013)
F. Leslie, Proc. R. Soc. A 307, 359 (1968)
D. Svenšek, H. Pleiner, H.R. Brand, Phys. Rev. E 78, 021703 (2008)
D. Forster, T.C. Lubensky, P.C. Martin, J. Swift, P.S. Pershan, Phys. Rev. Lett. 26, 1016 (1971)
D. Forster, Hydrodynamic Fluctuations, Broken Symmetry, and Correlation Functions (W.A. Benjamin, Reading, Mass., 1975)
P. Pieranski, P.E. Cladis, T. Garel, R. Barbetmassin, J. Phys. (Paris) 47, 139 (1986)
H.R. Brand, Mol. Cryst. Liq. Cryst. Lett. 3, 147 (1986)
R.B. Meyer, Phys. Rev. Lett. 22, 918 (1969)
H.R. Brand, H. Pleiner, Eur. Phys. J. E 40, 34 (2017)
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Brand, H.R., Pleiner, H. Cubic and tetragonal liquid crystal phases composed of non-chiral molecules: Chirality and macroscopic properties. Eur. Phys. J. E 42, 142 (2019). https://doi.org/10.1140/epje/i2019-11906-8
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DOI: https://doi.org/10.1140/epje/i2019-11906-8