Abstract
The adsorption capacity of studied aluminosilicate samples was found to depend significantly on the sizes of grains of adsorbents. The equations for calculating the statistical exchange capacity of aluminosilicate of different fractions in relation to ions of heavy metals Ni(II), Cu(II), Zn(II), Fe(III), and Cr(III) were derived. The effective coefficients of diffusion in the adsorbent grain and in the film of solution were found. It was determined that external diffusion kinetics served as a limiting step of adsorption. The rate of the process was determined as varying from 0.16 × 10–6 to 2.8 × 10–6 mol/m2 s.
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References
Breck, D.W., Zeolite Molecular Sieves: Structure, Chemistry, and Use, New York: Wiley, 1973.
Meier, W.M., Molecular Sieves, London: Soc. Chem. Ind., 1968, p. 10.
Zhdanov, S.P. and Egorova, E.N., Khimiya tseolitov (Chemistry of Zeolites), Leningrad: Nauka, 1968.
Zhdanov, S.P., Khvoshchev, S.S., and Samulevich, N.N., Sinteticheskie tseolity (Synthetic Zeolites), Moscow: Khimiya, 1981.
Batjargal, T., Yang, J.-S., Kim, D.-H., and Baek, K., Sep. Sci. Technol., 2011, vol. 46, p. 1313.
Al-Haj Ali, A. and El-Bishta, R., J. Chem. Technol. Biotechnol., 1997, vol. 69, no. 1, p. 27.
Salunkhe, B. and Raut, S.J., Int. J. Chem. Res., 2012, vol. 10, p. 1133.
Egashira, R., Tanabe, S., and Habaki, H., J. Chem. Eng. Jpn., 2013, vol. 46, p. 50.
Zhao, B., Zhang, L, Narty, O.D., and Li, R., Asian J. Chem., 2013, vol. 25, p. 3161.
Hamidpour, M., Kalbasi, M., and Afyuni, M., J. Hazard. Mater., 2010, vol. 181, nos. 1–3, p. 686.
Smical, I., AACL Bioflux, 2011, vol. 4, p. 481.
Marinos, A. Stylianou, S., and Michalis, P., J. Hazard. Mater., 2007, vol. 143, nos. 1–2, p. 575.
Argun, M., J. Hazard. Mater., 2008, vol. 150, p. 587.
Jovanovic, M., Rajic, N., and Obradovic, B., J. Hazard. Mater., 2012, vols. 233–234, no. 9, p. 57.
Shi, L.-N., Zhou, Y., Chen, Z., Megharaj, M., and Naidu, R., Environ. Sci. Pollut. Res., 2013, vol. 20, p. 3639.
Maicaneanu, A., Bedelean, H., Burca, S., and Stanca, M., Stud. Univ. Babes-Bolyai, Chem., 2009, vol. 3, p. 127.
Vasil’ev, V.P., Analiticheskaya khimiya (Analytical Chemistry), Moscow: Drofa, 2004, in 2 vols.
Lur’e, Yu.Yu. and Rybnikova, A.I., Khimicheskii analiz proizvodstvennykh stochnykh vod (Chemical Analysis of Industrial Waste Waters), Moscow: Khimiya, 1974.
Marczenko, Z., Spektrofotometryczne Oznaczanie Pierwiastków, Warszawa: Panstw. Wydaw. Nauk, 1971.
PND (Normative Documents) F 14.1:2.50-96: Sulfosalicylic acid photometric determination of the mass concentration of total iron in natural and waste waters.
PND (Normative Documents) F 14.1:2.52-9: Diphenylcarbazide photometric determination of the mass concentration of chromium ions in natural and waste waters.
Pomazkina, O.I., Filatova, E.G., and Pozhidaev, Yu.N., Prot. Met. Phys. Chem. Surf., 2014, vol. 50, no. 3, p. 312.
Marhol, M., Ion Exchangers in Analytical Chemistry, New York: Elsevier, 1982.
Pomazkina, O.I., Filatova, E.G., and Pozhidaev, Yu.N., Prot. Met. Phys. Chem. Surf., 2015, vol. 51, no. 4, p. 518.
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Original Russian Text © E.G. Filatova, Yu.N. Pozhidaev, O.I. Pomazkina, 2016, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2016, Vol. 52, No. 3, pp. 285–289.
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Filatova, E.G., Pozhidaev, Y.N. & Pomazkina, O.I. Investigation of adsorption of heavy metal ions by natural aluminosilicate. Prot Met Phys Chem Surf 52, 438–442 (2016). https://doi.org/10.1134/S2070205116030102
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DOI: https://doi.org/10.1134/S2070205116030102