Abstract
Glucose is an organic molecule whose characteristics are corrosion inhibitors. The adsorption and inhibitory effect of glucose on copper surfaces in alkaline (pH 8.0) Chloride solutions were investigated by potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM). The data obtained indicate that glucose behaves as a mixed-type inhibitor by physically adsorbing onto copper surfaces according to the Langmuir isotherm. The inhibition activity of glucose increases with increasing the concentration of glucose.
Similar content being viewed by others
References
Kilinççeker, G. and Demir, H., Prot. Met. Phys. Chem. Surf., 2013, vol. 49, no. 6, pp. 788–797.
Kilinççeker, G. and Demir, H., Anti-Corros. Methods Mater., 2013, vol. 60, p. 134.
Umoren, S.A., Li, Y., and Wang, F.H., Corros. Sci., 2010, vol. 52, p. 2422.
Leckie, H.P. and Uhling, H.H., J. Electrochem. Soc., 1966, vol. 113, p. 1262.
Jafari, A.H., Hosseini, S.M.A., and Jamalizadeh, E., Electrochim. Acta, 2010, vol. 55, p. 9004.
Kabasakaloglu, M., Kiyak, T., Sendil, O., and Asan, A, Appl. Surf. Sci., 2002, vol. 193, p. 167.
Bockris, J.O.M. and Reddy, A.K.N., Modern Electrochemistry, New York: Plenum Press, 1977, vol. 2.
Erbil, M. and Lorenz, W., Werkst. Korros., 1978, vol. 29, p. 505.
Rozenfeld, I.L. and Hardin, R., Corrosion Inhibitors, New York McGraw-Hill, 1981.
Qin, T.T., Li, J., Luo, H.Q., et al., Corros. Sci., 2011, vol. 53, p. 1072.
Wang, X., Yang, H., and Wang, F., Corros. Sci., 2011, vol. 53, p. 113.
Aksüt, A.A. and Bilgiç, S., Corros. Sci., 1992, vol. 33, p. 379.
Sherif, E.S.M., Appl. Surf. Sci., 2006, vol. 252, p. 8615.
Khaled, K.F., Mater. Chem. Phys., 2008, vol. 112, p. 104.
Baeza, H., Guzman, M., Ortega, P., and Vera, L., J. Chil. Chem. Soc., 2003, vol. 48, p. 1.
Kilinççeker, G. and Erbil, M., Mater. Chem. Phys., 2010, vol. 119, p. 30.
Abdallah, M., Corros. Sci., 2002, vol. 44, p. 717.
Feng, Y., Siow, K.S., Teo, W.K., and Hsieh, A.K., Corros. Sci., 1999, vol. 41, p. 829.
Musa, A.Y., Kadhum, A.A.H., Mohamad, A.B., and Takriff, M.S., Corros. Sci., 2010, vol. 52, p. 3331.
Ahamad, I., Prasad, R., and Quraishi, M., Corros. Sci., 2010, vol. 52, p. 3033.
Obot, I.B., Obi-Egbedi, N.O., and Umoren, S.A., Corros. Sci., 2009, vol. 51, p. 276.
Soneyik, V.L. and Jenkins, D., Water Chemistry, New York John Wiley & Sons, 1980.
Aytaç, A., Özmen, Ü., and Kabasakaloglu, M., Mater. Chem. Phys., 2005, vol. 89, p. 176.
Kilinççeker, G., Yazici, B., Yilmaz, A., and Erbil, M., Br. Corros. J., 2002, vol. 37, p. 23.
Kilinççeker, G., Taze, N., Galip, H., and Yazici, B., Anti-Corros. Methods Mater., 2011, vol. 58, p. 4.
Stern, M. and Geary, A.L., J. Electrochem. Soc., 1957, vol. 104, p. 56.
Khaled, K.F., Corros. Sci., 2010, vol. 52, p. 3225.
Kilinççeker, G., Colloids Surf., A, 2008, vol. 329, p. 112.
Kilinççeker, G. and Menekse, C., Prot. Met. Phys. Chem. Surf., 2015, vol. 51, no. 4, pp. 659–666.
Pavithra, M.K., Venkatesha, T.V., Vathsala, K., and Nayana, K.O., Corros. Sci., 2010, vol. 52, p. 3811.
Abd El-Maksoud, S.A., Corros. Sci., 2002, vol. 44, p. 803.
Ali, J.Z., Guo, X.P., Qu, J.E., et al., Colloids Surf., A, 2006, vol. 281, p. 147.
Kilinççeker, G. and Galip H., Prot. Met. Phys. Chem. Surf., 2009, vol. 45, no. 2, p. 232.
Tavakoli, H., Shahrabi, T., and Hosseini, M.G., Mater. Chem. Phys., 2008, vol. 109, p. 281.
Hamed, E., Mater. Chem. Phys., 2010, vol. 121, p. 70.
Zhang, Q.B. and Hua, Y.X., Electrochim. Acta, 2009, vol. 54, p. 1881.
Kilinççeker, G. and Çelik, S., Ionics, 2013, vol. 19, p. 1655.
Sherif, E.M. and Park, S.M., Electrochim. Acta, 2006, vol. 51, p. 6556.
Damaskin, B.B., Petrii, O.A., and Batrakov, V.V., Adsorption of Organic Compounds on Electrodes, New York Plenum Press, 1971.
Lipkowski, J. and Ross, P.N., Adsorption of Molecules at Metal Electrodes, New York VCH, 1992.
Herrag, L., Chetouani, A., Elkadiri, S., et al., Electrochim. Acta, 2008, vol. 26, p. 211.
Yohai, L., Schreiner, W.H., Vazquez, M., and Valcarce, M., Appl. Surf. Sci., 2011, vol. 257, p. 10089.
Author information
Authors and Affiliations
Corresponding author
Additional information
The article is published in the original.
Rights and permissions
About this article
Cite this article
Kılınççeker, G., Doğan, T. The influences of glucose on corrosion behaviour of copper in chloride solution. Prot Met Phys Chem Surf 52, 910–920 (2016). https://doi.org/10.1134/S2070205116050129
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S2070205116050129