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Form factor of the electron density of an anion specifically adsorbed on metal surface in an electrolyte

  • Physicochemical Processes at the Interfaces
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Abstract

The character of distribution of electron density over the proximity of a halide anion specifically adsorbed at the s,p-metal-electrolyte solution interface boundary was considered. An assumption was made that the physical nature of the specific bonding of the anion is caused by mixing of electron waves of free electrons in the metal and the valent state of the anion as the electrons resonantly overcome the potential barrier between the anion and the metal. The physical (dissipative quantum) mechanism of microscopic processes is described using the Anderson impurity model, the Friedel sum rule, and the Parr conception of equalization of electronegativity values that determine the partial transfer of electron charge from the anion to the metal and the emergence of localized dipole at the interphase boundary. The equations renormalizing the microscopic parameters of the adsorption event to macroscopic state functions of the adsorption phase on an electrode were obtained. The chemical potential of the halide anion specifically adsorbed from electrolyte solution on an uncharged electrode is estimated. The mechanism under consideration explains the details of the dependences of polarization parameters of the electrode on anion and metal nature.

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References

  1. Frumkin, A.N., Potentsialy nulevogo zaryada (Potentials of Zero Charge), Moscow: Nauka, 1982.

    Google Scholar 

  2. Marnin, Th., Bruinsma, R., and Platsman, P.M., Phys. Rep., 1993, vol. 223, p. 135.

    Article  Google Scholar 

  3. Lang, N.D., Phys. Rev. Lett., 1981, vol. 46, p. 842.

    Article  Google Scholar 

  4. Gabovich, A.M., Reznikov, Yu.A., and Voitenko, A.I., Phys. Rev. E, 2006, vol. 73. p. 021606.

    Article  Google Scholar 

  5. Kuklin, R.N., Elektrokhimiya, 1977, vol. 13, p. 1182.

    Google Scholar 

  6. Vorotyntsev, M.A. and Kornyshev, A.A., Elektrostatika sred s prostranstvennoi dispersiei (Electrostatics of Media with the Spatial Dispersion), Moscow: Nauka, 1993.

    Google Scholar 

  7. Gurney, R., Phys. Rev., 1935, vol. 45, p. 479.

    Article  Google Scholar 

  8. Grimley, T.B., Proc. Phys. Soc., 1967, vol. 90, p. 751.

    Article  Google Scholar 

  9. Bennett, A.J. and Falicov, L.M., Phys. Rev., 1966, vol. 151, p. 512.

    Article  Google Scholar 

  10. Lorenz, W. and Salie, G., Z. Phys. Chem., 1961, vol. 218, p. 259.

    Google Scholar 

  11. Schultze, J.W. and Vetter, K.J., J. Electroanal. Chem., 1973, vol. 44, p. 63.

    Article  Google Scholar 

  12. Koppitz, F.D., Schultze, J.W., and Rolle, D., J. Electroanal. Chem., 1984, vol. 170, p. 5.

    Article  Google Scholar 

  13. Parr, R.G. and Yang, W., Density Functional Theory of Atoms and Molecules, New York: Oxford Univ. Press, 1989.

    Google Scholar 

  14. Newns, D.M., Phys. Rev., 1969, vol. 178, p. 1123.

    Article  Google Scholar 

  15. Kuklin, R.N., Elektrokhimiya, 1979, vol. 15, p. 1763.

    Google Scholar 

  16. Landau L.D., Lifshits E.M., Kvantovaya mekhanika. Nerelyativistskaya teoriya (Quantum Mechanics. Nonrelativistic Theory), Moscow: Nauka, 1989.

    Google Scholar 

  17. Volokitin, A.I., Fiz. Tverd. Tela, 1978, vol. 20, p. 1206.

    Google Scholar 

  18. Medvedev, I.G., Khim. Fiz., 1985, vol. 4, p. 103.

    Google Scholar 

  19. Davydov, S.Yu. and Troshin, S.V., Phys. Solid State, 2007, vol. 49, p. 1583.

    Article  Google Scholar 

  20. Migdal, A.B., Kachestvennye metody v kvantovoi teorii (Qualitative Methods in Quantum Theory), Moscow: Nauka, 1975.

    Google Scholar 

  21. Fukui, K., Yonezawa, T., and Shingu, H., J. Chem. Phys., 1952, vol. 20, p. 722.

    Article  Google Scholar 

  22. Ziman, J., Principles of the Theory of Solids, Cambridge, Mass.: Cambridge Univ. Press, 1972.

    Book  Google Scholar 

  23. Langer, J.S. and Ambegaokar, V., Phys. Rev., 1961, vol. 121, p. 1090.

    Article  Google Scholar 

  24. Friedel, J., Philos. Mag., 1952, vol. 43, p. 153.

    Google Scholar 

  25. Langer, J.S., Phys. Rev., 1966, vol. 150, p. 516.

    Article  Google Scholar 

  26. Muscat, J.P. and Newns, D.M., J. Phys. C: Solid State Phys., 1974, vol. 7, p. 2630.

    Article  Google Scholar 

  27. Ashcroft, N. and Mermin, N., Solid State Physics, New York: Holt, Rinehart, and Winston, 1976.

    Google Scholar 

  28. Kratkii spravochnik fiziko-khimicheskikh velichin (Brief Handbook on Physicochemical Values), Mishchenko, K.P. and Ravdel’, A.A, Eds., Moscow: Goskhimizdat, 1974.

    Google Scholar 

  29. Grahame, D.C., J. Am. Chem. Soc., 1954, vol. 76, p. 4819.

    Article  Google Scholar 

  30. Kuklin, R.N. and Emets, V.V., Prot. Met. Phys. Chem. Surf., 2012, vol. 48, no. 4, p. 406.

    Article  Google Scholar 

  31. Kuklin, R.N., Elektrokhimiya, 1979, vol. 15, p. 1763.

    Google Scholar 

  32. Kuklin, R.N., Elektrokhimiya, 1982, vol. 18, p. 1526.

    Google Scholar 

  33. Kuklin, R.N. and Emets, V.V., Russ. J. Phys. Chem. B, 2009, vol. 3, p. 818.

    Article  Google Scholar 

  34. Kuklin, R.N., Inform.-Analit. Zh., 2008, no. 6, p. 131.

    Google Scholar 

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119071, Russia

    R. N. Kuklin & V. V. Emets

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  1. R. N. Kuklin
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  2. V. V. Emets
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Correspondence to R. N. Kuklin.

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Original Russian Text © R.N. Kuklin, V.V. Emets, 2014, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2014, Vol. 50, No. 1, pp. 8–18.

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Kuklin, R.N., Emets, V.V. Form factor of the electron density of an anion specifically adsorbed on metal surface in an electrolyte. Prot Met Phys Chem Surf 50, 5–14 (2014). https://doi.org/10.1134/S2070205114010079

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