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Extraction of europium trifluoromethanesulfonate into nitrobenzene in the presence of some electroneutral calixarene ligands

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Abstract

From extraction experiments and γ-activity measurements, the extraction constants corresponding to the general equilibrium Eu3+(aq) + 3 A−(nb) + L(nb) ⇔ EuL3+(nb) + A−(nb) taking place in the two-phase water–nitrobenzene system (\( {\text{A}}^{ - } = {\text{CF}}_{3} {\text{SO}}_{3}^{ - } \); L = tetrakis(2-ethoxyethoxy)-tetra-p-tert-butylcalix[4]arene (1), tetraethyl p-tert-butylcalix[4]arene tetraacetate (2), p-tert-butylcalix[4]arene-tetrakis(N,N-diethylacetamide) (3), hexaethyl p-tert-butylcalix[6]arene hexaacetate (4), p-tert-butylcalix[6]arene-hexakis(N,N-diethylacetamide) (5); aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Further, the stability constants of the EuL3+ complexes in nitrobenzene saturated with water were calculated; they were found to increase in the series of 2 < 4 < 1 < 5 < 3.

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Acknowledgement

The present work was supported by the Czech Ministry of Education, Youth and Sports, Projects MSM 4977751303 and MSM 6046137307.

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Authors and Affiliations

  1. Faculty of Applied Sciences, University of West Bohemia, Husova 11, 306 14, Pilsen, Czech Republic

    E. Makrlík

  2. Institute of Chemical Technology, Technická 5, 166 28, Prague, Czech Republic

    J. Budka & P. Vaňura

  3. Nuclear Research Institute, 250 68, Řež, Czech Republic

    P. Selucký

Authors
  1. E. Makrlík
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  2. J. Budka
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  3. P. Vaňura
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  4. P. Selucký
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Correspondence to E. Makrlík.

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Makrlík, E., Budka, J., Vaňura, P. et al. Extraction of europium trifluoromethanesulfonate into nitrobenzene in the presence of some electroneutral calixarene ligands. J Radioanal Nucl Chem 283, 193–196 (2010). https://doi.org/10.1007/s10967-009-0205-5

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