Abstract
Adsorption of hydrogen in four types of activated carbons of different origin with specific micropore volumes ranging from 0.46 to 0.96 cm3/g is studied at temperatures of 303, 313, 323, and 333 K and pressures up to 20 MPa. The saturation adsorption of hydrogen vapors in the considered types of activated carbons is calculated at the hydrogen boiling point (20.38 K) and a pressure of 0.101 MPa using the Dubinin theory of volume filling of micropores (TVFM). The theoretical calculations show that the type FAS-2008 adsorbent, which is produced using liquid-phase furfural polymerization, has the highest adsorption capacity. Using the TVFM and taking into account linearity of the adsorption isosteres, we also estimate adsorption of hydrogen in the type AU3:5 slit-shaped microporous carbon adsorbent at a temperature of 303 K and pressures 10 and 20 MPa. The collected experimental data and theoretical calculations are compared to the data for 101 kPa and 20.38 K. The highest hydrogen adsorption, 7.9 wt %, at 20 MPa and 303 K is predicted for a model slit-shaped microporous graphene-based adsorbent, type AU3:5.
Similar content being viewed by others
Notes
m3(STP)/m3 is a cubic meter of hydrogen at standard temperature and pressure (101 kPa, 293 K) per cubic meter of the hydrogen storage tank.
REFERENCES
Gamburg, D.Yu., Semenov, V.P., Dubovkin, N.F., and Smirnova, L.N., Vodorod. Svoistva, poluchenie, khranenie, transportirovanie, primenenie (Hydrogen. Properties, Synthesizing, Storage, Transportation, Application), Gamburg, D.Yu. and Dubovkin, N.F., Eds., Moscow: Khimiya, 1989.
Zaluska, A., Zaluski, L., and Strom-Olsen, J.O., J. Alloys Compd., 2000, vol. 298, p. 125.
A Multiyear Plan for the Hydrogen R&D Program. Rationale, Structure, and Technology Roadmaps, Washington, DC: Office of Power Technologies, Energy Efficiency and Renewable Energy, U.S. Department of Energy, 1999, p. 55.
Bradley, T.H., Moffitt, B.A., Mavris, D.N., and Parekh, D.E., J. Power Sources, 2007, vol. 171, p. 793.
Stroman, R.O., Schuette, M.W., Swider-Lyons, K., Rodgers, J.A., and Edwards, D.J., Int. J. Hydrogen Energy, 2014, vol. 39, p. 11279.
Dubinin, M.M., Adsorbtsiya i poristost' (Adsorption and Porosity), Moscow: Military Academy of Chemical Defense Named after Marshal of the USSR S.K. Timoshenko, 1972.
Vlasov, A.I., Bakaev, V.A., Dubinin, M.M., and Serpinskii, V.V., Dokl. Akad. Nauk SSSR, 1981, vol. 260, no. 4, p. 904.
Keffer, D., Davis, H.T., and McCormick, A.V., J. Phys. Chem., 1996, vol. 100, no. 2, p. 638.
Fomkin, A.A., Anuchin, K.M., Korotych, A.P., and Tolmachev, A.M., Fizikokhim. Poverkhn. Zashch. Mater., 2014, vol. 50, no. 2, p. 156. Anuchin, K.M., Fomkin, A.A., Korotych, A.P., and Tolmachev, A.M., Prot. Met. Phys. Chem. Surf., 2014, vol. 50, no. 2, p. 173.
Shkolin, A.V., Fomkin, A.A., Tsivadze, A.Yu., Anuchin, K.M., Men’shchikov, I.E., and Pulin, A.L., Prot. Met. Phys. Chem. Surf., 2016, vol. 52, no. 6, p. 955.
Kel’tsev, N.V., Osnovy adsorbtsionnoi tekhniki (Foundations of Adsorption Technique), Moscow: Khimiya, 1976.
Carpetis, C. and Peschka, W., Int. J. Hydrogen Energy, 1980, vol. 5, p. 539.
Srtobel, R., Jorissen, L., Schiermann, T., Trapp, V., Schutz, W., Bohmhammel, K., Wolf, G., and Garche, J., J. Power Sources, 1999, vol. 84, p. 221.
Tibbetts, G.G., Meisher, G.P., and Olk, C.H., Carbon, 2001, vol. 39, p. 2291.
Shindo, K., Kondo, T., Arakowa, M., and Sakurai, Y., J. Alloys Compd., 2003, vol. 359, p. 267.
Sethia, G. and Sayari, A., Carbon, 2016, vol. 99, p. 289.
Kostoglou, N., Koczwara, C., Prehal, C., and Terziyska, V., Nano Energy, 2017, vol. 40, p. 49.
Breck, D.W., Zeolite Molecular Sieves: Structure, Chemistry, and Use, New York: Wiley, 1973.
Isaeva, V.I. and Kustov, L.M., Ross. Khim. Zh., 2006, no. 6, p. 56.
