Abstract
The separation dynamics of mixtures of trans-stilbene hydroxyl derivatives (4-hydroxystilbene, 4,4′-dihydroxystilbene, α,α′-diethyl-4,4′-dihydroxystilbene (diethylstilbestrol), and 3,5,4′-trihyxrodystilbene (resveratrol)) is studied by the centrifugal (recycling) chromatography method. An algorithm of numerical modeling of the hydroxystilbene concentration front motion under conditions of a preparative thin-layer chromatography on chromatron is proposed. The correspondence of theoretical and experimental results is shown.
Similar content being viewed by others
References
Riviere, C., Pawlus, A.D., and Merillon, J.-M., Nat. Prod. Rep., 2012, vol. 29, p. 1317.
Fenol’nye soedineniya: Fundamental’nye i prikladnye aspekty (Phenolic Compounds: Fundamental and Applied Aspects) Zagoskin, N.V. and Burlakov, E.B., Eds., Moscow: Nauchnyi Mir, 2010, p. 400.
Shen, T., Wang, X.N., and Lou, X.X., Nat. Prod. Rep., 2009, vol. 26, p. 916.
Abbott, J.A., Medina-Bolivar, F., Martin, E.M., et al., Biotechnol. Prog., 2010, vol. 26, p. 1344.
Polunin, K.E., Shmal’ts, Kh.-G, and Polunina, I.A., Izv. Akad. Nauk, Ser. Khim., 2002, no. 7, p. 1219.
Zga, N., Papastamoulis, Y., Toribio, A., et al., J. Chromatogr., B: Anal. Technol. Biomed. Life Sci., 2009, vol. 877, p. 1000.
Polunin, K.E., Polunina, I.A., and Schmalz, H.-G., Mendeleev Commun., 2002, vol. 12, no. 5, p. 178.
Miller, R.B. and Case, W.S., J. Chem. Educ., 2011, vol. 88, no. 9, p. 1328.
Araki, T., Okazawa, T., Kubo, Y., Asai, H., and Ando, H., J. Liq. Chromatogr., 1988, vol. 11, p. 2473.
Huang, S.H., Lee, W.-C., and Tsao, G.T., Chem. Eng. J., 1988, vol. 38, p. 179.
Larin, A.V., Bull. Acad. Sci. USSR. Div. Chem. Sci., 1983, vol. 32, p. 211.
Larin A.V, Bull. Acad. Sci. USSR. Div. Chem. Sci., 1984, vol. 33, p. 1112.
Larin, A.V., Frolova, E.A., and Chicherina, N.Yu., Colloid. J., 1994, vol. 56, no. 3, p. 383.
Larin A.V, Russ. Chem. Bull., 2011, vol. 60, p. 376.
Larin, A.V., Prot. Met. Phys. Chem. Surf., 2011, vol. 47, no. 6, p. 743.
Larin, A.V., Prot. Met. Phys. Chem. Surf., 2013, vol. 49, no. 6, p. 642.
Larin, A.V., Colloid J., 2012, vol. 74, no. 3, p. 411.
Kolotilov, P.N., Polunin, K.E., Polunina, I.A., and Larin, A.V., Sorbtsionnye Khromatogr. Processy, 2008, vol. 8, no. 2, p. 210.
Kolotilov, P.N., Polunin, K.E., Polunina, I.A., and Larin, A.V., Prot. Met. Phys. Chem. Surf., 2009, vol. 45, no. 1, p.19.
Polunin, K.E., Kolotilov, P.N., Polunina, I.A., and Larin, A.V., Prot. Met. Phys. Chem. Surf., 2010, vol. 46, no. 1, p. 64.
Kolotilov, P.N., Polunin, K.E., Polunina, I.A., and Larin, A.V., Colloid J., 2010, vol. 72, no. 4, p. 499.
Martin, A.J.P. and Synge, R.L.M., Biochem. J., 1941, vol. 35, p. 1358.
Larin, A.V., J. Eng. Phys. Thermophys., 2011, vol. 84, no. 6, p. 1263.
Larin A.V., Colloid J., 2011, vol. 73, no. 6, p. 856.
Snyder, L.R., Principles of adsorption chromatography, NewYork: Marcel Dekker, 1968.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © D.V. Dzardanov, K.E. Polunin, I.A. Polunina, 2014, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2014, Vol. 50, No. 1, pp. 31–37.
Rights and permissions
About this article
Cite this article
Dzardanov, D.V., Polunin, K.E. & Polunina, I.A. Modeling of dynamic separation of hydroxystilbene mixtures in centrifugal chromatography. Prot Met Phys Chem Surf 50, 27–33 (2014). https://doi.org/10.1134/S207020511401002X
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S207020511401002X