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Regularities of the mechanism of protodesorption of metal cations in the heterophase system of H2O-HCl-MCl2-Cellulose sorbent

  • Physicochemical Processes at the Interfaces
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Abstract

The effect of pH of the medium on the process of distribution of Co(II), Cu(II), and Ni(II) ions in a heterophase system of H2O-HCl-MCl2-wood cellulose is studied. The specifics of the mechanism of metal cation protodesorption are explained by the experimental linear correlation dependence of the distribution coefficient of metal cations on the acidity of the medium in the logarithmic scale, logK D = f(pH), with tanα ≈ 1/4, which is inconsistent with the classical mechanism of simple ion exchange of M2+ to 2H+. The underrating of the exponent corresponding to proton participation in desorption of the metal cation is due to participation of their carrier-anions in the interphase exchange in the form of MCl2 and 2HCl, which allows the mechanism of metal cation protodesorption to be interpreted in the terms of the general equation of inter-phase ion exchange in the molecular form.

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References

  1. Hubbe, M.A., Hasan, S.H., and Ducoste, J.J., BioResources, 2011, vol. 6, p. 2161.

    Google Scholar 

  2. Farooq, U., Kozinski, J.A., Khan, M.A., and Athar, M., Bioresour. Technol., 2010, vol. 101, p. 5643.

    Article  Google Scholar 

  3. Demirbas, A., J. Hazard. Mater., 2008, vol. 157, p. 220.

    Article  Google Scholar 

  4. Farinella, N.V., Matos, G.D., and Arruda, M.A.Z., Bioresour. Technol., 2007, vol. 98, p. 1940.

    Article  Google Scholar 

  5. Nikiforova, T.E., Bagrovskaya, N.A., Kozlov, V.A., and Lilin, S.A., Khim. Rastit. Syr’ya, 2009, no. 1, p. 5.

    Google Scholar 

  6. Nikiforova, T.E. and Kozlov, V.A., Zh. Fiz. Khim., 2012, vol. 86, no. 10, p. 1724.

    Google Scholar 

  7. Sobgaida, N.A., Ol’shanskaya, L.N., and Makarova, Yu.A., Izv. VUZov, Ser. Khim. Khim. Tekhnol., 2010, vol. 53, no. 11, p. 36.

    Google Scholar 

  8. Frolov, Yu.G., Kurs kolloidnoi khimii. Poverkhnostnye yavleniya i dispersnye sistemy (Lecturers on Colloid Chemistry. Surface Events and Disperse Systems), Moscow: Khimiya, 1988.

    Google Scholar 

  9. Nikitin, N.I., Khimiya drevesiny i tsellyulozy (Chemistry of Wood and Cellulose), Moscow: Akad. Nauk SSSR, 1962.

    Google Scholar 

  10. Saldadze, K.M. and Kopylova-Valova, V.D., Kompleksoobrazuyushchie ionity (kompleksity) (Complexing Ion Exchanger: Complexites), Moscow: Khimiya, 1980.

    Google Scholar 

  11. Aydin, H., Bulut, Y., and Yerlikaya, C., J. Environ. Manage., 2008, vol. 87, p. 37.

    Article  Google Scholar 

  12. Hamissa, A., Lodi, A., Seffen, M., et al., Chem. Eng. J., 2010, vol. 159, p. 67.

    Article  Google Scholar 

  13. Garcia-Rosales, G. and Colin-Cruz, A., J. Environ. Manage., 2010, vol. 91, p. 2079.

    Article  Google Scholar 

  14. Farinella, N.V., Matos, G.D., and Arruda, M.A.Z., Bioresource Technol., 2007, vol. 98, p. 1940.

    Article  Google Scholar 

  15. Jolly, G., Dupont, L., Apiincourt, M., and Lambert, J., Environ. Chem. Lett., 2006, vol. 4, p. 219.

    Article  Google Scholar 

  16. De Sousa, D.A., Oliveira, E., Costa Nogueira, M., and Esposito, B.P., Bioresour. Technol., 2010, vol. 101, p. 138.

    Article  Google Scholar 

  17. Escudero, C., Gabaldon, C., Marzal, P., and Villaescusa, I., J. Hazard. Mater., 2008, vol. 152, p. 476.

    Article  Google Scholar 

  18. Pagnanelli, F., Mainelli, S., and Toro, L., Water Res., 2008, vol. 42, p. 2953.

    Article  Google Scholar 

  19. Nikiforova, T.E., Kozlov, V.A., and Islyaikin, M.K., Russ. J. Phys. Chem. A, 2012, no. 86, no. 12, p. 1836.

    Google Scholar 

  20. Akhnazarova, S.L. and Kafarov, V.V., Metody optimizatsii eksperimenta v khimicheskoi tekhnologii (Methods of Experiment Optimization in Chemical Technology), Moscow: Vysshaya Shkola, 1985.

    Google Scholar 

  21. Nikiforova, T.E. and Kozlov, V.A., Prot. Met. Phys. Chem. Surf., 2011, no. 47, no. 1, p. 20.

    Google Scholar 

  22. Nikiforova, T.E., Kozlov, V.A., and Loginova, V.A., Adsorpt. Sci. Technol., 2014, vol. 32, p. 389.

    Article  Google Scholar 

  23. Fizicheskaya khimiya. Teoreticheskoe i prakticheskoe rukovodstvo (Physical Chemistry: Theoretical and Practical Manual), Nikol’skii, B.P., Ed., Leningrad: Khimiya, 1987, 2nd ed.

    Google Scholar 

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Authors and Affiliations

  1. Ivanovo State University of Chemistry and Technology, Sheremetev av. 7, Ivanovo, 153000, Russia

    V. A. Kozlov & T. E. Nikiforova

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  1. V. A. Kozlov
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  2. T. E. Nikiforova
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Correspondence to V. A. Kozlov.

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Original Russian Text © V.A. Kozlov, T.E. Nikiforova, 2015, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2015, Vol. 51, No. 4, pp. 362–369.

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Kozlov, V.A., Nikiforova, T.E. Regularities of the mechanism of protodesorption of metal cations in the heterophase system of H2O-HCl-MCl2-Cellulose sorbent. Prot Met Phys Chem Surf 51, 510–517 (2015). https://doi.org/10.1134/S2070205115040206

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  • DOI: https://doi.org/10.1134/S2070205115040206

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