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The effect of aggregate state of octa-(benzo-15-crown-5)-substituted phthalocyanines in aqueous solutions on the structure of self-organized composites of ultrathin ion layers

  • Nanoscale and Nanostructured Materials and Coatings
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Abstract

The method of layer-by-layer (LbL) deposition from aqueous solutions was used to obtain electrostatic self–organized composites consisting of cationic fragments of octa-[(4′-benzo-15-crown-5)oxy]phthalocyaninates of metals (Mcr8Pc)/K+ and anionic fragments of sodium polystyrenesulfonate or 4,4′,4″,4‴-[cobalt phthalocyaninate-2,(3),9,(10),16,(17),23,(24)-tetrayl-tetrakis(oxy)]-tetrabenzoic acid. The electronic absorption spectra of composite coatings indicate preservation of structures formed in aqueous solutions of Mcr8Pc: coaxial associates, noncoaxial associates, and high-order aggregates. An increase in the content of noncoaxial associates and the possible presence of suspension particles in the composite are observed.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, building 4, Moscow, 119071, Russia

    E. V. Ovsyannikova, V. E. Baulin, I. P. Kalashnikova, V. I. Zolotarevskii, V. N. Andreev, A. Yu. Tsivadze & N. M. Alpatova

  2. Institute of Physiologically Active Substances, Russian Academy of Sciences, Chernogolovka, 142432, Russia

    V. E. Baulin & I. P. Kalashnikova

Authors
  1. E. V. Ovsyannikova
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  2. V. E. Baulin
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  3. I. P. Kalashnikova
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  4. V. I. Zolotarevskii
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  5. V. N. Andreev
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  6. A. Yu. Tsivadze
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  7. N. M. Alpatova
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Corresponding author

Correspondence to V. E. Baulin.

Additional information

Original Russian Text © E.V. Ovsyannikova, V.E. Baulin, I.P. Kalashnikova, V.I. Zolotarevskii, V.N. Andreev, A.Yu. Tsivadze, N.M. Alpatova, 2016, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2016, Vol. 52, No. 5, pp. 525–532.

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Ovsyannikova, E.V., Baulin, V.E., Kalashnikova, I.P. et al. The effect of aggregate state of octa-(benzo-15-crown-5)-substituted phthalocyanines in aqueous solutions on the structure of self-organized composites of ultrathin ion layers. Prot Met Phys Chem Surf 52, 839–846 (2016). https://doi.org/10.1134/S2070205116040195

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  • DOI: https://doi.org/10.1134/S2070205116040195

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