Hirsher, H., Becher, M., Halushka, M., Dettlaff-Weglikowska, U., Quintel, A., Duesberg, G.S., Choi Y.-M., Downes, F., Hulman, M., Roth, C., Stepanek, I., and Bernier, P., Appl. Phys. A: Mater. Sci. Process., 2001, vol. 72, p. 129.
Parilla, P.A., Dillon, A.C., Gennat, T., Alleman, J.L., Jones, K.M., and Heben, M.J., Mater. Res. Soc. Symp. Proc., 2001, vol. 633, p. 1.
Park, C., Anderson, P.E., Tan, C.D., Hidalgo, R., and Rodrigez, N.M., J. Phys. Chem. B, 1999, vol. 103, p. 10572.
Tarasov, B.P. and Goldshleger, N.F., Int. Sci. J. “Altern. Energy Ecol.” (ISJAEE), 2002, no. 3, p. 20.
Yakovlev, V.Yu., Shkolin, A.V., Fomkin, A.A., and Men’shchikov, I.E., Prot. Met. Phys. Chem. Surf., 2018, vol. 54, no. 5, p. 754.
Fomkin, A.A. and Sinitsyn, V.A., Russ. Chem. Bull., 2009, vol. 58, no. 4, p. 1.
Fomkin, A.A., Sinitsyn, V.A., and Gur’yanov, V.V., Colloid J., 2008, vol. 70, no. 3, p. 372.
Wang, D.-Y., Gong, M., Chou, H.-L., and Pan, C.-J., J. Am. Chem. Soc., 2015, vol. 137, no. 4, p. 1587.
Dresselhaus, M.S., Williams, K.A., and Eklund, P.C., MRS Bull., 1999, vol. 24, no. 11, p. 45.
Ivakhnyuk, G.K., Sevryugov, L.B., and Plachenov, T.G., Poluchenie, struktura i svoistva adsorbentov (Synthesizing, Structure, and Properties of Adsorbents), Leningrad: Lensovet Leningrad Institute of Technology, 1977, p. 19.
Fedorov, N.F., Ivakhnyuk, G.K., Gavrilov, D.N., Tetenev, V.V., Smetanin, G.N., Samonin, V.V., Babkin, O.E., and Zaitsev, Yu.A, in Uglerodnye adsorbenty i ikh primenenie v promyshlennosti (Carbon Adsorbents and their Application for Industry), Plachenov, T.G., Ed., Moscow: Nauka, 1983, p. 20.
Shkolin, A.V. and Fomkin, A.A., Meas. Tech., 2018, vol. 61, no. 4, p. 395.
Pribylov, A.A., Kalashnikov, S.M., and Serpinskii, V.V., Izv. Akad. Nauk SSSR, Ser. Khim., 1990, no. 6, p. 1233.
Yin, Y.F., Mays, T., and McEnaney, B., Langmuir, 2000, vol. 16, p. 10521.
Barrer, R.M. and Papadopoulos, R., Proc. R. Soc. London, Ser. A, 1972, vol. 326, p. 331.
Shkolin, A.V., Fomkin, A.A., and Yakovlev, V.Yu., Russ. Chem. Bull., 2007, vol. 56, no. 3, p. 393.
Shekhovtsova, L.G. and Fomkin, A.A., Izv. Akad. Nauk SSSR, Ser. Khim., 1992, no. 1, p. 19.
Shkolin, A.V. and Fomkin, A.A., Colloid J., 2009, vol. 71, no. 1, p. 119.
Shkolin, A.V., Potapov, S.V., and Fomkin, A.A., Colloid J., 2015, vol. 77, no. 6, p. 812.
Potapov, S.V., Shkolin, A.V., and Fomkin, A.A., Colloid J., 2014, vol. 76, no. 3, p. 351.
Fomkin, A.A., Serpinskii, V.V., and Fidler, K., Izv. Akad. Nauk SSSR, Ser. Khim., 1982, no. 6, p. 1207.
Dubinin, M.M., in Uglerodnye adsorbenty i ikh primenenie v promyshlennosti (Carbon Adsorbents and Their Application for Industry), Moscow: Nauka, 1983, p. 100.
Shkolin, A.V., Fomkin, A.A., and Sinitsyn, V.A., Colloid J., 2008, vol. 70, no. 6, p. 796.
Tarkovskaya, I.A., Okislennyi ugol’ (Oxygenated Coal), Kiev: Naukova Dumka, 1981.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by A. Kukharuk
Rights and permissions
About this article
Cite this article
Fomkin, A.A., Pribylov, A.A., Murdmaa, K.O. et al. Adsorption of Hydrogen in Microporous Carbon Adsorbents of Different Origin. Prot Met Phys Chem Surf 55, 413–419 (2019). https://doi.org/10.1134/S2070205119030134
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S2070205119030134