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Sorption of Eu(III) on Merrifield resin modified with thiacalix[4]arenes

  • Molecular and Supramolecular Structures at the Interfaces
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Abstract

We have studied the sorption of Eu(III) ions on Merrifield resin (chloromethylated polystyrene) impregnated and covalently modified with tetrahydroxythiacalix[4]arenes that contain hydrogen atoms, tertbutyl, and dialkoxyphosphonylmethyl moieties on the macrocyclic upper rim. The resulting materials have a sorption capacity of up to 70 mg/g and allow one to extract up to 99% of Eu(III) from aqueous solutions with medium mineral content at pH 5.5–6.

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Authors and Affiliations

  1. Institute of Monocrystals, National Academy of Sciences of Ukraine, pr. Lenina 60, Kharkiv, 61178, Ukraine

    M. S. Lukashova, K. N. Belikov & E. Yu. Bryleva

  2. Karazin Kharkiv National University, pl. Svobody 4, Kharkiv, 61000, Ukraine

    K. N. Belikov

  3. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 5, Kyiv, 02660, Ukraine

    S. G. Kharchenko, S. G. Vishnevskii & V. I. Kal’chenko

Authors
  1. M. S. Lukashova
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  2. K. N. Belikov
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  3. E. Yu. Bryleva
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  4. S. G. Kharchenko
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  5. S. G. Vishnevskii
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  6. V. I. Kal’chenko
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Corresponding author

Correspondence to M. S. Lukashova.

Additional information

Original Russian Text © M.S. Lukashova, K.N. Belikov, E.Yu. Bryleva, S.G. Kharchenko, S.G. Vishnevskii, V.I. Kal’chenko, 2014, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2014, Vol. 50, No. 5, pp. 506–511.

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Lukashova, M.S., Belikov, K.N., Bryleva, E.Y. et al. Sorption of Eu(III) on Merrifield resin modified with thiacalix[4]arenes. Prot Met Phys Chem Surf 50, 608–612 (2014). https://doi.org/10.1134/S2070205114050116

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  • DOI: https://doi.org/10.1134/S2070205114050116

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