Abstract
Ceramic samples of the multiferroic perovskite Pb(Fe1−xScx)2∕3W1∕3O3 with 0 ≤ x ≤ 0.4 have been synthesized using a conventional solid-state reaction method, and investigated experimentally and theoretically using first-principle calculations. Rietveld analyses of joint synchrotron X-ray and neutron diffraction patterns show the formation of a pure crystalline phase with cubic (Fm3̅m) structure with partial ordering in the B-sites. The replacement of Fe by Sc leads to the increase of the cation order between the B′ and B′′ sites. As the non-magnetic Sc3+ ions replace the magnetic Fe3+ cations, the antiferromagnetic state of PbFe2∕3W1∕3O3 is turned into a ferrimagnetic state reflecting the different magnitude of the magnetic moments on the B′ and B′′ sites. The materials remain ferroelectric relaxors with increasing Sc content. Results from experiments on annealed and quenched samples show that the cooling rate after high temperature annealing controls the degree of cationic order in Pb(Fe1−xScx)2∕3W1∕3O3 and possibly also in the undoped PbFe2∕3W1∕3O3.
Graphical abstract
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
M.M. Vopson, Crit. Rev. Solid State Mater. Sci. 40, 223 (2015)
B. Wang,Mechanics of Advanced Functional Materials. Advanced Topics in Science and Technology in China (Springer, Berlin, Heidelberg, 2013)
K.F. Wang, J.M. Liu, Z.F. Ren, Adv. Phys. 58, 321 (2009)
H. Liu, X. Yang, Ferroelectrics 507, 69 (2017)
I.E. Chupis, Low Temp. Phys. 36, 477 (2010)
S. Vasala, M. Karppinen, Prog. Solid State Chem. 43, 1 (2015)
G.A. Smolenski, A.I. Agranovskaya, V.A. Isupov, Sov. Phys. Sol. State 1, 907 (1959)
G.A. Smolenskii, J. Phys. Soc. Jpn. (Suppl.) 28, 26 (1970)
L.E. Cross, Ferroelectrics 76, 241 (1987)
A.A. Bokov, Z.G. Ye, J. Mater. Sci. 41, 31 (2006)
A. Levstik, Appl. Phys. Lett. 91, 012905 (2007)
I.W. Chen, J. Phys. Chem. Solids 61, 197 (2000)
L. Chen, A.A. Bokov, W. Zhu, H. Wu, J. Zhuang, Z.G. Ye, Sci. Rep. 6, 22327 (2016)
Y. Shimakawa, M. Azuma, N. Ichikawa, Materials 4, 153 (2011)
S. Matteppanavar, S. Rayaprol, A.A. Angadi, B. Sahoo, Ceram. Int. 41, 11680 (2015)
J.F. Scott, NPG Asia Mater. 5, e72-11 (2013)
Y.N. Venevtsev, E.D. Politova, S.A. Ivanov, inFerro- and Antiferroelectrics of Barium Titanate Family, Chemistry (Moscow, 1985), p. 256
Yu. N. Venevtsev, V.V. Gagulin, V.N. Ljubimov, inFerroelectromagnets (Nauka, Moscow, 1982), p. 172
L. Zhou, P.M. Vilarinho, P.Q. Mantas, J.L. Baptista, E. Fortunato, J. Eur. Ceram. Soc. 20, 1035 (2000)
S.A. Ivanov, Magnetoelectric complex metal oxides: main features of preparation, structure and properties, inAdvanced Functional Materials, edited by B. Sanyal, O. Eriksson (Elsevier, Oxford, UK, 2012), pp. 163–234
R.N.P. Choudhary, D.K. Pradhan, C.M. Tirado, G.E. Bonilla, R.S. Katiyar, Phys. Status Solidi B 244, 2254 (2007)
Y.A. Shevchuk, S.K. Korchagina, V.V. Gagulin, V.V. Bogatko, Ferroelectrics 199, 223 (1997)
B. Fraygola, J.A. Eiras, Mater. Res. 17, 1594 (2014)
D. Lee, S.M. Yang, Y. Jo, T.K. Song, J. Korean Phys. Soc. 57, 1914 (2010)
