Abstract
The inhibition effect of expired Simvastan drug on Cu corrosion in 1 M HNO3 at 25°C was investigated using potentiodynamic polarization (PP), electrochemical impedance spectroscopy (EIS) and electrical frequency modulation (EFM) as well as weight loss (WL) measurements. Electrochemical studies data support that examined expired drug is an efficient inhibitor for mild steel corrosion. The adsorption of the examined drug obeys Langmuir’s adsorption isotherm. Polarization studies indicate that this inhibitor acts as a mixed type inhibition. The effect of temperature on corrosion inhibition has been studied and the thermodynamic activation and adsorption parameters were calculated and discussed. The protective film formed on the surface was confirmed by scanning electron microscopy (SEM) and energy dispersive X-ray (EDX). The results collected from the studied techniques are in good agreement to confirm the ability of using expired Simvastan drug as corrosion inhibitor for Cu in acid media. The relationships between the inhibition efficiency (%IE) and some quantum chemical parameters have been discussed.
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REFERENCES
Khaled, K.F., Fadl-Allah, Sahar A., and Hammouti, B., Mater. Chem. Phys., 2009, vol. 117, p. 148.
Abd El-Maksoud, S.A. and Hassan, H.H., Mater. Corros., 2007, vol. 58, p. 369.
Fouda, A.S., Abd El-Aal, A., and Kandil, A.B., Desalination, 2006, vol. 201, p. 216.
Maayta, A.K., Bitar, M.B., and Al-Abdallah, M.M., Br. Corros. J., 2001, vol. 36, p. 133.
El Issami, S., Bazzi, L., Mihit, M., Hilali, M., Salghi, R., and Ait Addi, E., Ann. Chim. Sci. Mater., 2002, vol. 27, p. 63.
Ebenso, E.E., Eddy, N.O., and Odiongenyi, A.O., Port. Electrochim. Acta, 2009, vol. 27, p. 13
Eddy, N.O. and Ebenso, E.E., Int. J. Electrochem. Sci., 2010, vol. 5, p. 731.
Eddy, N.O., PhD Thesis, Calabar: Univ. of Calabar, 2008.
Eddy, N.O., Odoemelam, S.A., and Mbaba, A.J., Afr. J. Pure Appl. Chem., 2008, vol. 2, p. 132.
Eddy, N.O., Ebenso, E.E., and JIbok, U., J. Appl. Electrochem., 2010, vol. 40, p. 445
Hari Kumar, S. and Karthikeyan, S., J. Mater. Environ. Sci., 2012, vol. 3, p. 925.
Naqui, I., Saleemi, A.R., and Naveed, S., Int. J. Electrochem. Sci., 2011, vol. 6, p. 146.
Singh, A.K., Singh S.K., and Ebenso, E.E, Int. J. Electrochem. Sci., 2011, vol. 6, p. 5689
Gece, G., Corros. Sci., 2011, vol. 53, p. 3873.
Fouda, A.S., Abdallah, A., and Yousef, M., Chem. Sci. Rev. Lett., 2014, vol. 3, p.130.
Abdallah, M., Corros. Sci., 2004, vol. 46, p. 1981.
Mohammed, K.Z., Hamdy, A., and Abbas, M., Res. J. Pharm., Biol. Chem. Sci., 2012, vol. 3, p. 912.
Singh, A.K. and Quraishi, M.A., Corros. Sci., 2010, vol. 52, p. 152,
Shukla, S.K. and Quraishi, M.A., Mater. Chem. Phys., 2010, vol. 120, p. 142.
Hameed, R.S.A., Port. Electrochim. Acta, 2011, vol. 29, no. 4.
Vaszilcsin, N., Ordadi, V., and Borza, A., Int. J. Pharm., 2012, vol. 15.
Bosch, R.W., Hubrecht, J., Bogaerts, W.F., and Syrett, B.C., Corrosion, 2001, vol. 57, p. 60.
Muller, A., Stockel, W., and Schumacher, R., J. Electroanal. Chem., 1987, vol. 219, nos. 1–2, p. 311.
Comprehensive Treatise of Electrochemistry, Smyrl, W.H., Bockris, J.O.M., Conway, B.E., Yeager, E., and White, R.E., Eds., New York: Plenum Press, 1981, vol. 4, p. 116.
McCafferty, E. and Hackerman, N., J. Electrochem. Soc., 1972, vol. 119, p. 146.
Kus, E. and Mansfeld, F., Corros. Sci., 2006, vol. 48, no. 4, p. 965.
Anand, R.R., Hurd, R.M., and Hackerman, N., J. Electrochem. Soc., 1965, vol. 112, p. 138.
Abdel–Rehim, S.S., Khaled, K.F., and Abd–Elshafi, N.S., Electrochim. Acta, 2006, vol. 51, p. 3269
Trabanelli, G., in Corrosion Mechanisms, Mansfeld, F., Ed., New York: Marcel Dekker, 1987, p. 119.
Fouda, A.S., Abd El-Aal, A., and Kandil, A.B., Desalination, 2006, vol. 201, nos. 1–3, p. 216.
Gomma, M.K and Wahdan, M.H., Mater. Chem. Phys., 1995, vol. 39, p. 209.
Khamis, E., Corrosion, 1990, vol. 46, p. 476.
Putilova, I.K., Balizen, S.A., and Barasanik, Y.P., Metallic Corrosion Inhibitors, Oxford: Pergamon Press, 1960, vol. 30.
Fouda, A.S. and Mekkia Badr, D.A.H., J. Korean Chem. Soc., 2013, vol. 57, no. 2, p. 264.
Laque, F.L. and Gapson, H.R., Corrosion Resistance of Metals and Alloys, New York: Reinhold Publ., 1963.
Lukovits, I., Palfi, K., and Kalman, E., Corrosion, 1997, vol. 53, p. 915.
Zhao, P., Liang, Q., and Li, Y., Appl. Surf. Sci., 2005, vol. 252, p. 1596.
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Fouda, A.S., Badawy, A.A. Adsorption and Corrosion Inhibition of Cu in Nitric Acid by Expired Simvastatin Drug. Prot Met Phys Chem Surf 55, 572–582 (2019). https://doi.org/10.1134/S2070205119030146
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DOI: https://doi.org/10.1134/S2070205119030146