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Thermodynamics of chemical and electrochemical stability of copper-nickel alloys

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Abstract

With the use of the substitution solution model, thermodynamic properties of Cu-Ni solid solutions are described in the stratification region. Cross sections of the Cu-Ni-O phase diagram and potentialpH diagrams of the German silver-H2O systems, such as CuNi19-H2O and MNZhMts30-1-1-H2O, at 25°C and 1 bar are plotted. The homogeneity region of NiO x phase at equilibrium with atmospheric oxygen is estimated at various temperatures. Thermodynamic features of the corrosion-electrochemical behavior of copper-nickel alloys are analyzed.

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  1. Chelyabinsk State University, ul Brat’ev Kashirinykh 129, Chelyabinsk, 454021, Russia

    P. A. Nikolaychuk & A. G. Tyurin

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Original Russian Text © P.A. Nikolaychuk, A.G. Tyurin, 2012, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2012, Vol. 48, No. 4, pp. 398–412.

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Nikolaychuk, P.A., Tyurin, A.G. Thermodynamics of chemical and electrochemical stability of copper-nickel alloys. Prot Met Phys Chem Surf 48, 462–476 (2012). https://doi.org/10.1134/S2070205112040132

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