M. Yokosuka, H. Kojima, Jpn. J. Appl. Phys. 36, 6046 (1997)
S.A. Ivanov, P. Nordblad, R. Tellgren, T. Ericsson, H. Rundlöf, Solid State Sci. 9, 440 (2007)
D. Szwagierczak, J. Kulawik. J. Eur. Ceram. Soc. 25, 1657 (2005)
L. Zhou, P.M. Vilarinho, J.L. Baptista, J. Appl. Phys. 85, 2312 (1999)
D. Brzezinska, R. Skulski, D. Bochenek, P. Niemiec, A. Chrobak, L. Fajfrowski, S. Matyjasik, J. Alloys Compd. 737, 299 (2018)
C. Miranda, P.M. Vilarinho, L.Q. Zhou, Ferroelectrics 223, 269 (1999)
B.H. Lee, N.K. Kim, B.O. Park, S.H. Cho, Mater. Lett. 33, 57 (1997)
A.S. Khim, J. Wang, X. Junmin, Solid State Ionics 127, 285 (2000)
K. Uchino, S. Nomura, J. Phys. Soc. Jpn. 41, 542 (1976)
K. Uchino, S. Nomura, Jpn. J. Appl. Phys. 18, 1493 (1979)
S.A. Ivanov, A.A. Bush, C. Ritter, M.A. Behtin, V.M. Cherepanov, C. Autieri, Y.O. Kvashnin, I. Di Marco, B. Sanyal, O. Eriksson, P. Anil Kumar, P. Nordblad, R. Mathieu, Mater. Chem. Phys. 187, 218 (2017)
S. Matteppanavar, S. Rayaprol, B. Angadi, B. Sahoo, J. Supercond. Novel Magn. 30, 1317 (2017)
S. Matteppanavar, S. Rayaprol, B. Angadi, B. Sahoo, J. Alloys Compd. 677, 27 (2016)
P.M. Vilarinho, L. Zhou, M. Pöckl, N. Marques, J.L. Baptista, J. Am. Ceram. Soc. 83, 1149 (2000)
L. Feng, H. Guo, Z.G. Ye, J. Mater. Res. 22, 2116 (2006)
E. Dulkin, E. Mojaev, M. Roth, S. Kamba, P.M. Vilarinho, J. Appl. Phys. 103, 083542 (2008)
R. Wongmaneerung, X. Tan, R.W. McCallum, S. Ananta, R. Yimnirun, Appl. Phys. Lett. 90, 242905 (2007)
X. Tan, R. Wongmaneerung, R.W. McCallum, J. Appl. Phys. 102, 104114 (2007)
Z.G. Ye, K. Toda, M. Sato, J. Korean Phys. Soc. 32, S1028 (1998)
S.A. Ivanov, S.-G. Eriksson, R. Tellgren, H. Rundlöf, Mater. Res. Bull. 39, 2317 (2004)
B. Fraygola, A. Mesquita, A.A. Coelho, D. Garcia, V.R. Mastelaro, J.A. Eiras, Phys. Status Solidi A 210, 386 (2013)
Z.G. Ye, H. Schmid, J. Cryst. Growth 167, 628 (1996)
A.F. Koroleva, A.A. Bush, K.E. Kamentsev, V.Ya. Shkuratov, S.A. Ivanov, V.M. Cherepanov, S. Shafeie, Inorg. Mater. 54, 288 (2018)
G.A. Komandin, O.E. Porodinkov, A.A. Bush, A.F. Koroleva, I.E. Spektor, S.V. Chuchupal, D.S. Seregin, L.D. Iskhakova, Phys. Solid State 59, 2365 (2017)
J. Rodriguez-Carvajal, Physica B 192, 55 (1993)
A.C. Dippel, H.P. Liermann, J.T. Delitz, P. Walter, H. Schulte-Schrepping, O.H. Seeck, H. Franz, J. Synchrotron Radiat. 22, 675 (2015)
A.P. Hammersley, S.O. Svensson, M. Hanfland, A.N. Fitch, D. Hausermann, High Pressure Res. 14, 235 (1996)
V.F. Sears, Neutron News 3, 26 (1992)
M.I. Aroyo, J.M. Perez-Mato, D. Orobengoa, E. Tasci, G. de la Flor, A. Kirov, Bulg. Chem. Commun. 43, 183 (2011)
A.S. Kamzin, V.A. Bokov, Phys. Solid State 55, 1191 (2013)
G. Kresse, J. Furthmüller, Phys. Rev. B 54, 11169 (1996)
G. Kresse, D. Joubert, Phys. Rev. B 59, 1758 (1999)
J.P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett. 77, 3865 (1996)
A.I. Liechtenstein, V.I. Anisimov, J. Zaanen, Phys. Rev. B 52, R5467 (1995)
V.I. Anisimov, F. Aryasetiawan, A.I. Lichtenstein, J. Phys.: Condens. Matter 9, 767 (1997)
