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Multiplicity of metastable nonergodic states of a dispersed nonwetting liquid in a disordered nanoporous medium

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Abstract

Three different metastable nonergodic states of a dispersed nonwetting liquid (water) in the Fluka 100 C8 and Fluka 100 C18 disordered porous media, as well as transitions between these states under variation of the temperature and the degree of filling, have been qualitatively described. It has been shown that the appearance of such states is due to spatial variations of the number of the nearest neighbors because of the broadening of the pore size distribution function f(R), fluctuations of various local configurations of neighbors in the system of pores, and fluctuations of a configuration of a pore and its environment consisting of filled and empty pores on a percolation cluster. These states and transitions are caused by the competition between the effective repulsion of the nonwetting liquid from the wall of the pore, which is responsible for the “extrusion” of the liquid from the pore, and the effective collective multiparticle attraction of the liquid cluster in the pore to clusters in the neighboring connected pores. The theoretical dependences obtained make it possible to qualitatively describe experimental data.

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References

  1. V.D. Borman, A.A. Belogorlov, V.A. Byrkin, V.N. Tronin, V.I. Troyan, JETP Lett. 95, 511 (2012)

    Article  ADS  Google Scholar 

  2. V.D. Borman, A.A. Belogorlov, V.A. Byrkin, V.N. Tronin, Phys. Rev. E 88, 052116 (2013)

    Article  ADS  Google Scholar 

  3. V.D. Borman, A.A. Belogorlov, V.A. Byrkin, V.N. Tronin, V.I. Troyan, J. Exp. Theor. Phys. 117, 1139 (2013)

    Article  Google Scholar 

  4. V.D. Borman, A.M. Grekhov, V.I. Troyan, J. Exp. Theor. Phys. 91, 170 (2000)

    Article  ADS  Google Scholar 

  5. V.D. Borman, A.A. Belogorlov, A.M. Grekhov, G.V. Lisichkin, V.N. Tronin, V.I. Troyan, J. Exp. Theor. Phys. 100, 385 (2005)

    Article  ADS  Google Scholar 

  6. A. Han, X. Kong, Y. Qiao, J. Appl. Phys. 100, 014308 (2006)

    Article  ADS  Google Scholar 

  7. X. Kong, Y. Qiao, Appl. Phys. Lett. 86, 151919 (2005)

    Article  ADS  Google Scholar 

  8. F.B. Surani, Y. Qiao, J. Appl. Phys. 100, 034311 (2006)

    Article  ADS  Google Scholar 

  9. B. Lefevre, A. Saugey, J.L. Barrat, L. Bocquet, E. Charlaix, P.F. Gobin, G. Vigier, J. Chem. Phys. 120, 4927 (2004)

    Article  ADS  Google Scholar 

  10. B. Lefevre, A. Saugey, J.L. Barrat, Colloids Surf. A 241, 265 (2004)

    Article  Google Scholar 

  11. A. Han, W. Lu, V.K. Punyamurtula, T. Kim, Y. Qiao, J. Appl. Phys. 105, 024309 (2009)

    Article  ADS  Google Scholar 

  12. V. Eroshenko, R.-C. Regis, M. Soulard, J. Patarin, C.R. Phys. 3, 111 (2002)

    Article  ADS  Google Scholar 

  13. A. Han, W. Lu, T. Kim, X. Chen, Y. Qiao, Phys. Rev. E 78, 031408 (2008)

    Article  ADS  Google Scholar 

  14. L. Liu, X. Chen, W. Lu, A. Han, Y. Qiao, Phys. Rev. Lett. 102, 184501 (2009)

    Article  ADS  Google Scholar 

  15. L. Coiffard, V. Eroshenko, J. Colloid Interface Sci. 300, 304 (2006)

    Article  Google Scholar 

  16. Y.A. Kumzerov, A.A. Nabereznov, S.B. Vakhrushev, B.N. Savenko, Phys. Rev. B 52, 4772 (1995)

    Article  ADS  Google Scholar 

  17. F. Gomez, R. Denoyel, J. Rouquerol, Langmuir 16, 4374 (2000)

    Article  Google Scholar 

  18. F. Porcheron et al., Langmuir 23, 3372 (2007)

    Article  Google Scholar 

  19. I.Ya. Korenblit, E.F. Shender, Sov. Phys. Usp. 32, 139 (1989)

    Article  ADS  Google Scholar 

  20. V.S. Dotsenko, Phys. Usp. 36, 455 (1993)

    Article  ADS  Google Scholar 

  21. S.P. Rigby, K.J. Edler, J. Colloid Interface Sci. 250, 175 (2002)

    Article  Google Scholar 

  22. N. Wardlaw, M. McKellar, Powder Technol. 29, 127 (1981)

    Article  Google Scholar 

  23. J.R. Edison, P.A. Monson, J. Low Temp. Phys. 157, 395 (2009)

    Article  ADS  Google Scholar 

  24. V.D. Borman, A.A. Belogorlov, G.V. Lisichkin, V.N. Tronin, V.I. Troyan, J. Exp. Theor. Phys. 108, 389 (2009)

    Article  ADS  Google Scholar 

  25. C.V. Suciu, T. Iwatsubo, S. Deki, J. Colloid Interface Sci. 259, 62 (2003)

    Article  Google Scholar 

  26. A.Y. Fadeev, V.A. Eroshenko, J. Colloid Interface Sci. 187, 275 (1997)

    Article  Google Scholar 

  27. V.D. Borman, A.A. Belogorlov, V.A. Byrkin, G.V. Lisichkin, V.N. Tronin, V.I. Troyan, J. Exp. Theor. Phys. 112, 385 (2011)

