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The Influence of Chemical Modification of Cellulose with 4-Aminobenzoic Acid on Sorption of Cu(II) Ions

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Abstract

The effect of chemical modification on the sorption properties of cellulose with respect to Cu(II) ions has been studied. Modification was carried out through the oxidation of cellulose with sodium metaperiodate with the formation of dialdehyde cellulose, its subsequent interaction with 4-aminobenzoic acid and conversion into a derivative capable of chelating heavy metal ions. Analysis of the obtained sample with grafted carboxyl groups is carried out, and a conclusion is drawn about the influence of the structure of sorption centers on the efficiency of sorption of heavy metal ions. The kinetics and equilibrium of sorption of Cu(II) ions by the modified sorbent in comparison with the native sample have been investigated. Sorption kinetic curves were processed within the framework of the pseudofirst and -second order kinetic models. The results of the kinetic experiment are described most correctly within the framework of the pseudosecond order model. The experimental isotherms of sorption of Cu(II) ions from aqueous solutions by native and modified cellulose are well described by the Langmuir equation. The processing of isotherms in the linear form of the equation made it possible to determine the values of the limiting sorption of Cu(II) ions by the studied cellulose samples. The modified sorbent surpasses native cellulose in sorption capacity by about 2.7 times, which is due to the presence of new sorption centers in its structure. Studies performed by scanning electron microscopy indicate a change in the surface structure of the modified sorption material in comparison with the original one. IR spectra indicate the appearance in cellulose in the process of modification carboxyl groups.

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REFERENCES

  1. Hubbe, M.A., Hasan, S.H., and Ducoste, J.J., BioResources, 2011, vol. 6, no. 2, p. 2161.

    Article  Google Scholar 

  2. Bădescua, I.S., Bulgariu, D., Ahmadd, I., and Bulgariua, L., J. Environ. Manage., 2018, vol. 224, p. 288.

    Article  Google Scholar 

  3. Nikiforova, T.E., Kozlov, V.A., and Sionikhina, A.N., Prot. Met. Phys. Chem. Surf., 2019, vol. 55, no. 5, p. 849.

    Article  CAS  Google Scholar 

  4. Losev, N.V., Nikiforova, T.E., Makarova, L.I., and Lipatova, I.M., Prot. Met. Phys. Chem. Surf., 2017, vol. 53, no. 5, p. 801.

    Article  CAS  Google Scholar 

  5. Ali, A., Mannan, A., Hussain, I., Hussain, I., and Zia, M., Environ. Nanotechnol. Monit. Manage., 2018, vol. 9, p. 1.

    Google Scholar 

  6. Fakhre, N.A. and Ibrahim, B.M., J. Hazard. Mater., 2018, vol. 343, p. 324.

    Article  CAS  Google Scholar 

  7. Kumar, R., Sharma, R.Kr., and Singh, A.P., J. Mol. Liq., 2017, vol. 232, p. 62.

    Article  CAS  Google Scholar 

  8. Nikiforova, T.E., Kozlov, V.A., Bagrovskaya, N.A., and Rodionova, M.V., Russ. J. Appl. Chem., 2007, vol. 80, no. 2, p. 236.

    Article  CAS  Google Scholar 

  9. Wei, W., Kim, S., Song, M.-H., Bediako, J.K., and Yun, Y.-S., J. Taiwan Inst. Chem. Eng., 2015, vol. 57, p. 104.

    Article  CAS  Google Scholar 

  10. Ren, H., Gao, Z., Wu, D., Jiang, J., Sun, Y., and Luo, C., Carbohydr. Polym., 2016, vol. 137, p. 402.

    Article  CAS  Google Scholar 

  11. Zhou, D., Zhang, L., and Guo, S., Water Res., 2005, vol. 39, p. 3755.

    Article  CAS  Google Scholar 

  12. Gopi, S., Balakrishnan, P., Chandradhara, D., Poovathankandy, D., and Thomas, S., Mater. Today Chem., 2019, vol. 13, p. 59.

    Article  CAS  Google Scholar 

  13. Vatansever, E., Arslan, D., and Nofar, M., Int. J. Biol. Macromol., 2019, vol. 137, p. 912.

    Article  CAS  Google Scholar 

  14. Chitpong, N. and Husson, S.M., J. Membr. Sci., 2017, vol. 523, p. 418.

    Article  CAS  Google Scholar 

  15. Qiu, X. and Hu, S., Materials (Basel), 2013, vol. 6, no. 3, p. 738.

    Article  Google Scholar 

  16. Kokotov, Yu.A. and Pasechnik, V.A., Ravnovesie i kinetika ionnogo obmena (Equilibrium and Kinetic of Ion Exchange), Leningrad: Khimiya, 1970.

  17. Vasil’ev, V.P., Morozova, R.P., and Kochergina, L.A., Analiticheskaya khimiya. Laboratornyi praktikum: uchebnoe posobie dlya vuzov khimiko-tekhnologicheskogo profilya (Analytical Chemistry. Laboratory Practical Course: Student’s Book for Institutions of Higher Chemical-Technological Education), Vasil’ev, V.P., Ed., Moscow: Drofa, 2004.

  18. Akhnazarova, S.L. and Kafarov, V.V., Metody optimizatsii eksperimenta v khimicheskoi tekhnologii (Methods for Optimizing Experiment for Chemical Technology), Moscow: Vysshaya Shkola, 1985.

  19. Klemm, D., Philipp, B., Heinze, D., Heinze, U., and Wagenknecht, W., Comprehensive Cellulose Chemistry, vol. 1: Fundamentals and Analytical Methods, Weinheim: Wiley-WCH, 1998.

    Google Scholar 

  20. Nikiforova, T.E. and Kozlov, V.A., Russ. J. Gen. Chem., 2011, vol. 81, no. 10, p. 2136.

    Article  CAS  Google Scholar 

  21. Nikiforova, T.E. and Kozlov, V.A., Prot. Met. Phys. Chem. Surf., 2012, vol. 48, no. 6, p. 620.

    Article  CAS  Google Scholar 

  22. Bulgariu, D. and Bulgariu, L., Bioresour. Technol., 2012, vol. 103, p. 489.

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

The study was carried out using the resources of the Center for Collective Use of Scientific Equipment of the Federal State Budgetary Educational Institution of Higher Education Ivanovo State University of Chemical Technology.

Funding

The study was carried out using the resources of the Center for Shared Use of Scientific Equipment of the ISUCT (with the support of the Ministry of Science and Higher Education of Russia, grant no. 075-15-2021-671).

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Authors and Affiliations

  1. Ivanovo State University of Chemical Technology, 153000, Ivanovo, Russia

    T. E. Nikiforova, V. A. Kozlov & E. N. Karaseva

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  1. T. E. Nikiforova
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  2. V. A. Kozlov
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  3. E. N. Karaseva
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Correspondence to T. E. Nikiforova.

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Nikiforova, T.E., Kozlov, V.A. & Karaseva, E.N. The Influence of Chemical Modification of Cellulose with 4-Aminobenzoic Acid on Sorption of Cu(II) Ions. Prot Met Phys Chem Surf 57, 680–686 (2021). https://doi.org/10.1134/S2070205121040195

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  • DOI: https://doi.org/10.1134/S2070205121040195

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