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Proton-Exchange Hybrid Membranes: A Copolymer of Ethylene Glycol Vinyl Glycidyl Ether and Vinyl Chloride/Polyorganylsilsesquioxane

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Abstract

Copolymers of ethylene glycol vinyl glycidyl ether (VGE) and vinyl chloride (VC) have been obtained via radical copolymerization of VGE with VC at 70°C in the presence of the initiator azobisisobutyronitrile. By the sol–gel synthesis involving VGE–VC copolymers and carbofunctional organosilicon precursors, such as N,N'-bis(3-triethoxysilylpropyl)thiocarbamide (BTM) and 2-([triethoxysilylpropyl]amino)pyridine (TEAP), hybrid organic–inorganic membranes possessing proton conductivity after doping with orthophosphoric acid have been fabricated. The proton conductivity of the membranes in the temperature range of 30–80°C is characterized by the values of 3.52–4.88 × 10−3 S cm−1 for VGE–VC/ BTM/H3PO4 and 1.19–2.89 × 10−3 S cm−1 for VGE–VC/TEAP/H3PO4.

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Authors and Affiliations

  1. Irkutsk National Research Technical University, 664074, Irkutsk, Russia

    O. V. Lebedeva & Yu. N. Pozhidaev

  2. Angarsk State Technical University, 665835, Angarsk, Russia

    E. A. Malakhova & T. V. Raskulova

  3. Favorsky Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, 664033, Irkutsk, Russia

    A. S. Pozdnyakov

  4. CSIR-Centre Salt & Marine Chemicals Research Institute, Bhavnagar India, Gijubhai Badheka Marg, 364002, Bhavnagar, Guj., India

    Vaibhav Kulshrestha & Vikrant Yadav

Authors
  1. O. V. Lebedeva
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  2. E. A. Malakhova
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  3. T. V. Raskulova
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  4. Yu. N. Pozhidaev
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  5. A. S. Pozdnyakov
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  6. Vaibhav Kulshrestha
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  7. Vikrant Yadav
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Corresponding authors

Correspondence to O. V. Lebedeva or Yu. N. Pozhidaev.

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Translated by E. Boltukhina

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Lebedeva, O.V., Malakhova, E.A., Raskulova, T.V. et al. Proton-Exchange Hybrid Membranes: A Copolymer of Ethylene Glycol Vinyl Glycidyl Ether and Vinyl Chloride/Polyorganylsilsesquioxane. Membr. Membr. Technol. 1, 145–152 (2019). https://doi.org/10.1134/S2517751619030016

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  • DOI: https://doi.org/10.1134/S2517751619030016

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