    Article  ADS  Google Scholar 

  28. M. Vasin, J. Stat. Mech. 2011, P05009 (2011)

    Article  Google Scholar 

  29. S. Lowell, J.E. Shields, M.A. Thomas, M. Thommes, Characterization of Porous Solids and Powders: Surface Area, Pore Size and Density (Springer, New York, 2006)

  30. E.P. Barrett, L.G. Joyner, P.P. Halenda, J. Am. Chem. Soc. 73, 373 (1951)

    Article  Google Scholar 

  31. C.V. Suciu, T. Iwatsubo, K. Yaguchi, M. Ikenaga, J. Colloid Interface Sci. 283, 196 (2005)

    Article  Google Scholar 

  32. A.Y. Fadeev, S.M. Staroverov, J. Chromatogr. 447, 103 (1988)

    Article  Google Scholar 

  33. S.M. Staroverov, A.Y. Fadeev, J. Chromatogr. 544, 77 (1991)

    Article  Google Scholar 

  34. L.I. Kheifets, A.V. Neimark, Multiphase Processes in Porous Media (Khimiya, Moscow, 1982)

  35. M. Sahimi, Rev. Mod. Phys. 65, 1393 (1993)

    Article  ADS  Google Scholar 

  36. M. Isichenko, Rev. Mod. Phys. 64, 961 (1992)

    Article  MathSciNet  ADS  Google Scholar 

  37. L.D. Landau, E.M. Lifshitz, in Statistical Physics, Part 1, Course of Theoretical Physics, 3rd edn. (Pergamon, New York, 1980), Vol. 5

  38. Y. Qiao, V.K. Punyamurtula, G. Xian, V.M. Karbhari, A. Han, Appl. Phys. Lett. 92, 063109 (2008)

    Article  ADS  Google Scholar 

  39. W. Haller, J. Chem. Phys. 42, 686 (1965)

    Article  ADS  Google Scholar 

  40. V.D. Borman, A.A. Belogorlov, G.V. Lisichkin, V.N. Tronin, V.I. Troyan, J. Exp. Theor. Phys. 108, 389 (2009)

    Article  ADS  Google Scholar 

  41. Yu. Kumzerov, A. Nabereznov, S. Vakhrushev, B. Savenko, Phys. Rev. B 52, 4772 (1995)

    Article  ADS  Google Scholar 

  42. CRC Handbook of Chemistry and Physics: A Ready Reference Book of Chemical and Physical Data, edited by W.M. Haynes, D.R. Lide, T.J. Bruno, 93rd edn. (CRC Press, Boca Raton, 2012)

  43. V.D. Borman, A.A. Belogorlov, V.A. Byrkin, V.N. Tronin, V.I. Troyan, arXiv:1302.5547 (2013)

  44. P.S. Grinchuk, O.S. Rabinovich, J. Exp. Theor. Phys. 96, 301 (2003)

    Article  ADS  Google Scholar 

  45. V.D. Borman, A.A. Belogorlov, V.A. Byrkin, G.V. Lisichkin, V.N. Tronin, V.I. Troyan, J. Phys.: Conf. Ser. 291, 012044 (2011)

    ADS  Google Scholar 

  46. E. Mamontov, Yu. Kumzerov, S. Vakhrushev, Phys. Rev. E 71, 061502 (2005)

    Article  ADS  Google Scholar 

  47. V.S. Dotsenko, Phys. Usp. 38, 457 (1995)

    Article  ADS  Google Scholar 

Download references

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Authors and Affiliations

  1. Molecular Physics Department, National Research Nuclear University MEPhI (Moscow Engineering Physics Institute), Kashirskoe sh. 31, 115409, Moscow, Russia

    Vladimir D. Borman, Anton A. Belogorlov, Alexey M. Grekhov & Vladimir N. Tronin

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  1. Vladimir D. Borman
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  2. Anton A. Belogorlov
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  3. Alexey M. Grekhov
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  4. Vladimir N. Tronin
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Correspondence to Anton A. Belogorlov.

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Borman, V., Belogorlov, A., Grekhov, A. et al. Multiplicity of metastable nonergodic states of a dispersed nonwetting liquid in a disordered nanoporous medium. Eur. Phys. J. B 87, 249 (2014). https://doi.org/10.1140/epjb/e2014-50342-7

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