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A Study of the Kinetics of Adsorption of Zinc(II) Ions by a Natural Aluminosilicate of Eastern Transbaikalia

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Abstract

The adsorption of zinc ions by a natural aluminosilicate of Eastern Transbaikalia has been investigated. The effect of the grain size of aluminosilicate on the adsorption of zinc ions has been studied. It has been determined that, along with the decrease of the grain size from 5 to 0.1 mm, the adsorption value increased by 3.8 times and reached a value of 0.075 mmol/g. The kinetics of zinc adsorption at pH 5.4 in the temperature range from 298 to 318 K have been studied using pseudo-first- and -second-order models. It has been determined that the adsorption of zinc ions decreases along with the increasing temperature. It has been shown that the adsorption kinetics are best described by the second-order model. The values of the correlation coefficients were 0.998–0.999. The maximum value of the adsorption rate constant of 0.446 g/(mmol min) corresponded to the temperature of 298 K. The value of the thermodynamic equilibrium constant decreased along with the increasing temperature. The studied adsorption process was followed by a small change in the enthalpy of ion exchange. The calculated values of ∆H and ΔG indicate an exothermic adsorption process with the formation of thermodynamically stable surface compounds of zinc(II) ions.

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Notes

  1. Modified natural aluminosilicates are also used for adsorption removal of zinc ions from wastewater [24].

REFERENCES

  1. Oren, A.H. and Kaya, A., J. Hazard. Mater., 2006, vol. 131, nos. 1–3, p. 59.

    Article  Google Scholar 

  2. Malamis, S. and Katsou, E., J. Hazard. Mater., 2013, vol. 15, nos. 252–253, p. 428.

    Article  Google Scholar 

  3. Cabrera, C., Gabaldon, C., and Marzal, P., J. Chem. Technol. Biotechnol., 2005, vol. 80, no. 4, p. 477.

    Article  CAS  Google Scholar 

  4. Athanasiadis, K. and Helmreich, B., Water Res., 2005, vol. 39, no. 8, p. 1527.

    Article  CAS  Google Scholar 

  5. Shavandi, M.A., Haddadian, Z., Ismail, M.H.S., Abdullah, N., and Abidin, Z.Z., J. Taiwan Inst. Chem. Eng., 2012, vol. 43, no. 5, p. 750.

    Article  CAS  Google Scholar 

  6. Stefanovic, S.C., Logar, N.Z., Margeta, K., Tusar, N.N., Arčon, I., Maver, K., Kovač, J., and Kaučič, V., Microporous Mesoporous Mater., 2007, vol. 105, no. 3, p. 251.

    Article  Google Scholar 

  7. Fomin, G.S., Voda. Kontrol’ khimicheskoi, bakterial’noi i radiatsionnoi bezopasnosti po mezhdunarodnym standartam (Water. Monitoring of Chemical, Bacterial, and Radiation Safety in Accordance with International Standards), Moscow: Protektor, 2010.

  8. Coruh, S., Desalination, 2008, vol. 225, nos. 1–3, p. 41.

    Article  CAS  Google Scholar 

  9. Peric, J., Trgo, M., and Medvidovic, N.V., Water Res., 2004, vol. 38, no. 7, p. 1893.

    Article  CAS  Google Scholar 

  10. Alyuz, B. and Veli, S., J. Hazard. Mater., 2009, vol. 167, nos. 1–3, p. 482.

    Article  Google Scholar 

  11. Trgo, M., Peric, J., and Medvidovic, N.V., J. Hazard. Mater., 2006, vol. 136, no. 3, p. 938.

    Article  CAS  Google Scholar 

  12. Jovanovic, M., Rajic, N., and Obradovic, B., J. Hazard. Mater., 2012, vol. 233, p. 57.

    Article  Google Scholar 

  13. Filatova, E.G., Pozhidaev, Yu.N., and Pomazkina, O.I., Prot. Met. Phys. Chem. Surf., 2016, vol. 52, no. 3, p. 438.

    Article  CAS  Google Scholar 

  14. Breck, D.W., Zeolite Molecular Sieves: Structure, Chemistry, and Use, New York: Wiley, 1973.

    Google Scholar 

  15. Tsitsishvili, G.V., Andronikoshvili, T.G., Kirov, G.N., and Filizova, L.D., Prirodnye tseolity (Natural Zeolites), Moscow: Nauka, 1988.

  16. Lur’e, Yu.Yu. and Rybnikova, A.I., Khimicheskii analiz proizvodstvennykh stochnykh vod (Chemical Analysis of Industrial Waste Waters), Moscow: Khimiya, 1974.

  17. Marczenko, Z., Spectrophotometric Determination of the Elements, Ellis Horwood Series in Analytical Chemistry, New York: Wiley, 1976.

    Google Scholar 

  18. Kaya, A. and Oren, A.H., J. Hazard. Mater., 2005, vol. 125, nos. 1–3, p. 183.

    Article  CAS  Google Scholar 

  19. Chelishchev, N.F., Volodin, V.F., and Kryukov, V.L., Ionoobmennye svoistva prirodnykh vysokokremnistykh tseolitov (Ion-Exchange Properties of Natural High-Silicon Zeolites), Moscow: Nauka, 1988.

  20. Chelishchev, N.F., Gribanov, N.K., and Kryukov, V.L., Khromatograficheskoe razdelenie shchelochnykh metallov na klinoptilolite (Chromatographic Separation of Alkaline Metals on Clinoptilolite), Tbilisi: Metsniereba, 1977.

  21. Tsivadze, A.Yu., Rusanov, A.I., Fomkin, A.A., et al., Fizicheskaya khimiya adsorbtsionnykh yavlenii (Physical Chemistry of Adsorption Phenomena), Moscow: Granitsa, 2011.

  22. Pomazkina, O.I., Filatova, E.G., and Pozhidaev, Yu.N., Prot. Met. Phys. Chem. Surf., 2017, vol. 53, no. 3, p. 416.

    Article  CAS  Google Scholar 

  23. Filatova, E.G., Pomazkina, O.I., and Pozhidaev, Y.N., J. Water Chem. Technol., 2014, vol. 36, no. 6, p. 303.

    Article  Google Scholar 

  24. Filatova, E.G., Pozhidaev, Yu.N., and Pomazkina, O.I., Prot. Met. Phys. Chem. Surf., 2020, vol. 56, no. 5, p. 911.

    Article  Google Scholar 

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Funding

The work was carried out with the financial support of project of the Russian Foundation for Fundamental Research no. 18-08-00718.

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Authors and Affiliations

  1. Irkutsk National Research Technical University, 664074, Irkutsk, Russia

    E. G. Filatova, O. I. Pomazkina & Yu. N. Pozhidaev

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  1. E. G. Filatova
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  2. O. I. Pomazkina
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  3. Yu. N. Pozhidaev
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Correspondence to E. G. Filatova.

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Translated by D. Marinin

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Filatova, E.G., Pomazkina, O.I. & Pozhidaev, Y.N. A Study of the Kinetics of Adsorption of Zinc(II) Ions by a Natural Aluminosilicate of Eastern Transbaikalia. Prot Met Phys Chem Surf 58, 935–940 (2022). https://doi.org/10.1134/S2070205122050069

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