Skip to main content
SpringerLink
Log in

Characterization of the alumino–silico–oxygen clinoptilolite framework and its hydrogen forms via IR spectroscopy

  • Investigation Methods for Physicochemical Systems
  • Published:
Protection of Metals and Physical Chemistry of Surfaces Aims and scope Submit manuscript

Abstract

In this work, clinoptilolite hydrogen forms are obtained from the Khonguruu zeolite locality (Republic of Sakha, Russia) using hydrochloric acid solutions of different concentrations. The chemical composition is identified via X-ray spectral microprobe analysis and thermogravimetry. IR vibrational spectra of the alumino–silico–oxygen framework are studied in its dealumination and decationization. The effect of the aluminum content in clinoptilolite hydrogen forms on the intensity change and frequencies of the principal vibrational bands of alumino–silico–oxygen framework is established as well.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Breger, J.A., Chandler, I.C., and Zubovic, P., Am. Mineral., 1970, vol. 55, p. 825.

    Google Scholar 

  2. Barrer, R.M. and Makki, M.B., Can. J. Chem., 1964, vol. 42, p. 1481.

    Article  Google Scholar 

  3. Tsitsishvili, G.V. and Tsitsishvili, V.G., Khim., Fiz., Tekhnol. Poverkhn., 2011, vol. 2, p. 329.

    Google Scholar 

  4. Rhodes, C.J., Sci. Progr., 2010, vol. 93, p. 223.

    Article  Google Scholar 

  5. Spiridonov, A.M., Koryakina, V.V., Okhlopkova, A.A., et al., Vestn. Sev.-Vost. Fed. Univ. im. M.K. Ammosova, 2014, vol. 11, pp. 7–12.

    Google Scholar 

  6. Spiridonov, A.M., Sokolova, M.D., Okhlopkova, A.A., et al., J. Struct. Chem., 2015, vol. 56, no. 2, pp. 297–303.

    Article  Google Scholar 

  7. Brek, D., Zeolite Molecular Sieves: Structure, Chemistry and Use, New York: Wiley, 1973.

    Google Scholar 

  8. Murata, K.J., Am. Mineral., 1943, vol. 28, p. 545.

    Google Scholar 

  9. Mishin, I.V., Bayer, G.K., Klyachko, A.L., et al., Kinet. Katal., 1987, vol. 28, p. 706.

    Google Scholar 

  10. Minachev, Kh.M., Dmitriev, R.V., Mishin, I.V., and Klyachko, A.L., Russ. Chem. Bull., 1979, vol. 28, p. 2241.

    Article  Google Scholar 

  11. Flanigan, E.M., Khatami, H., and Szymanski, H.A., Am. Chem. Soc., 1970, p. 460.

    Google Scholar 

  12. Wright, A.C., Rupert, J.P. and Granquist, W.T., Am. Mineral., 1968, vol. 53, p. 1293.

    Google Scholar 

  13. Zonkhoeva, E.L. and Sanzhanova, S.S., Russ. J. Phys. Chem. A, 2011, vol. 85, p. 1233.

    Article  Google Scholar 

  14. Garcia-Basabe, Y., Rodriguez-Iznag, I., de Menorval, L.-Ch., et al., Microporous Mesoporous Mater., 2010, vol. 135, p. 187.

    Article  Google Scholar 

  15. Bel’chinskaya, L.I., Khokhlov, V.Yu., Lu, T.Y. et al., Prot. Met. Phys. Chem. Surf., 2012, vol. 48, p. 322.

    Article  Google Scholar 

  16. Mozgawa, W., J. Mol. Struct., 2000, vol. 555, p. 299.

    Article  Google Scholar 

  17. Crupi, V., Longo, F., Majolino, D., and Venuti, V., J. Chem. Phys., 2005, vol.123.

  18. Hannachi, Y., Ghorbel, A., Lasram, T., and Boubaker, T., Chem. Ecol., 2012, vol. 28, p. 481.

    Article  Google Scholar 

  19. Ates, A. and Hardacre, Ch., Colloid Interface Sci., 2012, vol. 372, p. 130.

    Article  Google Scholar 

  20. Nakamoto, K., Infrared and Raman Spectra of Inorganic and Coordination Compounds. Part A, New Jersey: Wiley, 2009.

    Google Scholar 

  21. Milkey, R.G., Am. Mineral., 1960, vol. 45, p. 990.

    Google Scholar 

  22. Doerffel, K., Statistik in der Analytischen Chemie, Leipzig: VEB Deutscher Verlag für Grundstoffindustrie, 1966.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Northeastern Federal University, Yakutsk, Republic of Sakha, Russia

    A. M. Spiridonov, A. L. Fedorov, M. D. Sokolova, A. A. Okhlopkova, T. A. Okhlopkova & R. V. Borisova

  2. Institute of Oil and Gas Problems, Siberian Branch, Russian Academy of Sciences, Yakutsk, Republic of Sakha, Russia

    A. L. Fedorov, M. D. Sokolova & A. A. Okhlopkova

Authors
  1. A. M. Spiridonov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. L. Fedorov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. D. Sokolova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. A. Okhlopkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. T. A. Okhlopkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. R. V. Borisova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. M. Spiridonov.

Additional information

Original Russian Text © A.M. Spiridonov, A.L. Fedorov, M.D. Sokolova, A.A. Okhlopkova, T.A. Okhlopkova, R.V. Borisova, 2016, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2016, Vol. 52, No. 4, pp. 442–448.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Spiridonov, A.M., Fedorov, A.L., Sokolova, M.D. et al. Characterization of the alumino–silico–oxygen clinoptilolite framework and its hydrogen forms via IR spectroscopy. Prot Met Phys Chem Surf 52, 744–750 (2016). https://doi.org/10.1134/S2070205116020283

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070205116020283

Search

Navigation