G. Rollmann, A. Rohrbach, P. Entel, J. Hafner, Phys. Rev. B 69, 165107 (2004)
R.D. Shannon, Acta Crystallogr. A 32, 751 (1976)
K. Momma, F. Izumi, J. Appl. Crystallogr. 44, 1272 (2011)
C.G. Stenger, A.J. Burggraaf, Phys. Status Solidi A 61, 653 (1980)
D.J. Goossens, Acc. Chem. Res. 46, 2597 (2013)
P. Juhas, I. Grinberg, A.M. Rappe, W. Dmowski, T. Egami, P.K. Davies, Phys. Rev. B 69, 214101 (2004)
P. Juhas, P.K. Davies, M.A. Akbas, AIP Conf. Proc. 626, 108 (2002)
P. Juhas, P.K. Davies, M.A. Akbas, J. Am. Ceram. Soc. 87, 2086 (2004)
J. Blasco, C. Ritter, L. Morellon, P.A. Algarabel, J.M. De Teresa, D. Serrate, J. García, M.R. Ibarra, Solid State Sci. 4, 651 (2002)
J.B. Goodenough, J. Phys. Chem. Solids 6, 287 (1958)
J. Kanamori, J. Phys. Chem. Solids 10, 87 (1959)
P. Davies, H. Wu, A. Borisevich, I. Molodetsky, L. Farber, Annu. Rev. Mater. Res. 38, 369 (2008)
L. Zhou, P.M. Vilarinho, J.L. Baptista, J. Eur. Ceram. Soc. 18, 1383 (1998)
N. Setter, L.E. Cross, J. Appl. Phys. 51, 4356 (1980)
G. King, P.M. Woodward, J. Mater. Chem. 20, 5785 (2010)
M.W. Lufaso, P.M. Woodward, Acta Cryst. Sect. B 60, 10 (2004)
M.T. Anderson, K.B. Greenwood, G.A. Taylor, K.R. Poeppelmeier, Prog. Solid State Chem. 22, 197 (1993)
V.A. Isupov, Ferroelectrics 315, 149 (2005)
S.A. Larregola, J.A. Alonso, M. Alguero, R. Jimenez, E. Suard, F. Porcher, J.C. Pedregosa, Dalton Trans. 39, 5159 (2010)
B. Malibert, M. Dkhil, M. Dunlop, J.M. Kiat, G. Baldinozzi, S.B. Vakhrushev, Ferroelectrics 235, 87 (1999)
J.A. Alonso, I. Rasines, J. Phys. Chem. Solids 49, 3885 (1988)
K.S. Aleksandrov, S.V. Misyul, E.E. Baturinets, Ferroelectrics 354, 60 (2007)
Yu.N. Venevtsev, V.V. Sklyarevskii, I.I. Lukashevich, V.P. Romanov, N.M. Kotov, A.I. Kashlinskii, N.I. Filipov, A.S. Viskov, Sov. Phys. Crystallogr. 21, 556 (1976) [original article (in Russian): Kristallografiya 21, 971 (1976)]
I.P. Raevskii, D.A. Sarychev, S.A. Bryugeman, L.A. Reznichenko, L.A. Shilkina, O.N. Razumovskaya, V.S. Nikolaev, N.P. Vyshatko, A.N. Salak, Crystallogr. Rep. 47, 1012 (2002) [original article (in Russian): Kristallografiya 47, 1081 (2002)]
J. Zang, W. Jo, J. Rödel, Appl. Phys. Lett. 102, 032901 (2013)
H. Muramatsu, H. Nagata, T. Taken, Jpn. J. Appl. Phys. 55, 10TB07 (2016)
Y.C. Hu, Y.W. Cui, X.W. Wang, Y.P. Liu, Chin. Phys. Lett. 33, 026101 (2016)
Author information
Authors and Affiliations
Corresponding author
Additional information
Supplementary material in the form of one pdf file available from the Journal web page at https://doi.org/10.1140/epjb/e2019-100149-9
Electronic supplementary material
Supplementary data
Rights and permissions
Open Access This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
About this article
Cite this article
Ivanov, S.A., Beran, P., Bush, A.A. et al. Cation ordering, ferrimagnetism and ferroelectric relaxor behavior in Pb(Fe1−xScx)2∕3W1∕3O3 solid solutions. Eur. Phys. J. B 92, 163 (2019). https://doi.org/10.1140/epjb/e2019-100149-9
Received:
Revised:
Published:
DOI: https://doi.org/10.1140/epjb/e2019-100149-9