Abstract.
A statistical interpretation for the adsorption phenomenon is presented in the framework of the Maxwell-Boltzmann statistics. A model for an adsorbing surface is proposed and the connection between the phenomenological parameters, entering in the kinetic equation at the boundary surfaces, with the microscopic model is derived.
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Received: 14 June 2004, Published online: 14 September 2004
PACS:
66.10.-x Diffusion and ionic conduction in liquids - 68.43.-h Chemisorption/physisorption: adsorbates on surfaces - 68.43.Mn Adsorption/desorption kinetics
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Evangelista, L.R., Barbero, G. Statistical interpretation of the kinetic equation in the adsorption problem. Eur. Phys. J. E 15, 3–8 (2004). https://doi.org/10.1140/epje/i2004-10030-4
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DOI: https://doi.org/10.1140/epje/i2004-10030-4