Abstract
The impact of conditions in extraction of natural admixtures (pectin compounds, hemicelluloses, and lignin) from hemp fiber during chemical modification of fibrous mass was studied. It was shown that the maximum extraction of admixtures requires increasing the temperature of fiber treatment to 100°С and the sodium hydroxide concentration to 10 g/L. Using infrared spectroscopy and potentiometric titration methods, it was proved that the increase in alkalinity of the boiling liquor leads not only to the increase in the amount of admixtures in the liquor but also to their destruction, while the complex of reducing ingredients that was formed in the liquor can act as a reductant of silver ions even under conditions of low temperatures in extraction. The kinetics of reduction of silver ions in the extract liquor was investigated. The correlation of the efficiency of the reduction of silver ions and the quantitative content of admixtures in the liquor was found. Using photon correlation spectroscopy, it was shown that reduction in an extract obtained under high alkalinity makes it possible to obtain particles of small size, not more than 30 nm. It was proved that the antimicrobial activity of synthesized sols and cellulosic materials treated with these sols against test cultures depends on the synthesis conditions.
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REFERENCES
Ravindra, S., Murali Mohan, Y., Narayana Reddy, N., and Mohana Raju, K., Fabrication of antibacterial cotton fibres loaded with silver nanoparticles via “Green Approach,” Colloids Surf., A, 2010, vol. 367, pp. 31–40.
Nadagouda, M.N. and Varma, R.S., Green synthesis of silver and palladium nanoparticles at room temperature using coffee and tea extract, Green Chem., 2008, vol. 10, pp. 859–862.
Krutyakov, Yu.A., Kudrinskiy, A.A., Olenin, A.Yu., and Lisichkin, G.V., Synthesis and properties of silver nanoparticles: advances and prospects, Russ. Chem. Rev., 2008, vol. 77, no. 3, pp. 233–257.
Grishchenko, L.A., et al., Redox reactions of arabinogalactan with silver ions and formation of nanocomposites, Russ. J. Gen. Chem., 2006, vol. 76, no. 7, pp. 1111–1116.
Medvedeva, E.N., Babkin, V.A., and Ostroukhova, L.A., Larch arabinogalactan: properties and prospects of use (review), Khim. Rastit. Syr’ya, 2003, no. 1, pp. 27–37.
Dymnikova, N.S., Erokhina, E.V., and Moryganov, A.P., Modification of cellulose fibers with silver sols synthesized in the extracts of the natural impurities of flax, Perspekt. Mater., 2017, no. 6, pp. 29–38.
Mel’nikov, B.N., Otdelka khlopchatobumazhnykh tkanei: Spravochnik (Finishing of Cotton Fabrics: A Handbook), Ivanovo: Talka, 2003.
Aimukhamedov, G.B. and Shelukhin, N.P., Pektinovye veshchestva i metody ikh opredeleniya (Pectin Substances and Methods for Their Determination), Frunze: Ilim, 1964.
Dibrova, A.K. and Matveev, V.S., Analiticheskii kontrol’ proizvodstva iskusstvennykh volokon. Spravochnoe posobie (Analytical Control of the Production of Artificial Fibers: Handbook), Moscow: Khimiya, 1986.
Varshney, R.K., Singh, R.K., Sengupta, A.K., and Kothari, V.K., Varietal response of jute fibres with varying meshiness to alkali treatment: Part I—Effect of alkali concentration and treatment temperature on crimp development in jute fibres, Indian J. Fibre Text. Res., 2006, vol. 31, no. 2, pp. 267–273.
Stokozenko, V.G., Gubina, S.M., and Zavadskii, A.E., Investigation of the supramolecular structure of cottonized flax fiber, Izv. Vyssh. Uchebn. Zaved.,Khim. Khim. Tekhnol., 2004, vol. 47, no. 1, pp. 23–26.
Stokozenko, V.G. and Nemanova, Yu.V., The study of the kinetics of hydrolytic degradation of various types of cellulose under the action of sodium hydroxide, Izv. Vyssh. Uchebn. Zaved.,Khim. Khim. Tekhnol., 2009, vol. 52, no. 5, pp. 56–59.
Bellami, L.J., The Infrared Spectra of Complex Molecules, New York: Springer-Verlag, 1980.
Silverstain, R.M., Bassler, G.C., and Morril, T.C., Spectrometric Identification of Organic Compounds, New York: Wiley, 2014. ISBN 10 0471634042
Karklin’, V.B., IR spectroscopy of wood and its main components, Khim. Drev., 1981, no. 4, pp. 45–49.
Germer, E.I. and Shagaev, O.V., The change in the content of carbonyl and methoxyl groups in lignin during the oxygen-soda cooking of aspen, Khim. Drev., 1984, no. 1, pp. 52–54.
Kreshkov, A.P., Osnovy analiticheskoi khimii (Fundamentals of Analytical Chemistry), Moscow: Khimiya, 1971, vol. 2.
Lepilova, O.V., Spigno, G., Aleeva, S.V., and Koksharov, S.A., Study of the ability of reducing saccharides to chemically transform lignin, Eurasian Chem.-Technol. J., 2017, vol. 19, no. 1, pp. 31–40.
Venediktov, E.A. and Padokhin, V.A., Synthesis of silver nanoclusters in starch aqueous solutions, Russ. J. Appl. Chem., 2008, vol. 81, no. 11, pp. 2040–2042.
Dymnikova, N.S., Erokhina, E.V., Kuznetsov, O.Yu., and Moryganov, A.P., The effect of the substantivity of silver-containing preparations to cellulosic material on its biological activity, Ross. Khim. Zh., 2017, vol. 62, no. 2, pp. 3–12.
Kotelnikova, N.E., Paakkari, T., and Serimaa, R., Study of metal clusters intercalation into cellulose by wacs, spectroscopic, and microscopic methods, Macromol. Symp., 1997, vol. 114, pp. 165–169.
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The spectral studies were carried out using the equipment of the shared access center Upper Volga Regional Center for Physicochemical Research.
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Dymnikova, N.S., Erohina, E.V., Moryganov, A.P. et al. Optimization of Conditions for Synthesis of Ultrafine Silver Particles in Hemp Fiber Extract. Inorg. Mater. Appl. Res. 11, 385–393 (2020). https://doi.org/10.1134/S2075113320020082
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DOI: https://doi.org/10.1134/S2075113320020082