Abstract
Mixtures of high-density polyethylene and low-density polyethylene with 90 wt % adamantane, cyanuric acid, BeO, SiO2, KF, AgI, and AgNO3 were subjected to plastic deformation under a pressure of 1 GPa on an anvil-type high-pressure apparatus and studied by DSC. The endothermic processes were associated with the destruction of intermolecular bonds at the filler–polymer interfaces caused by the formation of double electric layers and the occurrence of interphase electrostatic interaction.
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Notes
During the formation of mechanoelectrets, significant volumetric and dipole electric charges are obtained by mechanical compression of polymer samples between press plates [19].
It is known that the ionic bond is amplified with an increase in the ordinal number of an element in the periodic table.
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Zhorin, V.A., Kiselev, M.R. & Kotenev, V.A. Melting and Crystallization of High- and Low-Density Polyethylenes in Mixtures with Some Oxides and Ionic Crystals after Intensive Plastic Deformation. Prot Met Phys Chem Surf 57, 289–296 (2021). https://doi.org/10.1134/S2070205121020118
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DOI: https://doi.org/10.1134/S2070205121020118